{"title":"在钌掺杂石墨烯和氧空位中植入HxYO2−x位用于低过电位碱性析氢","authors":"Xiang Li, Wei Deng, Yun Weng, Jingjing Zhang, Haifang Mao, Tiandong Lu, Wenqian Zhang, Renqiang Yang, Fei Jiang","doi":"10.1038/s41427-023-00501-z","DOIUrl":null,"url":null,"abstract":"Abstract Highly efficient electrocatalysts for the hydrogen evolution reaction (HER) are essential for sustainable hydrogen energy. The controllable production of hydrogen energy by water decomposition depends heavily on the catalyst, and it is extremely important to seek sustainable and highly efficient water-splitting electrocatalysts for energy applications. Herein, bimetallic RuYO 2 − x nanoparticles (Ru: 8.84 at.% and Y: 13 at.%) with high densities and low loadings were synthesized and anchored on graphene through a simple solvothermal strategy by synthesizing hydrogen yttrium ketone (H x YO 2 − x ) serving as an inserted medium. Electron microscopy demonstrated that the RuYO 2 − x /C was composed of densely arranged particles and graphene flakes. Electrochemical results showed that the RuYO 2 − x /C had a remarkably low overpotential of η 10 = 56 mV at a current density of 10 mA cm −2 in alkaline media, a Tafel slope of 63.18 mV dec −1 , and 24 h of stability. The oxygen vacancies of RuYO 2 − x /C provided a large proton storage capacity and a strong tendency to bind hydrogen atoms. DFT calculations showed that RuYO 2 − x/ C catalysts with more Ru-O-Y bonds and V O dramatically decreased the energy barrier for breaking H-OH bonds. Moreover, the robust metal-support interactions provided optimized energies for hydrogen adsorption and desorption, which explained the high activity and favorable kinetics for RuYO 2 − x /C catalytic hydrogen precipitation in alkaline electrolyte reactions. This work presents a hydrogen insertion method for the preparation of low-loading, high-density, high-performance and stable water decomposition catalysts for hydrogen production.","PeriodicalId":19382,"journal":{"name":"Npg Asia Materials","volume":"1 1","pages":"0"},"PeriodicalIF":8.6000,"publicationDate":"2023-10-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Implanting HxYO2−x sites into Ru-doped graphene and oxygen vacancies for low-overpotential alkaline hydrogen evolution\",\"authors\":\"Xiang Li, Wei Deng, Yun Weng, Jingjing Zhang, Haifang Mao, Tiandong Lu, Wenqian Zhang, Renqiang Yang, Fei Jiang\",\"doi\":\"10.1038/s41427-023-00501-z\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract Highly efficient electrocatalysts for the hydrogen evolution reaction (HER) are essential for sustainable hydrogen energy. The controllable production of hydrogen energy by water decomposition depends heavily on the catalyst, and it is extremely important to seek sustainable and highly efficient water-splitting electrocatalysts for energy applications. Herein, bimetallic RuYO 2 − x nanoparticles (Ru: 8.84 at.% and Y: 13 at.%) with high densities and low loadings were synthesized and anchored on graphene through a simple solvothermal strategy by synthesizing hydrogen yttrium ketone (H x YO 2 − x ) serving as an inserted medium. Electron microscopy demonstrated that the RuYO 2 − x /C was composed of densely arranged particles and graphene flakes. Electrochemical results showed that the RuYO 2 − x /C had a remarkably low overpotential of η 10 = 56 mV at a current density of 10 mA cm −2 in alkaline media, a Tafel slope of 63.18 mV dec −1 , and 24 h of stability. The oxygen vacancies of RuYO 2 − x /C provided a large proton storage capacity and a strong tendency to bind hydrogen atoms. DFT calculations showed that RuYO 2 − x/ C catalysts with more Ru-O-Y bonds and V O dramatically decreased the energy barrier for breaking H-OH bonds. Moreover, the robust metal-support interactions provided optimized energies for hydrogen adsorption and desorption, which explained the high activity and favorable kinetics for RuYO 2 − x /C catalytic hydrogen precipitation in alkaline electrolyte reactions. This work presents a hydrogen insertion method for the preparation of low-loading, high-density, high-performance and stable water decomposition catalysts for hydrogen production.\",\"PeriodicalId\":19382,\"journal\":{\"name\":\"Npg Asia Materials\",\"volume\":\"1 1\",\"pages\":\"0\"},\"PeriodicalIF\":8.6000,\"publicationDate\":\"2023-10-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Npg Asia Materials\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1038/s41427-023-00501-z\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Npg Asia Materials","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1038/s41427-023-00501-z","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Implanting HxYO2−x sites into Ru-doped graphene and oxygen vacancies for low-overpotential alkaline hydrogen evolution
Abstract Highly efficient electrocatalysts for the hydrogen evolution reaction (HER) are essential for sustainable hydrogen energy. The controllable production of hydrogen energy by water decomposition depends heavily on the catalyst, and it is extremely important to seek sustainable and highly efficient water-splitting electrocatalysts for energy applications. Herein, bimetallic RuYO 2 − x nanoparticles (Ru: 8.84 at.% and Y: 13 at.%) with high densities and low loadings were synthesized and anchored on graphene through a simple solvothermal strategy by synthesizing hydrogen yttrium ketone (H x YO 2 − x ) serving as an inserted medium. Electron microscopy demonstrated that the RuYO 2 − x /C was composed of densely arranged particles and graphene flakes. Electrochemical results showed that the RuYO 2 − x /C had a remarkably low overpotential of η 10 = 56 mV at a current density of 10 mA cm −2 in alkaline media, a Tafel slope of 63.18 mV dec −1 , and 24 h of stability. The oxygen vacancies of RuYO 2 − x /C provided a large proton storage capacity and a strong tendency to bind hydrogen atoms. DFT calculations showed that RuYO 2 − x/ C catalysts with more Ru-O-Y bonds and V O dramatically decreased the energy barrier for breaking H-OH bonds. Moreover, the robust metal-support interactions provided optimized energies for hydrogen adsorption and desorption, which explained the high activity and favorable kinetics for RuYO 2 − x /C catalytic hydrogen precipitation in alkaline electrolyte reactions. This work presents a hydrogen insertion method for the preparation of low-loading, high-density, high-performance and stable water decomposition catalysts for hydrogen production.
期刊介绍:
NPG Asia Materials is an open access, international journal that publishes peer-reviewed review and primary research articles in the field of materials sciences. The journal has a global outlook and reach, with a base in the Asia-Pacific region to reflect the significant and growing output of materials research from this area. The target audience for NPG Asia Materials is scientists and researchers involved in materials research, covering a wide range of disciplines including physical and chemical sciences, biotechnology, and nanotechnology. The journal particularly welcomes high-quality articles from rapidly advancing areas that bridge the gap between materials science and engineering, as well as the classical disciplines of physics, chemistry, and biology. NPG Asia Materials is abstracted/indexed in Journal Citation Reports/Science Edition Web of Knowledge, Google Scholar, Chemical Abstract Services, Scopus, Ulrichsweb (ProQuest), and Scirus.