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Petrogenesis of Paleoproterozoic mafic magmatic rocks from Garhwal Lesser Himalayan Sequence: Implications for Precambrian crustal recycling and geodynamic evolution of proto-northern Indian continental margin Garhwal小喜马拉雅层序古元古代基性岩浆岩的岩石成因:对前寒武纪地壳再循环和原北印度大陆边缘地球动力学演化的启示
IF 2.9 3区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-01-09 DOI: 10.1016/j.chemer.2026.126387
Ashutosh Pandey , H.K. Sachan , Digvijay K. Dubey
The Precambrian geodynamic evolution of the proto-northern Indian continental margin remains elusive. Mafic magmatic rocks from the Lesser Himalayan Sequence, representing the northern extremity of the Indian Shield, provide key constraints on this evolution. This study presents new mineralogical and whole-rock geochemical data from mafic rocks in the Rudraprayag-Karnaprayag sector of the Garhwal Lesser Himalayan region, aiming to elucidate their genesis and geodynamic significance. The whole-rock geochemistry of the studied rocks exhibits enrichment in large-ion lithophile elements and depletion in high-field strength elements, with elevated Ba/Nb, Th/Yb, and La/Sm ratios, indicative of subduction-related metasomatism of the mantle source. The most primitive samples (with MgO > 7.5 wt%) exhibit major element systematics consistent with melts derived from a pyroxene-dominated mantle source, possibly produced by interaction between peridotite and siliceous melt. Estimated melting temperatures (1198–1385 °C) exclude the possibility of involvement of anomalously hot mantle plumes in the origin of these rocks and point towards a passive continental rifting setting. These observations suggest that the Paleoproterozoic mafic magmatic rocks of the Lesser Himalayan Sequence possibly originated in a continental back-arc extensional setting linked to an Andean-type active continental margin along the proto-northern Indian cratonic block. Our results support the evidence for an Andean-type active continental margin along the proto-northern Indian continental margin during the assembly of the Columbia supercontinent in the Paleoproterozoic.
原北印度大陆边缘的前寒武纪地球动力学演化仍然难以捉摸。来自小喜马拉雅层序的基性岩浆岩,代表了印度地盾的北端,为这一演化提供了关键的限制。本文介绍了加尔瓦尔小喜马拉雅地区Rudraprayag-Karnaprayag板块基性岩的新的矿物学和全岩地球化学资料,旨在阐明其成因和地球动力学意义。岩石全岩地球化学特征显示大离子亲石元素富集,高场强元素亏缺,Ba/Nb、Th/Yb、La/Sm比值升高,表明地幔源存在俯冲交代作用。最原始样品(含MgO >; 7.5% wt%)的主要元素系统特征与源自辉石岩为主的地幔源的熔体一致,可能是由橄榄岩和硅质熔体相互作用产生的。估计的熔融温度(1198-1385°C)排除了异常热地幔柱参与这些岩石起源的可能性,并指向被动大陆裂谷环境。这些观测结果表明,小喜马拉雅层序的古元古代基性岩浆岩可能起源于与原北印度克拉通地块的安第斯型活动大陆边缘相联系的大陆弧后伸展环境。我们的研究结果支持了古元古代哥伦比亚超大陆组装期间沿原北印度大陆边缘存在安第斯型活动大陆边缘的证据。
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引用次数: 0
Compositional zoning, crystal chemistry and metamorphic growth of monazite in the Greater Himalayan Sequence, Dhauliganga Valley, Garhwal Himalaya 大喜马拉雅层序中独居石的成分分带、晶体化学及变质生长
IF 2.9 3区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-01-07 DOI: 10.1016/j.chemer.2025.126384
Chandni Chaurasia , Satyajeet S. Thakur , Suresh C. Patel , Nainika Gour , Janisar M. Sheikh
X-ray elemental mapping and quantitative analysis of monazite grains contained in metapelites from the Greater Himalayan Sequence (crystalline core of the Himalaya) of the Dhauliganga Valley, Garhwal Himalaya were performed by electron probe micro-analyser to evaluate the zoning patterns. The rocks, from which monazites have been studied, include those with peak metamorphism (650–715 °C and 8.0–9.9 kbar) under subsolidus conditions and also those showing evidences of partial melting (<800 °C and 10.5 kbar). All the monazite analyses taken together show that Light Rare Earth Elements (LREEs) constitute 80–89 % of the total cation proportion (exclusive of P) and Heavy Rare Earth Elements (HREEs) 1–4 %, while other elements make 9–18 %. Zoning patterns vary from core–rim to patchy and irregular types. The rim is invariably Y-rich compared to the core. Compositional variability of monazites can be explained mostly by the brabantite substitution: 2REE3+ = (Th,U)4+ + Ca2+. Y shows negative correlation with LREE and positive correlation with HREE. The U-Th-Pb in situ analyses of one of the samples (HH52) suggests that the monazite grew at 26.28 ± 0.19 Ma. Likely metamorphic reactions for the growth of Y-poor monazite core and its resorption followed by overgrowth of Y-rich rim during progressive metamorphism have been explored. Phase equilibria considerations indicate that resorption and regrowth of monazite can occur in both subsolidus and suprasolidus regimes. The P–T path for the development of resorption–regrowth texture of monazite is inferred to be isothermal decompression in the case of subsolidus regime, and isobaric cooling to retrograde decompression in the case of suprasolidus conditions.
