五氧化二钒(V2O5)光催化剂的合成、性能及应用综述

IF 0.8 Q3 MULTIDISCIPLINARY SCIENCES Malaysian Journal of Fundamental and Applied Sciences Pub Date : 2023-10-19 DOI:10.11113/mjfas.v19n5.2774
K. S. A. Sohaimi, J. Jaafar, N. Rosman
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引用次数: 0

摘要

世界范围内的水污染日益严重,引发了人们对光催化的兴趣,这是一种可行的水处理方法。五氧化二钒(V2O5)具有结晶度好、收率高、可循环利用、成本低、耐光腐蚀、带隙小(2.3 eV)、电子迁移率高、吸收范围宽等优点,是一种良好的光催化降解光催化剂。纯V2O5的光催化效率受到低效的光子和量子过程的限制,其微小的结构使光生载流子重组,降低了效率。这阻止了V2O5的广泛使用。本文综述了V2O5作为一种有效的可见光催化剂,重点介绍了它的结构、合成方法和提高其效率的修饰。综述了水热法、溶胶-凝胶法、共沉淀法、溶剂热法等。所采用的方法影响光催化剂的效率。光生电子-空穴分离、电荷向催化剂表面或跨两相催化剂界面的转移以及活性物质与有害污染物的相互作用都受到影响。对染料、酚类和制药废物的光氧化还原利用进行了探索。根据过去几十年的回顾,V2O5主要用于染料污染物的降解,较少用于制药废物和其他污染物的降解。V2O5对不同目标污染物的处理能力和质量有待进一步研究。本文讨论了目前生产五氧化二钒体系的障碍和未来的研究前景。尽管V2O5具有作为光催化剂的潜力,但作为电子存储材料的研究还不够深入。大量的研究表明,V2O5可以像锂电池一样储存能量。这一发现可能会激励研究人员和新来者探索V2O5的潜力,以合成具有更高电子存储容量的纳米材料,使其成为一种良好的昼夜光催化剂。本文综述对今后V2O5的研究有一定的指导意义。
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Synthesis, Properties, and Applications of Vanadium Pentoxide (V2O5) as Photocatalyst: A Review
Water pollution has increased worldwide, sparking interest in photocatalysis, a viable water treatment approach. Vanadium pentoxide (V2O5) is a good photocatalyst for photocatalytic degradation due to its excellent crystallinity, high yield and recyclability, low cost, photo-corrosion resistance, small band gap (2.3 eV), improved electron mobility, and broad absorption range. Pure V2O5's photocatalytic efficiency is limited by inefficient photonic and quantum processes, and its tiny structure enables photogenerated carriers to recombine, reducing efficiency. This prevents widespread use of V2O5. This mini-review examines V2O5 as a potent visible-light photocatalyst, focusing on its structure, synthesis methods, and modifications that improve its efficiency. Hydrothermal, sol-gel, co-precipitation, solvothermal, and others are reviewed. The methods employed affect the photocatalyst's efficiency. Photogenerated electron-hole separation, charge transfer to catalyst surface or across two-phase catalyst interfaces, and reactive species interaction with hazardous contaminants are all affected. Photoredox uses have been explored for dyes, phenols, and pharmaceutical wastes. According to a review of the past decades, V2O5 has primarily been used for the degradation of dye pollutants, with fewer applications for pharmaceutical wastes and other pollutants. More research on V2O5's capabilities and qualities on diverse target pollutants is needed. This mini-review discusses present obstacles in producing vanadium pentoxide-based systems and future research prospects. Despite its potential as a photocatalyst, V2O5 has not been thoroughly researched as an electron storage material. Numerous investigations have shown that V2O5 can store energy like lithium batteries. This finding will likely motivate researchers and newcomers to explore V2O5's potential to synthesise nanomaterials with increased electron storage capacity, making it a good day-night photocatalyst. This review should improve future V2O5 research.
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CiteScore
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45
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