天然高岭石-高岭石双组分一维纳米材料对Ce3+离子的吸附

Thao Le Thi Phuong, Thoa Nguyen Thi Kim, Duyen Le Thi
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摘要

稀土元素由于其独特的电光性质,被广泛应用于反应物、合金元素、催化剂、电池、超导体等诸多技术领域。稀土元素的回收和分离尤其重要,因为它们可以增加稀缺资源并减少与辐射有关的废物处置危害。近年来,关于稀土元素对微生物、植物和动物的有害影响的报道越来越普遍。更危险的是,稀土元素的残留物会通过食物链的摄入或消化在人体内积累。因此,找到一种实用且经济的方法来使用稀土元素或将其从我们的环境中移除是至关重要的。为了提取这些元素,高岭土采用一种简单的化学过程来生产稀土金属离子吸附材料。经过处理的高岭土具有棒状的一维纳米形态。高岭石-高岭石是两相型的吸附剂材料。研究结果表明,高岭土对Ce3+具有较强的吸附能力。高岭土对Ce3+的吸附采用单层物理吸附模型和拟二级吸附动力学方程。
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Adsorption of Ce3+ ions using a one-dimensional nanomaterial with natural halloysite-kaolinite dual components
Rare earth elements are widely used in many technological domains, including reactants, alloying elements, catalysts, batteries, superconductors, etc., because of their unique electro-optical properties. Recovery and separation of rare earth elements are particularly crucial due to the steadily rising demand, as they can enhance scarce resources and reduce radiation-related waste disposal harm. Reports about the harmful effects of rare earth elements on microbes, plants, and animals have become increasingly common in recent years. More dangerously, residues from rare earth elements can build up in the human body through ingestion or digestion in the food chain. Finding a practical and affordable way to use rare earth elements or remove them from our surroundings is therefore essential. To extract these elements, halloysite is processed using a straightforward chemical procedure to produce rare earth metal ion adsorbent materials. The Halloysite that has been processed has a rod-shaped, one-dimensional nanomorphology. Halloysite-kaolinite is the two-phase version of the adsorbent material. The strong adsorption capacity of halloysite for Ce3+ is demonstrated by research findings. Halloysite adsorbs Ce3+ using the monolayer physical adsorption model and the pseudo-second-order adsorption kinetic equation.
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