利用电子探针微量分析仪对喜马拉雅大喜马拉雅层序(喜马拉雅结晶岩心)的变长岩中独居石颗粒进行了x射线元素测图和定量分析,以评价其分带规律。对独居石进行了研究的岩石,包括那些在亚固态条件下具有峰值变质作用(650-715°C和8.0-9.9 kbar)的岩石,以及那些显示部分熔融证据(<;800°C和10.5 kbar)的岩石。所有独居石分析表明,轻稀土元素(lree)占总阳离子比例的80 - 89%(不含P元素),重稀土元素(hree)占1 - 4%,其他元素占9 - 18%。分区模式从核心-边缘到斑驳型和不规则型不等。与核心相比,边缘总是富含y元素。单氮石的组成变异性主要可以用钙辉石取代来解释:2REE3+ = (Th,U)4+ + Ca2+。Y与LREE呈负相关,与HREE呈正相关。其中一个样品(HH52)的U-Th-Pb原位分析表明,独居石生长在26.28±0.19 Ma。探讨了贫y独居石岩心生长和贫y独居石岩心再吸收后富y边缘过度生长的可能变质反应。相平衡的考虑表明,独居石的再吸收和再生长可以发生在亚固体和超固体状态。推断单独居石再吸收-再生长织构发育的P-T路径在亚固相状态下为等温减压,在超固相状态下为等压冷却到逆行减压。
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引用次数: 0
Degassing in middle-crust magma chamber: Evidence from the texture and chemistry of the zonal clinopyroxene from the high magnesium basalt in Ganzhou Basin, Jiangxi, South China 中壳岩浆房脱气:赣州盆地高镁玄武岩中斜辉石的结构与化学证据
IF 2.9 3区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-01-06 DOI: 10.1016/j.chemer.2026.126386
Lin Jia , Guolin Guo , Yan Zhao , Zhaobin Yan , Jianhua Wu , Wenya Yan , Tingting Zou
<div><div>Magmatic degassing is a key process during the ascent and evolution of basaltic magmas, providing critical insights into deep crust environments and geodynamics. Clinopyroxene, a ubiquitous ferromagnesian mineral in basaltic systems, exhibits compositional sensitivity to magmatic physicochemical conditions (e.g., temperature, pressure, H₂O content, oxygen fugacity) and thus serves as a valuable petrogenetic archive. This study investigates degassing events recorded by compositionally-zoned clinopyroxene phenocrysts in Late Cretaceous high-Mg basalts from the Ganzhou Basin, Jiangxi Province, China. Previous Sr-Nd-Pb-O isotope results indicated that these basalts were derived from an enriched mantle source without significant crustal contamination. Clinopyroxene grains predominantly exhibit distinct core-mantle-rim zoning. Equilibrium melt compositions, simulated based on clinopyroxene core, mantle, and rim compositions, yield high MgO contents (14.01–15.00 wt%), consistent with the high-Mg bulk-rock composition of Ganzhou basalts, despite minor discrepancies in some trace elements. Systematic major- and trace-element variations are observed across the zonal domains: Al₂O₃ contents progressively decrease from core to rim, while Fe, Ti, and trace elements increase significantly. Cores and mantles display characteristic negative Pb, Nd, and Zr anomalies. The decreasing Al₂O₃ trend reflects reduction tetrahedral Al<sup>3+</sup> occupancy in the clinopyroxene lattice with declining temperature and pressure during magmatic evolution, whereas the negative anomalies are attributed to early-stage magma evolution, geochemical imprints from the enriched mantle source, and ilmenite crystallization. Clinopyroxene thermobarometry reveals significant differences among zones: cores and mantles crystallized under relatively high temperatures, pressures, and melt water contents conditions, whereas rims and matrix clinopyroxenes formed under distinctly lower temperature, pressure, and melt water content. The sharp decrease in melt water content coupled with relatively stable Fe<sup>3+</sup>/ΣFe ratio from core to mantle, indicate a degassing/dehydration process in the middle-crust. The observed trends-sharp decrease in temperature, pressure, and Fe<sup>3+</sup>/ΣFe from mantle to rim, alongside a more gradual decline in melt water content, suggest magma eruption following degassing from a middle-crustal chamber. The contrasts between clinopyroxene phenocryst rims and matrix grains, characterized by further decreases in temperature and pressure but slight increases in H₂O content and Fe<sup>3+</sup>/ΣFe ratio, are interpreted as reflecting eruption into an oxidizing and hydrating atmospheric environment. Combine the regional tectonic setting, the formation of the Ganzhou Basin Late Cretaceous high-Mg basalts is related to an intra-continental extensional environment induced by westward subduction of the paleo-Pacific Plate beneath the Eurasian continent, wi
