Inlice(土耳其科尼亚)高硫化热液型金矿床的矿物学、流体包裹体和稳定同位素特征:对热液演化和矿石成因的影响

IF 2.6 3区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Chemie Der Erde-Geochemistry Pub Date : 2023-10-18 DOI:10.1016/j.chemer.2023.126040
Mustafa Haydar Terzi , Erkan Yılmazer , İlkay Kuşcu , Tolga Oyman , Sercan Bozan
{"title":"Inlice(土耳其科尼亚)高硫化热液型金矿床的矿物学、流体包裹体和稳定同位素特征:对热液演化和矿石成因的影响","authors":"Mustafa Haydar Terzi ,&nbsp;Erkan Yılmazer ,&nbsp;İlkay Kuşcu ,&nbsp;Tolga Oyman ,&nbsp;Sercan Bozan","doi":"10.1016/j.chemer.2023.126040","DOIUrl":null,"url":null,"abstract":"<div><p>The Inlice high sulfidation epithermal gold deposit with 262,300 oz of gold ore is located in the Erenlerdağ-Alacadağ Volcanic Complex (EAVC) at the northern part of central Taurides. The volcanic succession of the study area is stratigraphically represented by andesite, block and ash flow, basaltic andesite lava flow and andesite lava flow. The deposit consists of seven neighboring mineralized veins termed Ana East, Ana West, West, Discovery, Güllü, Merkez and North Zone and is associated with an andesite (<em>ca</em> 8–9 Ma). Hydrothermal alteration from the innermost to the outermost parts of the deposit includes silicification, advanced argillic, intermediate argillic and propylitic. At the surface, quartz veins related to silicification are exposed as linear topographic relief trending mainly northwest-southeast and secondarily northeast-southwest and east-west. Deep drill core samples, including magnetite, quartz, biotite and anhydrite, imply the presence of potassic alteration in depth (50 to 970 m) possibly related to a porphyry Cu system. Ore assemblages are described as hypogene and supergene. The hypogene ore mainly includes pyrite (Py-I and Py-II) and enargite, and to a lesser extent chalcopyrite, sphalerite and marcasite. The supergene ore incorporates hematite and goethite, and minor covellite, chalcocite, malachite and native copper. Hypogene gold precipitation is associated with the mineral association of Py-II, chalcopyrite and enargite, while enargite mineral is a major host for gold (up to 600 ppm). Supergene oxidation resulted in the development of a secondary enrichment zone for gold (up to 14 g/t) extending to a depth of about 45 m.</p><p>Microthermometric measurements show that the silicification associated with the mineralization was formed at homogenization temperatures ranging between 147 and 360 °C and salinities up to 6.5 wt% NaCl. This suggests that the fluid mixing and/or fluid dilution processes were important factors controlling the precipitation of gold. δ<sup>34</sup>S isotope compositions are between −0.9 and − 9 ‰, and further indicate a significant involvement of magmatic components into the hydrothermal fluids. Thus, it is concluded that at Inlice the hydrothermal fluids responsible for the alteration and mineralization processes were derived by relatively dilute fluids formed by the mixing of magmatic fluids with meteoric waters.</p></div>","PeriodicalId":55973,"journal":{"name":"Chemie Der Erde-Geochemistry","volume":null,"pages":null},"PeriodicalIF":2.6000,"publicationDate":"2023-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0009281923000910/pdfft?md5=a47886f3b78fd7efcf5dc1f2f11968a6&pid=1-s2.0-S0009281923000910-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Mineralogy, fluid inclusion and stable isotope characteristics of the Inlice (Konya, Turkey) high sulfidation epithermal gold deposit: Implications for hydrothermal evolution and ore genesis\",\"authors\":\"Mustafa Haydar Terzi ,&nbsp;Erkan Yılmazer ,&nbsp;İlkay Kuşcu ,&nbsp;Tolga Oyman ,&nbsp;Sercan Bozan\",\"doi\":\"10.1016/j.chemer.2023.126040\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The Inlice high sulfidation epithermal gold deposit with 262,300 oz of gold ore is located in the Erenlerdağ-Alacadağ Volcanic Complex (EAVC) at the northern part of central Taurides. The volcanic succession of the study area is stratigraphically represented by andesite, block and ash flow, basaltic andesite lava flow and andesite lava flow. The deposit consists of seven neighboring mineralized veins termed Ana East, Ana West, West, Discovery, Güllü, Merkez and North Zone and is associated with an andesite (<em>ca</em> 8–9 Ma). Hydrothermal alteration from the innermost to the outermost parts of the deposit includes silicification, advanced argillic, intermediate argillic and propylitic. At the surface, quartz veins related to silicification are exposed as linear topographic relief trending mainly northwest-southeast and secondarily northeast-southwest and east-west. Deep drill core samples, including magnetite, quartz, biotite and anhydrite, imply the presence of potassic alteration in depth (50 to 970 m) possibly related to a porphyry Cu system. Ore assemblages are described as hypogene and supergene. The hypogene ore mainly includes pyrite (Py-I and Py-II) and enargite, and to a lesser extent chalcopyrite, sphalerite and marcasite. The supergene ore incorporates hematite and goethite, and minor covellite, chalcocite, malachite and native copper. Hypogene gold precipitation is associated with the mineral association of Py-II, chalcopyrite and enargite, while enargite mineral is a major host for gold (up to 600 ppm). Supergene oxidation resulted in the development of a secondary enrichment zone for gold (up to 14 g/t) extending to a depth of about 45 m.</p><p>Microthermometric measurements show that the silicification associated with the mineralization was formed at homogenization temperatures ranging between 147 and 360 °C and salinities up to 6.5 wt% NaCl. This suggests that the fluid mixing and/or fluid dilution processes were important factors controlling the precipitation of gold. δ<sup>34</sup>S isotope compositions are between −0.9 and − 9 ‰, and further indicate a significant involvement of magmatic components into the hydrothermal fluids. Thus, it is concluded that at Inlice the hydrothermal fluids responsible for the alteration and mineralization processes were derived by relatively dilute fluids formed by the mixing of magmatic fluids with meteoric waters.</p></div>\",\"PeriodicalId\":55973,\"journal\":{\"name\":\"Chemie Der Erde-Geochemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2023-10-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S0009281923000910/pdfft?md5=a47886f3b78fd7efcf5dc1f2f11968a6&pid=1-s2.0-S0009281923000910-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemie Der Erde-Geochemistry\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0009281923000910\",\"RegionNum\":3,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"GEOCHEMISTRY & GEOPHYSICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemie Der Erde-Geochemistry","FirstCategoryId":"89","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0009281923000910","RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"GEOCHEMISTRY & GEOPHYSICS","Score":null,"Total":0}
引用次数: 0

