温度对潜在绿色溶剂提取蓖麻籽油的影响

Zinhle Innocentia Mkhize, Peterson Thokozani Ngema, Suresh Ramsuroop
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摘要

以d-柠檬烯、对花香烃、α-蒎烯、乙醇和糠醛为溶剂,在(323 ~ 413)k的温度范围内提取蓖麻籽中的蓖麻油,并采用索氏提取法考察了大气压下温度对提取蓖麻油的影响。本研究的重点是研究一种潜在的绿色溶剂,与传统溶剂(己烷)相比,它可以产生更高的收率。结果表明,在平均反应时间为3 h 30 min时,蓖麻油的绿色溶剂得率依次为糠醛(47.13%)>乙醇(45.37%)>对花香烃(39.15%)> d-柠檬烯(39.13%)> α-蒎烯(38.11%)。每种绿色溶剂在最佳温度下得到蓖麻油收率。在相同平均时间内,蓖麻油得率与己烷得率(31.36%)进行了比较。除糠醛难回收外,其余绿色溶剂均采用简单蒸馏法回收。
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Effect of Temperature on Extraction of Castor Oil from Castor Seeds Using Potential Green Solvents
Extraction of castor oil from castor seeds was investigated using different green solvents which include d-limonene, p-cymene, α-pinene, ethanol, and furfural at the temperature range of (323 - 413) K. The Soxhlet extraction method was employed to investigate the effect of temperature at atmospheric pressure. The focus of the study was to investigate a potential green solvent that can produce the high yields compared to the traditional solvent (hexane). The results show that at the average time of 3 hours and 30 minutes, the castor oil yield for green solvents were ranked as furfural (47.13%) > ethanol (45.37%) > p-cymene (39.15%) > d-limonene (39.13%) > α-pinene (38.11%). These castor oil yields were obtained at optimum temperatures for each green solvent. The castor oil yields were compared to the yield of hexane (31.36%) at same average time. The green solvents were recovered by using simple distillation, except furfural which was difficult to be recovered.
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