岩浆脱气是玄武岩岩浆上升和演化过程中的一个关键过程,为深入了解地壳深部环境和地球动力学提供了重要依据。斜辉石是一种在玄武岩体系中普遍存在的镁铁矿物,其成分对岩浆的物理化学条件(如温度、压力、h2o含量、氧逸度)非常敏感,因此是一种有价值的岩石成因档案。研究了江西赣州盆地晚白垩世高镁玄武岩中斜辉石斑晶的脱气事件。前人的Sr-Nd-Pb-O同位素结果表明,这些玄武岩来源于富集的地幔源,没有明显的地壳污染。斜辉石颗粒主要表现出明显的核-幔-缘分带。根据斜辉石岩心、地幔和边缘组成模拟的平衡熔体组成显示出较高的MgO含量(14.01 ~ 15.00 wt%),与赣州玄武岩的高mg块状岩石组成一致,但部分微量元素差异较小。系统的主要元素和微量元素的变化在整个带域被观察到:Al₂O₃的含量从核心到边缘逐渐减少,而Fe、Ti和微量元素显著增加。岩心和地幔表现出典型的Pb、Nd、Zr负异常。Al₂O₃减少趋势反映了岩浆演化过程中温度和压力下降,斜辉石晶格中Al3+的四面体占用减少,而负异常则是早期岩浆演化、富集地幔源的地球化学印记和钛铁矿结晶所致。斜斜辉石的热气压测量结果显示,不同带间的斜斜辉石存在显著差异:岩心和地幔在相对较高的温度、压力和熔融水含量条件下结晶,而边缘和基质斜斜辉石在明显较低的温度、压力和熔融水含量条件下结晶。熔融水含量的急剧下降,以及相对稳定的Fe3+/ΣFe比值表明中地壳存在脱气脱水过程。观测到的趋势——从地幔到边缘的温度、压力和Fe3+/ΣFe急剧下降,同时熔体水含量逐渐下降,表明岩浆爆发是在中间地壳室脱气之后发生的。斜辉石斑晶边缘与基体颗粒的对比表现为温度和压力进一步降低,但H₂O含量和Fe3+/ΣFe比值略有升高,反映了火山喷发进入氧化水化大气环境。结合区域构造背景,赣州盆地晚白垩世高镁玄武岩的形成与欧亚大陆下古太平洋板块西俯冲所致的陆内伸展环境有关,岩浆来源于富集地幔的减压熔融作用。斜辉石斑晶的核-幔-缘分带及其平衡熔体特征全面记录了一个多阶段的岩浆演化过程,包括早期深部岩浆房结晶、中期减压脱气和后期快速喷发。本研究为利用斜辉石分带研究华南板内基性岩浆演化提供了一个实例。
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引用次数: 0
Major element zonation following rapid heating of homogeneous glass in superliquidus experiments 超流体实验中均质玻璃快速加热后的主要元素分区
IF 2.9 3区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-12-26 DOI: 10.1016/j.chemer.2025.126383
Siobhan E.L. Kingham , Matthew Varnam , Lee M. Saper , Geoffrey D. Bromiley
High-temperature melting experiments in gas-mixing furnaces are used to simulate magmatic processes and provide insight into melt properties at controlled conditions. These experiments assume that rapid melting results in formation of homogeneous molten samples, especially when glassed starting materials are used. As part of an investigation of evaporative loss of moderately volatile elements (MVE) from lunar magma, we performed short-duration, superliquidus experiments using homogeneous glass starting materials. Powdered glass pellets and glass fragments were suspended on Pt wire loops, and rapidly inserted into the hotspot of a 1-atm vertical gas-mixing furnace at 1350 °C and log fO2 = IW to IW +2 (oxygen fugacity at, or 2 log units above, the Fe-FeO buffer). Samples were held within the furnace for 5–60 min before being drop-quenched into water. Scanning electron microscopy and electron probe microanalysis of sectioned run products evidence progressive MVE loss from samples, but with additional, unexpected, redistribution of refractory elements (SiO2, TiO2, MgO, FeO, Al2O3, CaO). Refractory element zonation reflects early heating processes, and is progressively eradicated during prolonged heating via diffusion. Zonation in shorter duration experiments also reveals variable, and sometimes chaotic, disruption of samples during quenching. We propose that refractive element zonation arises due to phase separation during heating, driven by partial devitrification of the interiors of glassy samples. Our results demonstrate that element redistribution during melting, and physical disruption of samples induced by quenching, can significantly affect chemical homogeneity. These effects should be considered when designing and interpreting data from short-duration high-temperature experiments.
