{"title":"磁控溅射中放电电流调制提高TC4合金基体上CrN涂层的附着力","authors":"Shuai Xu, Zhuo Zhao, Yanwen Zhou, Kaice Zhang","doi":"10.1080/02670844.2023.2257359","DOIUrl":null,"url":null,"abstract":"ABSTRACTThe study reports the formation of multilayer coatings of CrN with variable gradient modulus on TC4 substrate by varying the discharge current of the hot filament in magnetron sputtering. Results show that multilayer CrN/TC4 has a higher critical failure load (63.4 N > 29.7 N), lower maximum tensile stress (103.8 GPa < 134.3 GPa), and a higher ratio of plastic to elastic deformation work (Wp/We, 2.11 > 1.58) than a single layer CrN/TC4. This indicates that the energy absorption ability of the coating/substrate before failure can be improved by increasing the loose energy-absorbing sublayer, thus improving the coating/substrate adhesion. Notably, the wear rate of both multilayer and single-layer coatings is in the order of 10−16 m3/(N·m), demonstrating their excellent wear resistance. Structural engineering enables the application of multilayer CrN coatings on low-modulus and high-strength alloy substrates, such as TC4.HIGHLIGHTS A dense-porous multilayer coating obtained by varying the filament discharge currents.The modulus difference between the multilayer CrN and TC4 reduced.The maximum tensile stress appeared at the interface of the Cr and CrN layers.The multilayer CrN/TC4 with high Wp/We and absorption ability of deformation work.The multilayer CrN/TC4 was with high adhesion and excellent wear resistance.KEYWORDS: Structure engineeringmagnetron sputteringdischarge currentsmultilayer coatingalloy substratesimulationadhesionmodulus Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThis work was supported by National Natural Science Foundation of China [grant number 51972155 and 52271056]; Foundation of Liaoning Educational Administration [grant number LJKZ0278 and LJKZ0306].","PeriodicalId":21995,"journal":{"name":"Surface Engineering","volume":"13 1","pages":"0"},"PeriodicalIF":2.4000,"publicationDate":"2023-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Improving the adhesion of CrN coatings on TC4 alloy substrates by discharge current modulation in magnetron sputtering\",\"authors\":\"Shuai Xu, Zhuo Zhao, Yanwen Zhou, Kaice Zhang\",\"doi\":\"10.1080/02670844.2023.2257359\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"ABSTRACTThe study reports the formation of multilayer coatings of CrN with variable gradient modulus on TC4 substrate by varying the discharge current of the hot filament in magnetron sputtering. Results show that multilayer CrN/TC4 has a higher critical failure load (63.4 N > 29.7 N), lower maximum tensile stress (103.8 GPa < 134.3 GPa), and a higher ratio of plastic to elastic deformation work (Wp/We, 2.11 > 1.58) than a single layer CrN/TC4. This indicates that the energy absorption ability of the coating/substrate before failure can be improved by increasing the loose energy-absorbing sublayer, thus improving the coating/substrate adhesion. Notably, the wear rate of both multilayer and single-layer coatings is in the order of 10−16 m3/(N·m), demonstrating their excellent wear resistance. Structural engineering enables the application of multilayer CrN coatings on low-modulus and high-strength alloy substrates, such as TC4.HIGHLIGHTS A dense-porous multilayer coating obtained by varying the filament discharge currents.The modulus difference between the multilayer CrN and TC4 reduced.The maximum tensile stress appeared at the interface of the Cr and CrN layers.The multilayer CrN/TC4 with high Wp/We and absorption ability of deformation work.The multilayer CrN/TC4 was with high adhesion and excellent wear resistance.KEYWORDS: Structure engineeringmagnetron sputteringdischarge currentsmultilayer coatingalloy substratesimulationadhesionmodulus Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThis work was supported by National Natural Science Foundation of China [grant number 51972155 and 52271056]; Foundation of Liaoning Educational Administration [grant number LJKZ0278 and LJKZ0306].\",\"PeriodicalId\":21995,\"journal\":{\"name\":\"Surface Engineering\",\"volume\":\"13 1\",\"pages\":\"0\"},\"PeriodicalIF\":2.4000,\"publicationDate\":\"2023-06-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Surface Engineering\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/02670844.2023.2257359\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, COATINGS & FILMS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Surface Engineering","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/02670844.2023.2257359","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, COATINGS & FILMS","Score":null,"Total":0}
Improving the adhesion of CrN coatings on TC4 alloy substrates by discharge current modulation in magnetron sputtering
ABSTRACTThe study reports the formation of multilayer coatings of CrN with variable gradient modulus on TC4 substrate by varying the discharge current of the hot filament in magnetron sputtering. Results show that multilayer CrN/TC4 has a higher critical failure load (63.4 N > 29.7 N), lower maximum tensile stress (103.8 GPa < 134.3 GPa), and a higher ratio of plastic to elastic deformation work (Wp/We, 2.11 > 1.58) than a single layer CrN/TC4. This indicates that the energy absorption ability of the coating/substrate before failure can be improved by increasing the loose energy-absorbing sublayer, thus improving the coating/substrate adhesion. Notably, the wear rate of both multilayer and single-layer coatings is in the order of 10−16 m3/(N·m), demonstrating their excellent wear resistance. Structural engineering enables the application of multilayer CrN coatings on low-modulus and high-strength alloy substrates, such as TC4.HIGHLIGHTS A dense-porous multilayer coating obtained by varying the filament discharge currents.The modulus difference between the multilayer CrN and TC4 reduced.The maximum tensile stress appeared at the interface of the Cr and CrN layers.The multilayer CrN/TC4 with high Wp/We and absorption ability of deformation work.The multilayer CrN/TC4 was with high adhesion and excellent wear resistance.KEYWORDS: Structure engineeringmagnetron sputteringdischarge currentsmultilayer coatingalloy substratesimulationadhesionmodulus Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThis work was supported by National Natural Science Foundation of China [grant number 51972155 and 52271056]; Foundation of Liaoning Educational Administration [grant number LJKZ0278 and LJKZ0306].
期刊介绍:
Surface Engineering provides a forum for the publication of refereed material on both the theory and practice of this important enabling technology, embracing science, technology and engineering. Coverage includes design, surface modification technologies and process control, and the characterisation and properties of the final system or component, including quality control and non-destructive examination.