摘要

拥有 262,300 盎司金矿石的 Inlice 高硫化热液型金矿位于陶里德斯中部北部的埃伦勒达-阿拉卡达火山群(Erenlerdağ-Alacadağ Volcanic Complex,EAVC)。研究区域的火山演替在地层上表现为安山岩、块状火山灰流、玄武安山岩熔岩流和安山岩熔岩流。该矿床由七条相邻的矿化脉组成,分别称为 Ana East、Ana West、West、Discovery、Güllü、Merkez 和 North Zone,与安山岩(约 8-9 Ma)有关。从矿床最内层到最外层的热液蚀变包括硅化、高级箭状、中级箭状和丙炔状。在地表,与硅化作用有关的石英脉以线状地形浮雕的形式出露,主要呈西北-东南走向,其次呈东北-西南和东西走向。深层钻探岩芯样本(包括磁铁矿、石英、生物岩和无水石膏)表明,深层(50 米至 970 米)存在钾盐蚀变,可能与斑岩铜矿系统有关。矿石组合被描述为下生矿石和超生矿石。下成岩矿石主要包括黄铁矿(Py-I 和 Py-II)和菱镁矿,以及少量黄铜矿、闪锌矿和黑云母。超生矿石包括赤铁矿和鹅铁矿,以及少量的鹅绿石、黄铜矿、孔雀石和原生铜。下成岩金沉淀与 Py-II、黄铜矿和菱镁矿的矿物组合有关,而菱镁矿是金的主要矿床(高达 600 ppm)。超生氧化作用导致金的二次富集区(最高达 14 克/吨)延伸至约 45 米深处。微测温测量显示,与矿化有关的硅化作用是在 147 至 360 ℃ 的均质温度和最高达 6.5 wt%的氯化钠盐度条件下形成的。这表明流体混合和/或流体稀释过程是控制金沉淀的重要因素。δ34S同位素组成介于-0.9和-9‰之间,进一步表明热液中含有大量岩浆成分。因此,可以得出结论,在 Inlice,造成蚀变和矿化过程的热液是由岩浆流体与陨石水混合形成的相对稀释的流体所产生的。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Mineralogy, fluid inclusion and stable isotope characteristics of the Inlice (Konya, Turkey) high sulfidation epithermal gold deposit: Implications for hydrothermal evolution and ore genesis

