高钨含量Ni-W合金镀层的内应力

IF 2.4 4区 材料科学 Q3 MATERIALS SCIENCE, COATINGS & FILMS Surface Engineering Pub Date : 2023-06-03 DOI:10.1080/02670844.2023.2257855
Yingjun Xu, Deyong Wang, Minqi Sheng, Huihua Wang
{"title":"高钨含量Ni-W合金镀层的内应力","authors":"Yingjun Xu, Deyong Wang, Minqi Sheng, Huihua Wang","doi":"10.1080/02670844.2023.2257855","DOIUrl":null,"url":null,"abstract":"ABSTRACTThis study investigates the impact of current density on the microstructure, composition, and internal stress of Ni-W alloys electrodeposited in a citrate system. Using XRD, SEM, EDS, TEM, and XPS, it was found that tungsten serves as a solute in a Ni-W FCC structure oriented in the (111) direction. Increasing current density led to higher tungsten content and current efficiency. The addition of 2-Butyne-1,4-diol altered the carbon content, significantly reducing internal stress by promoting carbide formation near grain boundaries, which prevented coating shrinkage during hydrogen escape. This carbon enrichment improved the alloy's corrosion resistance.KEYWORDS: ElectrodepositionNi-W alloyinternal stresscarbon contenthigh tungsten contentnanocrystallineAmorphous materialsElectrochemical corrosion Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThis work was supported by National Natural Science Foundation of China: [Grant Number 52174280]; Science and Technology Support Program of Jiangsu Province: [Grant Number SYG202022].","PeriodicalId":21995,"journal":{"name":"Surface Engineering","volume":"10 1","pages":"0"},"PeriodicalIF":2.4000,"publicationDate":"2023-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Internal stress of high tungsten content Ni-W alloy coatings\",\"authors\":\"Yingjun Xu, Deyong Wang, Minqi Sheng, Huihua Wang\",\"doi\":\"10.1080/02670844.2023.2257855\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"ABSTRACTThis study investigates the impact of current density on the microstructure, composition, and internal stress of Ni-W alloys electrodeposited in a citrate system. Using XRD, SEM, EDS, TEM, and XPS, it was found that tungsten serves as a solute in a Ni-W FCC structure oriented in the (111) direction. Increasing current density led to higher tungsten content and current efficiency. The addition of 2-Butyne-1,4-diol altered the carbon content, significantly reducing internal stress by promoting carbide formation near grain boundaries, which prevented coating shrinkage during hydrogen escape. This carbon enrichment improved the alloy's corrosion resistance.KEYWORDS: ElectrodepositionNi-W alloyinternal stresscarbon contenthigh tungsten contentnanocrystallineAmorphous materialsElectrochemical corrosion Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThis work was supported by National Natural Science Foundation of China: [Grant Number 52174280]; Science and Technology Support Program of Jiangsu Province: [Grant Number SYG202022].\",\"PeriodicalId\":21995,\"journal\":{\"name\":\"Surface Engineering\",\"volume\":\"10 1\",\"pages\":\"0\"},\"PeriodicalIF\":2.4000,\"publicationDate\":\"2023-06-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Surface Engineering\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/02670844.2023.2257855\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, COATINGS & FILMS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Surface Engineering","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/02670844.2023.2257855","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, COATINGS & FILMS","Score":null,"Total":0}
引用次数: 0

摘要

摘要本文研究了电流密度对柠檬酸盐电沉积Ni-W合金显微组织、成分和内应力的影响。通过XRD、SEM、EDS、TEM和XPS分析发现,在Ni-W FCC(111)取向结构中,钨作为溶质存在。增大电流密度可提高钨含量和电流效率。2-丁烯-1,4-二醇的加入改变了碳含量,通过促进晶界附近碳化物的形成显著降低了内应力,从而防止了氢逸出时涂层的收缩。这种碳富集提高了合金的耐腐蚀性。关键词:电沉积ni - w合金内应力碳含量高钨含量纳米晶非晶材料电化学腐蚀披露声明作者未报告潜在利益冲突。本研究由国家自然科学基金资助:[批准号52174280];江苏省科技支撑计划项目[批准号:SYG202022]。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Internal stress of high tungsten content Ni-W alloy coatings
ABSTRACTThis study investigates the impact of current density on the microstructure, composition, and internal stress of Ni-W alloys electrodeposited in a citrate system. Using XRD, SEM, EDS, TEM, and XPS, it was found that tungsten serves as a solute in a Ni-W FCC structure oriented in the (111) direction. Increasing current density led to higher tungsten content and current efficiency. The addition of 2-Butyne-1,4-diol altered the carbon content, significantly reducing internal stress by promoting carbide formation near grain boundaries, which prevented coating shrinkage during hydrogen escape. This carbon enrichment improved the alloy's corrosion resistance.KEYWORDS: ElectrodepositionNi-W alloyinternal stresscarbon contenthigh tungsten contentnanocrystallineAmorphous materialsElectrochemical corrosion Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThis work was supported by National Natural Science Foundation of China: [Grant Number 52174280]; Science and Technology Support Program of Jiangsu Province: [Grant Number SYG202022].
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Surface Engineering
Surface Engineering 工程技术-材料科学:膜
CiteScore
5.60
自引率
14.30%
发文量
51
审稿时长
2.3 months
期刊介绍: Surface Engineering provides a forum for the publication of refereed material on both the theory and practice of this important enabling technology, embracing science, technology and engineering. Coverage includes design, surface modification technologies and process control, and the characterisation and properties of the final system or component, including quality control and non-destructive examination.
期刊最新文献
Examination of the metallization behaviour of an ABS surface Performance of electrochemically deposited hydroxyapatite on textured 316L SS for applications in biomedicine Vanadium promoted ZnO films: effects on optical and photocatalytic properties Preparation and frictional characteristics of solid lubrication coating on CFRP surface Laser surface texturing of dies in strip drawing of DP600 steel sheet
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1