气体混合炉的高温熔融实验用于模拟岩浆过程,并提供受控条件下熔体特性的见解。这些实验假设快速熔化导致形成均匀的熔融样品,特别是当使用玻璃化的起始材料时。作为研究月球岩浆中中度挥发性元素(MVE)蒸发损失的一部分,我们使用均质玻璃起始材料进行了短时间的超流体实验。将玻璃颗粒和玻璃碎片悬浮在铂丝环上,并迅速插入1-atm垂直气体混合炉的热点,温度为1350℃,log fO2 = IW至IW +2(氧逸度在Fe-FeO缓冲液或2 log以上)。样品在炉内保持5-60分钟,然后滴淬到水中。扫描电子显微镜和电子探针显微分析表明,样品的MVE逐渐减少,但有额外的,意想不到的,耐火元素(SiO2, TiO2, MgO, FeO, Al2O3, CaO)重新分布。耐火元素分区反映了早期的加热过程,并在延长加热过程中通过扩散逐渐消除。在较短持续时间的实验中,分区也揭示了淬火过程中样品的可变,有时是混乱的破坏。我们提出,由于加热过程中的相分离,由玻璃样品内部的部分反玻璃化驱动,折射元件区带产生。我们的研究结果表明,元素在熔化过程中的重新分配,以及淬火引起的样品的物理破坏,可以显著影响化学均匀性。在设计和解释短时间高温实验数据时应考虑这些影响。
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引用次数: 0
Pyrite chemistry patterns in gold-bearing metaconglomerates of the Jacobina Group, São Francisco Craton, Northeastern Brazil: Multivariate mineral chemistry insights and geological implications for gold exploration 巴西东北部<s:1> o Francisco克拉通Jacobina群含金变质砾岩中黄铁矿化学模式:多元矿物化学特征及其找金地质意义
IF 2.9 3区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-12-23 DOI: 10.1016/j.chemer.2025.126382
Guilherme Ferreira da Silva , Adalene Moreira Silva , Catarina Labouré Bemfica Toledo , Guilherme dos Santos Teles , Farid Chemale Junior , Evandro Luiz Klein , Artur Areal Braga
The gold-bearing metaconglomerates of the Jacobina Group exhibit complex mineralogical and geochemical features that are significant for gold exploration in the northern São Francisco Craton. A comprehensive analysis of pyrite chemistry patterns within the Jacobina Group was carried out using multivariate mineral chemistry techniques and geological constraints to elucidate their significance for gold exploration. Distinct pyrite types, distinguished by morphology, texture, and stratigraphic position, were identified through Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry (LA-ICP-MS) analysis. The results reveal a clear positive correlation between trace elements within detrital and epigenetic pyrite populations, providing insights into their origin and evolution. Notably, the presence of accessory minerals such as sphalerite, chalcopyrite, and pyrrhotite serve as key indicators of late-stage hydrothermal alteration and potential gold mineralization. The dimensionality reduction techniques, including Uniform Manifold Approximation and Projection (UMAP), indicate a spatial distribution of pyrite populations across different stratigraphic units. Moreover, agglomerative clustering analysis indicates that both geological context and mineral chemistry are important for delineating exploration targets. Our findings demonstrate that integrating multivariate mineral chemistry analysis with geological constraints can enhance gold exploration strategies. This study provides valuable insights into the complex relationship between pyrite chemistry, geological processes, and gold mineralization within the Jacobina Group, advancing our understanding of auriferous metaconglomerate deposits.