The Inlice high sulfidation epithermal gold deposit with 262,300 oz of gold ore is located in the Erenlerdağ-Alacadağ Volcanic Complex (EAVC) at the northern part of central Taurides. The volcanic succession of the study area is stratigraphically represented by andesite, block and ash flow, basaltic andesite lava flow and andesite lava flow. The deposit consists of seven neighboring mineralized veins termed Ana East, Ana West, West, Discovery, Güllü, Merkez and North Zone and is associated with an andesite (ca 8–9 Ma). Hydrothermal alteration from the innermost to the outermost parts of the deposit includes silicification, advanced argillic, intermediate argillic and propylitic. At the surface, quartz veins related to silicification are exposed as linear topographic relief trending mainly northwest-southeast and secondarily northeast-southwest and east-west. Deep drill core samples, including magnetite, quartz, biotite and anhydrite, imply the presence of potassic alteration in depth (50 to 970 m) possibly related to a porphyry Cu system. Ore assemblages are described as hypogene and supergene. The hypogene ore mainly includes pyrite (Py-I and Py-II) and enargite, and to a lesser extent chalcopyrite, sphalerite and marcasite. The supergene ore incorporates hematite and goethite, and minor covellite, chalcocite, malachite and native copper. Hypogene gold precipitation is associated with the mineral association of Py-II, chalcopyrite and enargite, while enargite mineral is a major host for gold (up to 600 ppm). Supergene oxidation resulted in the development of a secondary enrichment zone for gold (up to 14 g/t) extending to a depth of about 45 m.

Microthermometric measurements show that the silicification associated with the mineralization was formed at homogenization temperatures ranging between 147 and 360 °C and salinities up to 6.5 wt% NaCl. This suggests that the fluid mixing and/or fluid dilution processes were important factors controlling the precipitation of gold. δ34S isotope compositions are between −0.9 and − 9 ‰, and further indicate a significant involvement of magmatic components into the hydrothermal fluids. Thus, it is concluded that at Inlice the hydrothermal fluids responsible for the alteration and mineralization processes were derived by relatively dilute fluids formed by the mixing of magmatic fluids with meteoric waters.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Chemie Der Erde-Geochemistry
Chemie Der Erde-Geochemistry 地学-地球化学与地球物理
CiteScore
7.10
自引率
0.00%
发文量
40
审稿时长
3.0 months
期刊介绍: GEOCHEMISTRY was founded as Chemie der Erde 1914 in Jena, and, hence, is one of the oldest journals for geochemistry-related topics. GEOCHEMISTRY (formerly Chemie der Erde / Geochemistry) publishes original research papers, short communications, reviews of selected topics, and high-class invited review articles addressed at broad geosciences audience. Publications dealing with interdisciplinary questions are particularly welcome. Young scientists are especially encouraged to submit their work. Contributions will be published exclusively in English. The journal, through very personalized consultation and its worldwide distribution, offers entry into the world of international scientific communication, and promotes interdisciplinary discussion on chemical problems in a broad spectrum of geosciences. The following topics are covered by the expertise of the members of the editorial board (see below): -cosmochemistry, meteoritics- igneous, metamorphic, and sedimentary petrology- volcanology- low & high temperature geochemistry- experimental - theoretical - field related studies- mineralogy - crystallography- environmental geosciences- archaeometry
期刊最新文献
Editorial Board Contrasting fluids and implications for ore genesis in the Jiawula-Chaganbulagen Porphyry Mo-epithermal PbZn metallogenetic system: Evidence from fluid inclusions and H-O-He-Ar isotopes Ediacaran anorogenic alkaline magmatism and wolframite mineralization linked to mantle plume activity in the north Arabian-Nubian Shield (Egypt) A hydrous sub-arc mantle domain within the northeastern Neo-Tethyan ophiolites: Insights from cumulate hornblendites Hydrothermal alteration of accessory minerals (allanite and titanite) in the late Archean Closepet granitoid (Dharwar Craton, India): A TEM study
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1