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Oil-infused surface on galvanized iron pipes for anti-scaling in industrial applications 工业应用中用于防垢的镀锌铁管浸油表面
IF 2.4 4区 材料科学 Q3 MATERIALS SCIENCE, COATINGS & FILMS Pub Date : 2024-08-09 DOI: 10.1177/02670844241273528
Jiaojiao Bai, Chengxi Deng, Wenjuan Sun, Hua Dong
Scale deposition on the surface of pipelines is a common phenomenon in industrial production. It not only decreases the heat conduction efficiency of the pipeline and increases energy consumption, but also leads to corrosion of the pipeline. Although varieties methods are developed to prevent pipeline scale deposition, these methods could not meet the requirements of harsh production conditions. This study introduces a novel oil-infused surface on galvanized iron for efficient anti-scaling in industrial pipelines. The surface of galvanized iron is firstly oxidized and modified to be superhydrophobic/superoleophilic, followed by injection of oil to form oil-infused surface. This oil-infused superhydrophobic/superoleophilic surface demonstrates excellent water repellency and superior anti-scaling performance compared to untreated galvanized iron. It may provide a promising anti-scaling option for iron-based pipelines in industrial productions.
管道表面的水垢沉积是工业生产中的常见现象。它不仅会降低管道的热传导效率,增加能耗,还会导致管道腐蚀。虽然已有多种方法可以防止管道结垢沉积,但这些方法无法满足苛刻的生产条件要求。本研究介绍了一种新型的镀锌铁表面注油方法,可有效防止工业管道结垢。首先对镀锌铁表面进行氧化和改性,使其具有超疏水/超亲油性,然后注入油,形成注油表面。与未经处理的镀锌铁相比,这种注油的超疏水/超亲油表面具有出色的憎水性和卓越的防结垢性能。它可以为工业生产中的铁基管道提供一种前景广阔的防结垢选择。
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引用次数: 0
Surface modification of cotton 棉花表面改性
IF 2.4 4区 材料科学 Q3 MATERIALS SCIENCE, COATINGS & FILMS Pub Date : 2024-07-23 DOI: 10.1177/02670844241265803
L. Gopal, T.S. Sudarshan
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引用次数: 0
The evolution and future of polymer cold spray technology 聚合物冷喷技术的发展与未来
IF 2.4 4区 材料科学 Q3 MATERIALS SCIENCE, COATINGS & FILMS Pub Date : 2024-07-23 DOI: 10.1177/02670844241265801
L. Gopal, T.S. Sudarshan
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引用次数: 0
Surface modification of polyester fabrics using choline hydroxide-catalysed glycolysis 利用氢氧化胆碱催化糖酵解对聚酯织物进行表面改性
IF 2.4 4区 材料科学 Q3 MATERIALS SCIENCE, COATINGS & FILMS Pub Date : 2024-07-23 DOI: 10.1177/02670844241263606
Masoud Mostajeran, A. Khoddami, Peyman Mirloo, Amir Abdolmaleki
This study explores the surface modification of polyethene terephthalate (PET) fabric via glycolysis, employing choline hydroxide as an eco-friendly catalyst. A range of chemicals was evaluated for catalysing the glycolysis reaction. Among them, choline hydroxide demonstrated notable enhancements in surface hydrophilicity, moisture regain, wicking properties, and water contact angle, surpassing other catalysts. Scanning Electron Microscopy (SEM) revealed a marked increase in surface roughness and irregularities following glycolysis in the presence of this ionic liquid. The surface modification technique employed in this investigation resulted in a decrease of less than 20% in the breaking force of the fabric. Fourier Transform Infrared (FT-IR) spectroscopy and the methylene blue staining method confirmed the emergence of free hydroxyl groups on the modified fabric's surface. These findings suggest that glycolysis catalysed by choline hydroxide is a promising approach for enhancing the surface characteristics of polyester fabrics, which may lead to improved functional properties in textile applications.