Jacobina群含金变质砾岩具有复杂的矿物学和地球化学特征,对弗朗西斯科克拉通北部的金矿找矿具有重要意义。利用多元矿物化学技术和地质约束条件对Jacobina群黄铁矿化学模式进行了综合分析,阐明了黄铁矿化学模式对金矿找矿的意义。通过激光烧蚀-电感耦合等离子体质谱(LA-ICP-MS)分析,以形态、质地和地层位置来区分不同的黄铁矿类型。结果揭示了碎屑中微量元素与表观遗传黄铁矿群体之间存在明显的正相关关系,为黄铁矿的起源和演化提供了新的思路。其中闪锌矿、黄铜矿、磁黄铁矿等伴生矿物的存在是后期热液蚀变和金矿化的重要标志。均匀流形近似和投影(UMAP)等降维技术显示了黄铁矿种群在不同地层单元中的空间分布。聚类分析表明,地质文脉和矿物化学对圈定找矿目标具有重要意义。研究结果表明,将多变量矿物化学分析与地质约束相结合,可以提高金矿找矿策略。本研究对Jacobina群黄铁矿化学、地质过程和金矿化之间的复杂关系提供了有价值的见解,促进了我们对含金变质砾岩矿床的认识。
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引用次数: 0
Mineralogical, geochemical, spectroscopic, and color-making elements investigation of agate and chalcedony mineralization; case study: Kasrab district, east Iran 玛瑙和玉髓矿化的矿物学、地球化学、光谱和制色元素研究案例研究:伊朗东部卡斯拉布地区
IF 2.9 3区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-12-22 DOI: 10.1016/j.chemer.2025.126381
Mohammadreza Hosseinzadeh , Ali Asadi , Vartan Simmonds , Matthew I. Leybourne
The agate and chalcedony mineralization in the Kasrab area displays a wide spectrum of colors, including black, purple, green, blue, lily (lavender), moss, red, lemon, and white, reflecting variations in trace elements and formation conditions. These minerals occur mainly in veins and veinlets cutting through carbonate rocks, as well as in open-space fillings within fresh and hydrothermally altered andesites. Moganite, a quartz polymorph, occurs both in vesicles and as microcrystalline overgrowths, indicating its role in the complex silica precipitation processes. Altered volcanic rocks show elevated concentrations of Al₂O₃, Fe₂O₃, Na₂O, K₂O, P₂O₅, and TiO₂, whereas fresh host rocks are richer in CaO and MgO, reflecting element mobilization during acidic hydrothermal alteration. Geochemical analyses reveal enrichment of LILEs (relative to primitive mantle-normalized values) and LREEs (relative to chondrite-normalized REE values) in both agates samples and host rocks, with agates showing slight LREE depletion, HREE enrichment (except Tm), and anomalies of Nb (negative) and Cs, U, Pb (positive), but negligible Eu anomaly. Petrographic study identified two main fluid inclusion types—vapor-rich (VL) and liquid-rich (LV)—with microthermometry indicating salinities up to 4.65 wt% NaCl equivalent and homogenization temperatures of 97–124 °C, consistent with low-salinity, low-temperature hydrothermal formation. Fluorescence spectroscopy revealed emission peaks of quartz, Cr3+, and Ca-bearing minerals (aragonite, calcite, diopside), while FT-IR confirmed hydroxyl groups, molecular water, and hydrated silica phases (opal-A, opal-C, opal-T). UV–Vis spectroscopy identified Fe3+ and Ni2+ transitions associated with hematite and goethite, contributing to coloration. Physical measurements show translucent agates have higher refractive indices and specific gravity than transparent ones, reflecting subtle differences in microstructure and impurity content.
Kasrab地区玛瑙和玉髓矿化呈现出广泛的颜色,包括黑色、紫色、绿色、蓝色、百合(薰衣草)、苔藓、红色、柠檬和白色,反映了微量元素和形成条件的变化。这些矿物主要存在于穿过碳酸盐岩的脉状和细静脉中,以及新鲜安山岩和热液蚀变安山岩中的露天充填物中。莫干石是一种石英多晶,既以囊泡形式存在,也以微晶过度生长的形式存在,表明它在复杂的二氧化硅沉淀过程中起着重要作用。蚀变火山岩中Al₂O₃、Fe₂O₃、Na₂O、K₂O、P₂O₅和TiO₂的浓度升高,而新鲜主岩中CaO和MgO的含量更丰富,反映了酸性热液蚀变过程中元素的调动。地球化学分析表明,在玛瑙样品和寄主岩石中均存在LILEs(相对于原始地幔归一化值)和LREE(相对于球粒陨石归一化REE值)富集,且玛瑙呈现轻微的LREE亏缺,HREE富集(Tm除外),Nb(负)和Cs、U、Pb(正)异常,但Eu异常可忽略不计。岩石学研究确定了两种主要的流体包裹体类型——富气包裹体(VL)和富液包裹体(LV),显微测温显示盐度高达4.65 wt% NaCl当量,均一温度为97 ~ 124℃,与低盐度、低温热液地层相一致。荧光光谱显示出石英、Cr3+和含钙矿物(文石、方解石、透辉石)的发射峰,而FT-IR证实了羟基、分子水和水合二氧化硅相(蛋白石- a、蛋白石- c、蛋白石- t)。紫外可见光谱鉴定出Fe3+和Ni2+与赤铁矿和针铁矿相关的跃迁,有助于着色。物理测量表明,半透明玛瑙的折射率和比重高于透明玛瑙,反映了其微观结构和杂质含量的细微差异。
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引用次数: 0
Petrogenesis of an A2-type intrusion associated with the late-post-collisional calc-alkaline Variscan granites from central-northern Portugal (Central Iberian Zone) 葡萄牙中北部(伊比利亚中部)与后碰撞晚期钙碱性Variscan花岗岩相关的a2型岩体的岩石成因
IF 2.9 3区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-12-15 DOI: 10.1016/j.chemer.2025.126376
Luís Portela, Maria Rosário Azevedo, Jorge Medina, Beatriz Valle Aguado
The Lusinde fine-grained biotite granite is a small pluton intruded into the metamorphic basement of the Central Iberian Zone during the waning stages of the Variscan Orogeny. LA-ICP-MS zircon UPb ages constrain pluton emplacement to ca. 297–295 Ma. Mineralogical and geochemical data reveals that the intrusion corresponds to a strongly ferroan, peraluminous, reduced A2-type granite (∆FMQ = −3.4 to −1.7, zircon oxybarometry), characterised by a narrow compositional range (SiO2 = 67.7–68.8 wt%), elevated FeOT/FeOT + MgO (0.90–0.92) and 10,000 × Ga/Al (3.1–3.4) ratios, high REE, LILE and HFSE contents and strong depletions in Ba, Sr, Nb, P, Eu and Ti. Decoupling between “mantle-like” Nd and zircon Hf (εNdi = −0.40 to +0.58; TDM2 = 0.81–0.95 Ga; zircon εHfi = −0.41 to +3.01; TDM2-Zrn = 1.08–1.30 Ga) and more “crust-like” Sr (87Sr/86Sri = 0.7097–0.7100) isotopic signatures suggests derivation from small degrees of partial melting of old juvenile mafic/intermediate rocks interlayered in the lower crust, with minor input from more evolved crustal sources. The only studied ferrodioritic enclave shares the A2-type affinity of the host granite and seems to have derived from a mixed source (enriched subcontinental lithospheric mantle and juvenile mafic crust), before injection into the silicic magma chamber. We propose that the generation of the Lusinde A-type granite magma and enclosed enclave occurred in a deep hot zone located at the mantle-lower crust interface, at about 7–10 kb and 850–950 °C, in an extensional post-collisional setting.
