{"title":"胶粘剂组合物中聚合物间黏附-内聚相互作用的研究","authors":"Darina ZHELEVA, Rashko DIMITROV","doi":"10.24264/lfj.23.1.4","DOIUrl":null,"url":null,"abstract":"The results of the research prove that adhesives based on chloroprene rubber can be obtained not only in combination with phenol-formaldehyde resins, but also with other polymers. Selected chlorobutyl rubber (CIIR) and high styrene rubber (KER) proved to be substitutes for phenolic resins, which were used to obtain adhesive compositions with good properties. Despite the existing opinion on the same polarity of the components of the adhesive composition, guaranteeing the most favorable properties, it was shown that compositions with different polarity have all the parameters of quality adhesives. Components with different polarity also show the effect of mutual reinforcement, which determines the alignment, orientation ability of macromolecular chains and occurrence of cohesion and adhesion interactions. The observed textures obtained after mechanical impact proved this claim. Adhesives with more developed textures have better adhesive properties. The selected research methods successfully predict the properties of the components and facilitate their selection and amount.","PeriodicalId":38857,"journal":{"name":"Leather and Footwear Journal","volume":"20 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2023-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Study of Adhesion-Cohesion Interactions between Polymers in Adhesive Compositions\",\"authors\":\"Darina ZHELEVA, Rashko DIMITROV\",\"doi\":\"10.24264/lfj.23.1.4\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The results of the research prove that adhesives based on chloroprene rubber can be obtained not only in combination with phenol-formaldehyde resins, but also with other polymers. Selected chlorobutyl rubber (CIIR) and high styrene rubber (KER) proved to be substitutes for phenolic resins, which were used to obtain adhesive compositions with good properties. Despite the existing opinion on the same polarity of the components of the adhesive composition, guaranteeing the most favorable properties, it was shown that compositions with different polarity have all the parameters of quality adhesives. Components with different polarity also show the effect of mutual reinforcement, which determines the alignment, orientation ability of macromolecular chains and occurrence of cohesion and adhesion interactions. The observed textures obtained after mechanical impact proved this claim. Adhesives with more developed textures have better adhesive properties. The selected research methods successfully predict the properties of the components and facilitate their selection and amount.\",\"PeriodicalId\":38857,\"journal\":{\"name\":\"Leather and Footwear Journal\",\"volume\":\"20 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-03-31\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Leather and Footwear Journal\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.24264/lfj.23.1.4\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"Engineering\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Leather and Footwear Journal","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.24264/lfj.23.1.4","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"Engineering","Score":null,"Total":0}
Study of Adhesion-Cohesion Interactions between Polymers in Adhesive Compositions
The results of the research prove that adhesives based on chloroprene rubber can be obtained not only in combination with phenol-formaldehyde resins, but also with other polymers. Selected chlorobutyl rubber (CIIR) and high styrene rubber (KER) proved to be substitutes for phenolic resins, which were used to obtain adhesive compositions with good properties. Despite the existing opinion on the same polarity of the components of the adhesive composition, guaranteeing the most favorable properties, it was shown that compositions with different polarity have all the parameters of quality adhesives. Components with different polarity also show the effect of mutual reinforcement, which determines the alignment, orientation ability of macromolecular chains and occurrence of cohesion and adhesion interactions. The observed textures obtained after mechanical impact proved this claim. Adhesives with more developed textures have better adhesive properties. The selected research methods successfully predict the properties of the components and facilitate their selection and amount.