本研究采用氢氧化胆碱作为环保催化剂,探索通过乙二醇反应对聚对苯二甲酸乙二酯(PET)织物进行表面改性。研究评估了一系列用于催化乙二醇反应的化学品。其中,氢氧化胆碱在表面亲水性、回潮性、吸湿性和水接触角方面都有显著提高,超过了其他催化剂。扫描电子显微镜(SEM)显示,在这种离子液体的存在下,乙二醇的表面粗糙度和不规则性明显增加。这项研究采用的表面改性技术使织物的断裂力降低了不到 20%。傅立叶变换红外光谱(FT-IR)和亚甲基蓝染色法证实了改性织物表面游离羟基的出现。这些研究结果表明,氢氧化胆碱催化的糖酵解是增强聚酯织物表面特性的一种很有前景的方法,可改善织物应用的功能特性。
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引用次数: 0
A novel approach of thick coating through selective jet electrodeposition process 通过选择性喷射电沉积工艺实现厚涂层的新方法
IF 2.8 4区 材料科学 Q2 Physics and Astronomy Pub Date : 2024-06-11 DOI: 10.1177/02670844241258711
Anand Mohan Pandey, S. Kapil, Manas Das
Selective Jet Electrodeposition (SJED) emerges as a cutting-edge Additive Manufacturing technology, offering the ability to produce metallic components at both nano and micro scales. In SJED, metallic deposition occurs atom by atom, showcasing potential applications for electroplating (coating) purposes. Achieving a smooth and void-free coating necessitates optimisation of layer height, width and the centre distance between two adjacent beads. An ANOVA study is performed to identify the most impactful input process parameters among source voltage, scan speed and frequency. It evaluates their contribution to the output responses (layer height and width). Furthermore, Response Surface Methodology is performed to obtain the optimal parameters to achieve maximum layer height and minimum layer width. Additionally, multi-bead optimisation is performed to achieve a flat surface condition. Subsequently, a coating is carried out using a toolpath, and a comparative analysis is conducted with the conventional coating method in terms of mechanical properties. The SJED-based coating exhibits superior characteristics compared to conventional coating.
选择性喷射电沉积(SJED)是一种尖端的增材制造技术,能够生产纳米和微米尺度的金属部件。在 SJED 中,金属沉积是以原子为单位进行的,这为电镀(涂层)用途提供了潜在的应用前景。要获得光滑无空隙的涂层,必须优化层高、宽度和相邻两珠之间的中心距。通过方差分析研究,确定了源电压、扫描速度和频率中影响最大的输入工艺参数。该研究评估了这些参数对输出响应(层高和宽度)的贡献。此外,还采用了响应面法(Response Surface Methodology)来获得最佳参数,以实现最大层高和最小层宽。此外,还进行了多珠优化,以实现平整的表面条件。随后,使用工具路径进行了涂层,并就机械性能与传统涂层方法进行了对比分析。与传统涂层相比,基于 SJED 的涂层表现出更优越的特性。
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引用次数: 0
Surface modification of synthetic polymer fibers 合成聚合物纤维的表面改性
IF 2.8 4区 材料科学 Q2 Physics and Astronomy Pub Date : 2024-06-06 DOI: 10.1177/02670844241259223
L. Gopal, T.S. Sudarshan
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引用次数: 0
Characterisation of laser-cladded 410 stainless steel for in situ repair of turbine blade 用于涡轮叶片原位修复的激光包覆 410 不锈钢的特性分析
IF 2.8 4区 材料科学 Q2 Physics and Astronomy Pub Date : 2024-06-06 DOI: 10.1177/02670844241259724
Dhiraj Raj, S. Maity, Bipul Das
Laser cladding was employed to apply a pure nickel powder coating onto 410 stainless steel turbine blade material, utilising a 50 W pulsed diode fibre laser system. Various process parameters were explored, including average laser power (20 W, 30 W, 40 W) and scanning speeds (SSs) (0.5 mm/s, 1 mm/s, 1.5 mm/s). The pulse width and frequency were fixed to 110 ns and 50 kHz, respectively. Successful deposition of nickel powder was accomplished at an average power of 40 W at various SSs. The microstructure, phase components, clad geometry, tensile properties, and microhardness of cladded specimens were examined. The experimental results show that the cladding layer has a metallurgical bonding with the substrate, having a visual interface with no cracks or defects. The clad layer's height peaked at 1 mm/s (175.889 μm), while the maximum clad depth occurred at 0.5 mm/s (367.797 μm). Predominant intermetallic phases observed included FeNi3, Cr1.36Fe0.52, along with fine carbides (M3C, M7C3, M23C6 where M – Fe, Ni). Enhanced mechanical properties were observed in the cladded samples compared to the substrate. At 1 mm/s SS, the clad zone exhibited the highest microhardness (221.4 HV), tensile strength (482.03 MPa), and Young's modulus (17.97 GPa).