卢辛德细粒黑云母花岗岩是瓦里斯坎造山运动末期侵入伊比利亚中部变质基底的小型岩体。LA-ICP-MS锆石UPb年龄限制了岩体就位时间约为297-295 Ma。矿物学和地球化学数据表明,该岩体为强铁、过铝、还原a2型花岗岩(∆FMQ = - 3.4 ~ - 1.7,锆石氧压测量),其特征是组成范围窄(SiO2 = 67.7 ~ 68.8 wt%), FeOT/FeOT + MgO(0.90 ~ 0.92)和10,000 × Ga/Al(3.1 ~ 3.4)比值升高,REE、LILE和HFSE含量高,Ba、Sr、Nb、P、Eu和Ti富集。“地幔状”Nd和锆石Hf (εNdi = - 0.40 ~ +0.58, TDM2 = 0.81 ~ 0.95 Ga,锆石εHfi = - 0.41 ~ +3.01, TDM2- zrn = 1.08 ~ 1.30 Ga)与“地壳状”Sr (87Sr/86Sri = 0.7097 ~ 0.7100)同位素特征之间的解耦合表明,这些同位素特征来源于下地壳层间的老幼基性/中间岩的小程度部分熔融,较演化的地壳源的输入较少。唯一研究的铁闪长岩包体与寄主花岗岩具有a2型亲和关系,似乎是在注入硅质岩浆房之前,由一个混合来源(富集的次大陆岩石圈地幔和幼年基性地壳)形成的。我们认为Lusinde a型花岗岩岩浆和封闭包裹体的形成发生在地幔-下地壳界面的深部热区,温度约为7-10 kb, 850-950℃,处于伸展的碰撞后环境中。
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引用次数: 0
Compositional balance analysis for geochemical prospectivity mapping in Nenjiang–Heihe region, China 嫩江-黑河地区地球化学找矿填图的成分平衡分析
IF 2.9 3区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-12-08 DOI: 10.1016/j.chemer.2025.126375
Lidong Zhang , Yue Liu , Kewei Zhang , Ziqiang Zha , Jianeng Wu , Wenjun Xuan , Huiyuan Zhang
The Nenjiang–Heihe district, on the eastern margin of the Central Asian Orogenic Belt, hosts porphyry CuMo and epithermal Au systems emplaced through multiple tectonomagmatic episodes. To extract process–diagnostic signals from regional geochemistry and convert them into practical exploration targets, we applied compositional balance analysis (CoBA) and the concentration–area (C–A) fractal model to stream–sediment geochemical data collected from the Nenjiang–Heihe region, China. Compositional hierarchical clustering and a suite of data– and knowledge–driven balances identify three complementary geochemical patterns: (i) Fe–oxide–rich intermediate–mafic domains that define broad NNE–NE corridors coincident with volcanic belts and major faults; (ii) porphyry/base–metal chalcophile behavior (e.g., b01, b02, b03, b08, b7, b26, and b31) that captures Cu anomalies along permeable structures; and (iii) felsic–HFSE/LILE fertility and volatile–rich epithermal overprints, highlighted by b05, b06, b07, b15, and b16, localized over or adjacent to intermediate–felsic intrusions. C–A breakpoints provide objective thresholds that delineate statistically significant targets. Highest–priority prospects occur where b01–b02 highs overlap at fault intersections and locally coincide with b06 anomalies. The results demonstrate that CoBA, coupled with C–A segmentation, offers a low–cost, and interpretable framework for prospectivity mapping in forest–swamp terrain, mitigating closure effects and enhancing weak but geologically meaningful signals for decision–making.
