锌离子电池研究与发展综述

Matthew Mackereth, Rong Kou, Sohail Anwar
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摘要

随着锂离子电池技术的进步,可充电、耐用、持久、轻便的离子电池的普及和意识已经进入公众视野一段时间了。锂离子(Li-ion)并不是唯一一种离子电池。锌离子(Zn-ion)电池更重,但更安全、更便宜、更环保,这种电池技术在便携性不是主要目标的情况下可以使用。一个这样的用例是用于间歇性可再生能源(如太阳能和风力场)的大型能源存储,当太阳不再发光或风吹时。锌离子电池的缺点之一是,目前的电池寿命需要增加,才能在消费者需求方面与锂离子电池抗衡。本文介绍了硬币电池中电极结构和充放电速率对电池循环寿命的影响。对称电池的研究表明,较高的充放电速率降低了电池的循环寿命,而聚合物包覆锌阳极提高了电池的循环寿命。此外,与电池中的所有主要部件保持良好的接触对于电池的正常工作至关重要。在这个手稿中描述了在实验室中进行的电池制造过程和电池制造的重要细节。
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Zinc-Ion Battery Research and Development: A Brief Overview
With the advancement in the technology of lithium-ion batteries, the popularity and awareness of rechargeable, durable, long-lasting, and lightweight ion batteries have been in the public eye for a while now. Lithium-ion (Li-ion) is not the only type of ion battery out there. Zinc-ion (Zn-ion) batteries are a heavier, but safer, cheaper, and environmentally friendly form of this battery technology that has uses when portability is not the primary objective. One such use case is large format energy storage for intermittent renewable energy such as solar and wind fields for when the sun is no longer shining, or the wind blowing. One of the disadvantages of Zn-ion batteries is that the current battery life needs to be increased to stand a chance against Li-ion batteries in terms of consumer demands. This paper describes the effect of electrode structures and charging/discharging rates on battery cycle life in coin cells. The symmetric cell study shows that higher charging/discharging rates decrease the battery's cycle life, and the polymer-coated Zn anodes improve the battery's cycle life. It is also noted that maintaining good contact with all the major components in batteries is crucial for batteries to work properly. The battery-making process carried out in the lab and the important details of battery manufacturing are described in this manuscript.
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