利用 50 W 脉冲二极管光纤激光系统,在 410 不锈钢涡轮叶片材料上进行激光熔覆纯镍粉涂层。对各种工艺参数进行了研究,包括平均激光功率(20 W、30 W、40 W)和扫描速度(SSs)(0.5 mm/s、1 mm/s、1.5 mm/s)。脉冲宽度和频率分别固定为 110 ns 和 50 kHz。在平均功率为 40 W、不同 SS 的条件下,镍粉沉积成功。对熔覆试样的微观结构、相成分、熔覆几何形状、拉伸性能和显微硬度进行了检测。实验结果表明,熔覆层与基体之间具有冶金结合,具有无裂纹或缺陷的可视界面。熔覆层高度在 1 mm/s 时达到峰值(175.889 μm),而最大熔覆深度出现在 0.5 mm/s 时(367.797 μm)。观察到的主要金属间相包括 FeNi3、Cr1.36Fe0.52 以及细碳化物(M3C、M7C3、M23C6,其中 M - Fe、Ni)。与基体相比,包覆样品的机械性能有所提高。在 1 mm/s SS 条件下,包覆区显示出最高的显微硬度(221.4 HV)、抗拉强度(482.03 MPa)和杨氏模量(17.97 GPa)。
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引用次数: 0
A state-of-the-art review on electrodeposited metal matrix composite coatings: recent innovations and challenges 电沉积金属基复合材料涂层最新进展综述:最新创新与挑战
IF 2.8 4区 材料科学 Q2 Physics and Astronomy Pub Date : 2024-06-05 DOI: 10.1177/02670844241258703
Mohsen Mesbah, S. Yazdani, V. Vitry
Metal-matrix electrodeposited composite coatings with specific characteristics have garnered increasing interest from researchers and businesses across diverse industries, including aerospace, automotive, marine, electrical, and wind energy. This comprehensive review critically examines the key challenges involved in fabricating these coatings through composite electrodeposition. It explores a range of deposition methods, techniques for modifying particle surfaces, different types of metal matrix composites, the impact of various parameters on composite electrodeposition, approaches to enhance particle stability, and the influence of bath parameters on coatings’ microstructure. The review thoroughly analyzes the advantages and limitations associated with each topic, providing insights into the underlying mechanisms for creating coatings with well-dispersed particles. Furthermore, it highlights recent advancements and presents promising opportunities for future research, aiming to expand the scope of applications for composite electrodeposited coatings.
航空航天、汽车、船舶、电气和风能等各行各业的研究人员和企业对具有特殊性能的金属基质电沉积复合涂层的兴趣与日俱增。这篇综合性综述批判性地探讨了通过复合电沉积制造这些涂层所面临的主要挑战。它探讨了一系列沉积方法、颗粒表面改性技术、不同类型的金属基复合材料、各种参数对复合电沉积的影响、提高颗粒稳定性的方法以及镀槽参数对涂层微观结构的影响。综述全面分析了与每个主题相关的优势和局限性,深入探讨了创造具有良好分散颗粒的涂层的基本机制。此外,文章还重点介绍了最近的研究进展,并为未来的研究提供了大有可为的机会,旨在扩大复合电沉积涂层的应用范围。
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引用次数: 0
Surface modification of poly (ethylene terephthalate) using imidazolium-based ionic liquids 使用咪唑基离子液体对聚对苯二甲酸乙二醇酯进行表面改性
IF 2.8 4区 材料科学 Q2 Physics and Astronomy Pub Date : 2024-06-05 DOI: 10.1177/02670844241258706
Bita Nouri, A. Khoddami, Masoud Mostajeran, Farzaneh Alihosseini
Ionic liquids (ILs), with their unique characteristics, are widely known as new alternatives for solvents and catalysts used in various chemical reactions. Due to their extensive range of applications and environmental compatibility, they are suitable options for treating fibrous substrates. In this regard, this paper focuses on investigating the possibility of poly (ethylene terephthalate) surface modification via imidazolium-based ILs. Surface modification was carried out under different process conditions by varying the temperature and the catalyst. The possibility of treating samples in the IL solution for the second time was also examined. Moreover, the effect of the modification on the dyeing of polyester with disperse dye without carrier at 100 °C was studied. The samples’ wettability properties were investigated through several test methods by measuring vertical wicking height, wetting time, drop contact angle, surface resistivity and absorption of methylene blue dye. The chemical and physical changes of the modified samples were also evaluated via scanning electron microscopy images, Fourier-transform infrared spectroscopy (FTIR) spectra and mechanical tests. Results demonstrate that treatment with [BMIM]Cl and [BMIM]Br induces morphological changes on the fibre surface, creating grooves and voids. FTIR analysis and Methylene blue staining test confirm the formation of hydroxyl and carboxyl groups, enhancing the fabric's hydrophilicity and dyeability. Wettability tests reveal that increased water absorption leads to reduced electrical resistivity. Mechanical tests indicate a slight reduction in tensile strength attributed to surface roughness.