中亚造山带东部边缘的嫩江-黑河地区发育多期构造岩浆侵位的斑岩型铜钼矿和浅热液型金成矿体系。为了从区域地球化学中提取过程诊断信号,并将其转化为实际的勘探目标,应用成分平衡分析(CoBA)和浓度-面积(C-A)分形模型对中国灌江-黑河地区的河流-沉积物地球化学数据进行了分析。成分分层聚类和一套数据和知识驱动的平衡确定了三种互补的地球化学模式:(i)富含氧化铁的中基性域,定义了与火山带和主要断层重合的广泛的NNE-NE走廊;(ii)斑岩/贱金属亲铜行为(如b01、b02、b03、b08、b7、b26和b31),可捕获沿渗透结构的Cu异常;(iii)长硅质- hfse /LILE肥力和挥发物丰富的低温热液叠层,以b05、b06、b07、b15和b16为突出特征,位于中长硅质侵入体之上或邻近。C-A断点提供客观阈值,描述统计上显著的目标。优先级最高的勘探区出现在b01-b02高点在断层交叉处重叠,局部与b06异常重合的地方。结果表明,CoBA与C-A分割相结合,为森林沼泽地形的远景制图提供了一种低成本、可解释的框架,减轻了封闭效应,增强了微弱但具有地质意义的决策信号。
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引用次数: 0
Assessing the evidence for active volcanism on Venus: current limitations and prospects for future investigations 评估金星上活火山活动的证据:目前的限制和未来调查的前景
IF 2.9 3区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-12-01 DOI: 10.1016/j.chemer.2025.126316
Justin Filiberto , Mikhail Yu. Zolotov , Erika Kohler , Piero D'Incecco , Dmitry A. Gorinov , Sriram S. Bhiravarasu , Matthew B. Weller , Jeremy F. Brossier , Iván López , Philippa J. Mason , Jemila A. Edmond , Nicola Mari , Goro Komatsu , Gaetano Di Achille , James B. Garvin
One of the biggest unknowns about Venus is how volcanically active it is today. Venus has a similar size and density to Earth, suggesting it may have a comparable composition, and therefore it is expected to be volcanically active; however, exploring Venus and confirming current volcanic activity is difficult because of the thick omnipresent optically opaque clouds that hamper traditional observations of the lower atmosphere and surface. Further, surface conditions make long-lived missions challenging. Despite the difficulty, there have been tantalizing hints of currently active or very recent volcanism. Here, we review what is known about active volcanism, point out gaps in knowledge to be addressed, and highlight techniques and approaches that need to be developed before the new decade of Venus exploration. It is crucial to constrain the activity and rate of volcanism today and through time to begin to understand the geodynamic state of the planet.
We find that the combination of all evidence strongly indicates that Venus is volcanically active today. The best evidence for active volcanism comes from combining data sets and approaches – specifically at Idunn Mons, Maat Mons, and Aramaiti Corona – in contrast to those from a single study or data set alone. Considering the evidence for activity, observations do not favor so-called “catastrophic” models of resurfacing, instead they are better represented by ongoing regional scale events. To reliably detect and characterize active or recent effusive basaltic volcanism new missions must collect high-resolution imaging, repeat observations, radar polarimetry, evidence of outgassing, and high-resolution topographical data that provide insights into surface changes over time. The ability to capture and interpret these data is vital for understanding Venus's geological activity, particularly in regions where volcanic processes are suspected to be ongoing.