离子液体(IL)以其独特的特性被广泛认为是用于各种化学反应的溶剂和催化剂的新替代品。由于其广泛的应用范围和环境兼容性,它们是处理纤维基质的合适选择。为此,本文重点研究了通过咪唑基 IL 对聚对苯二甲酸乙二醇酯进行表面改性的可能性。通过改变温度和催化剂,在不同的工艺条件下进行了表面改性。此外,还考察了在 IL 溶液中对样品进行二次处理的可能性。此外,还研究了改性对 100 °C 下无载体分散染料涤纶染色的影响。通过测量垂直吸水高度、润湿时间、液滴接触角、表面电阻率和亚甲基蓝染料吸收率,采用多种测试方法研究了样品的润湿性能。此外,还通过扫描电子显微镜图像、傅立叶变换红外光谱和机械测试评估了改性样品的化学和物理变化。结果表明,用[BMIM]Cl 和 [BMIM]Br 处理会引起纤维表面的形态变化,产生沟槽和空隙。傅立叶变换红外分析和亚甲蓝染色测试证实,羟基和羧基的形成增强了织物的亲水性和染色性。润湿性测试表明,吸水性的增加会导致电阻率的降低。机械测试表明,由于表面粗糙,拉伸强度略有降低。
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引用次数: 0
Study on the thermal insulation property of lanthanum–cerium oxide coatings 氧化镧铈涂层的隔热性能研究
IF 2.8 4区 材料科学 Q2 Physics and Astronomy Pub Date : 2024-05-24 DOI: 10.1177/02670844241255791
S. Zeng, Zhoufu Wang, Yan Ma, Hao Liu, Xitang Wang
Functional fillers with low thermal conductivity and high near-infrared reflectance play a vital role in high temperature thermal insulation coatings and make an outstanding contribution to achieving efficient comprehensive thermal insulation. In this work, the thermal insulation and bonding properties of lanthanum–cerium oxide (LCO) coatings were regulated by composition design. The effects of the La/Ce mole ratio on phase composition, the thermal conductivity and near-infrared reflectivity of LCO coatings were investigated systematically. The results showed that coating with a La/Ce mole ratio of 1:1 possess the excellent thermal insulation properties (ΔT ≈ 115°C) due to the formation of a LCO solid solution and a lanthanum phosphate mesophase with low thermal conductivity and high near-infrared reflectivity. In addition, the mortise and tenon structure was formed between the coating and the substrate, which led to the remarkable bonding properties. The LCO coating offers excellent thermal insulation properties and broad application prospects in the fields of high temperature and energy conservation.
具有低热导率和高近红外反射率的功能填料在高温隔热涂料中发挥着重要作用,为实现高效的全面隔热做出了突出贡献。本研究通过成分设计来调节氧化镧铈(LCO)涂层的隔热性能和粘结性能。系统研究了 La/Ce 摩尔比对 LCO 涂层相组成、热导率和近红外反射率的影响。结果表明,La/Ce 摩尔比为 1:1 的涂层具有优异的隔热性能(ΔT ≈ 115°C),这是由于形成了 LCO 固溶体和具有低导热率和高近红外反射率的磷酸镧介相。此外,涂层与基材之间形成了榫卯结构,从而产生了显著的粘合性能。LCO 涂层具有优异的隔热性能,在高温和节能领域具有广阔的应用前景。
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引用次数: 0
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Surface Engineering
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