关于金星最大的未知之一是它今天的火山活动有多活跃。金星的大小和密度与地球相似,这表明它可能具有类似的成分,因此预计它会有火山活动;然而,探索金星并确认当前的火山活动是困难的,因为厚厚的无所不在的光学不透明云阻碍了对低层大气和表面的传统观测。此外,地表条件使长期任务具有挑战性。尽管困难重重,但仍有一些诱人的迹象表明,目前有活跃的火山活动,或者是最近的火山活动。在这里,我们回顾了关于活火山作用的已知情况,指出了需要解决的知识空白,并强调了在金星探索的新十年之前需要开发的技术和方法。限制今天的火山活动和速度,随着时间的推移,开始了解地球的地球动力学状态是至关重要的。我们发现,综合所有证据强有力地表明,金星今天的火山活动很活跃。活火山活动的最佳证据来自于综合数据集和方法,特别是在伊杜恩蒙斯、马特蒙斯和阿拉米蒂科罗纳,而不是单一的研究或数据集。考虑到活动的证据,观测结果并不支持所谓的“灾难性”重铺模型,相反,它们更适合于正在进行的区域尺度事件。为了可靠地探测和描述活跃的或近期喷发的玄武岩火山活动,新的任务必须收集高分辨率成像、重复观测、雷达偏振测量、脱气证据和高分辨率地形数据,这些数据可以提供对地表随时间变化的见解。捕捉和解释这些数据的能力对于了解金星的地质活动至关重要,特别是在那些被怀疑正在进行火山活动的地区。
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引用次数: 0
Petrogenesis of the Niancaowan mafic-ultramafic intrusion: Decoding magmatic evolution in the cuNi Metallogenic Province of the Bayan obo rift zone 年草湾基性-超基性侵入岩的岩石成因:解读巴彦鄂博裂谷带古尼成矿省岩浆演化
IF 2.9 3区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-12-01 DOI: 10.1016/j.chemer.2025.126359
Linna LI , Jiangang JIAO , Yunfei MA
The Niancaowan mafic-ultramafic intrusion is located within the Bayan Obo Rift Zone of central Inner Mongolia. Systematic genetic investigations were conducted in this study to clarify the genetic relationship between the Niancaowan mafic-ultramafic intrusion and known CuNi deposits within the rift zone, as well as to assess the comparability of their mineralization potential. Through integrated petrographic observations, high-precision geochronological dating, whole-rock geochemical analyses, and zircon Hf isotope tracing, the research specifically focused on elucidating the magmatic source characteristics, rock-forming timing, and magmatic evolutionary processes of the intrusion. The Niancaowan mafic-ultramafic intrusion is predominantly composed of hornblende gabbro and gabbro-diabase. LA-ICP-MS zircon UPb dating reveals that the hornblende gabbro crystallized during the Early Permian (273.2 ± 3.5 Ma), which demonstrates temporal synchronicity with the emplacement ages of other mafic-ultramafic intrusions within the central-western Inner Mongolia rift system. Geochemical tracers further disclose significant zircon Hf isotopic heterogeneity, indicating that the parental magma was derived from partial melting of a lithospheric mantle source and underwent contamination by lower crustal materials during its ascent. Comparative analysis indicates that the zircon Hf isotopic compositions of the Niancaowan intrusion (εHf(t) = −17.0 to +1.4) are similar to those of typical regional intrusions such as the Wulantaolegai and Huanghuatan intrusions, revealing that crustal contamination was prevalent during the emplacement of mafic-ultramafic magmatic systems within the Bayan Obo Rift Zone. The incorporation of such crust-derived components may be controlled by the melting or assimilation processes of ancient basement rocks in the extensional setting of the rift zone. The petrological characteristics and quantitative modeling results indicate that the Niancaowan intrusion experienced relatively weak crustal contamination (4 %–8 %). If sulfide mineralization were to occur in this intrusion, it would primarily depend on deep-seated magmatic differentiation. Comparative studies between the Niancaowan intrusion and other intrusive bodies within the Bayan Obo Rift Zone reveal that the mineral exploration potential of mafic-ultramafic intrusions in the Bayan Obo Rift Zone should not be overlooked. Particular attention should be given to highly contaminated mafic-ultramafic intrusion clusters within the rift zone and multi-stage tectonic-magmatic convergence nodes.
年草湾基性-超镁铁性岩体位于内蒙古中部白云鄂博裂谷带内。本文通过系统的成因研究,明确了年草湾基性-超基性岩体与裂谷带内已知CuNi矿床的成因关系,并评价了两者成矿潜力的可比性。通过综合岩石学观测、高精度年代学、全岩地球化学分析、锆石Hf同位素示踪等方法,重点阐明了该侵入岩的岩浆源特征、成岩时间和岩浆演化过程。年草湾基性超镁铁质侵入岩主要由角闪辉长岩和辉绿岩组成。LA-ICP-MS锆石UPb定年结果表明,角闪辉长岩的结晶时间为早二叠世(273.2±3.5 Ma),与内蒙古裂谷系中西部其他基性-超基性岩体的侵位年龄具有时间同向性。地球化学示踪剂进一步揭示了明显的锆石Hf同位素非均质性,表明母岩浆来源于岩石圈地幔源的部分熔融,并在上升过程中受到下地壳物质的污染。对比分析表明,年草湾岩体的锆石Hf同位素组成(εHf(t) = - 17.0 ~ +1.4)与乌兰陶乐盖、黄花滩等典型区域性岩体相似,表明在白云鄂博裂谷区内,基性-超基性岩浆体系侵位期间,地壳污染十分普遍。这种壳源成分的结合可能受古基底岩在裂谷带伸展背景下的熔融或同化作用的控制。岩石学特征和定量模拟结果表明,年草湾岩体受较弱的地壳污染(4% ~ 8%)。如果在该侵入岩中发生硫化物矿化,则主要依赖于深部岩浆分异。通过与白云鄂博裂谷带内其他侵入体的对比研究,表明白云鄂博裂谷带基性-超基性侵入体的找矿潜力不容忽视。应特别注意裂谷带内的高污染基性-超基性侵入群和多期构造-岩浆汇聚节点。
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Chemie Der Erde-Geochemistry
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