{"title":"东达瓦尔克拉通阿穆尔花岗岩的地球化学和矿物化学:对氧化还原条件和构造-岩浆环境的影响","authors":"A. Ajay Kumar, Ch. Ashok","doi":"10.1007/s11631-023-00647-1","DOIUrl":null,"url":null,"abstract":"<div><p>The mineralogical and geochemical characteristics of the K-rich granites from the Armoor granitic rocks in the northeastern portion of the Eastern Dharwar Craton (EDC) are presented. In order to understand its physicochemical conditions, the petrogenesis of the granitoid was explained from biotite chemistry and geochemical systematics. Studies of mineral chemistry expose that compositionally, K-feldspar and plagioclase in Armoor granite rocks range from An<sub>0,</sub> Ab<sub>3−5.9,</sub> Or<sub>94−96.9</sub> and An<sub>5−29, Ab71.9−94.9,</sub> Or<sub>0−1.5,</sub> respectively. The mineral chemistry of biotite crystals exhibits composition that varies from primary to re-equilibrated primary biotites. Although biotites from the Armoor granites generally exhibit an I-type trend, with calc-alkaline parental magma in a subduction setting. Biotite chemistry of granites displays magnetite (oxidized) series nature, which has oxygen fugacity (<i>f</i>O<sub>2)</sub> = − 15.1 to − 16.7(log<sub>10</sub> bar), under high oxidizing conditions. Temperature and pressure estimates for the crystallization of Armoor granites based on biotite composition are T = 612–716 °C and 1.0−0.4 kbar, respectively. Geochemically, these rocks are metaluminous to slightly peraluminous and magnesian, with calc-alkaline potassium-rich granite. On the chondrite normalized REE diagram, the granites have positive europium anomalies; rich Sr/Y, (Dy/Yb)<sub>N</sub> ratios and reduced Mg<sup>#</sup>, Rb/Sr, Rb, Sr indicate that the melting of earlier rocks, crystal accumulation and residual garnet source formed at high pressures. The examined granites show that they are produced from the melting of crustal sources. Thus, the extensive analyses of the described Armoor granite suggest that they were produced by crust sources and developed under oxidizing conditions in subduction setting.</p></div>","PeriodicalId":7151,"journal":{"name":"Acta Geochimica","volume":"43 1","pages":"110 - 133"},"PeriodicalIF":1.4000,"publicationDate":"2023-11-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Geochemistry and mineral chemistry of the armoor granitoids, eastern dharwar craton: implications for the redox conditions and tectono-magmatic environment\",\"authors\":\"A. Ajay Kumar, Ch. Ashok\",\"doi\":\"10.1007/s11631-023-00647-1\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The mineralogical and geochemical characteristics of the K-rich granites from the Armoor granitic rocks in the northeastern portion of the Eastern Dharwar Craton (EDC) are presented. In order to understand its physicochemical conditions, the petrogenesis of the granitoid was explained from biotite chemistry and geochemical systematics. Studies of mineral chemistry expose that compositionally, K-feldspar and plagioclase in Armoor granite rocks range from An<sub>0,</sub> Ab<sub>3−5.9,</sub> Or<sub>94−96.9</sub> and An<sub>5−29, Ab71.9−94.9,</sub> Or<sub>0−1.5,</sub> respectively. The mineral chemistry of biotite crystals exhibits composition that varies from primary to re-equilibrated primary biotites. Although biotites from the Armoor granites generally exhibit an I-type trend, with calc-alkaline parental magma in a subduction setting. Biotite chemistry of granites displays magnetite (oxidized) series nature, which has oxygen fugacity (<i>f</i>O<sub>2)</sub> = − 15.1 to − 16.7(log<sub>10</sub> bar), under high oxidizing conditions. Temperature and pressure estimates for the crystallization of Armoor granites based on biotite composition are T = 612–716 °C and 1.0−0.4 kbar, respectively. Geochemically, these rocks are metaluminous to slightly peraluminous and magnesian, with calc-alkaline potassium-rich granite. On the chondrite normalized REE diagram, the granites have positive europium anomalies; rich Sr/Y, (Dy/Yb)<sub>N</sub> ratios and reduced Mg<sup>#</sup>, Rb/Sr, Rb, Sr indicate that the melting of earlier rocks, crystal accumulation and residual garnet source formed at high pressures. The examined granites show that they are produced from the melting of crustal sources. 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引用次数: 0
摘要
本文介绍了东达瓦尔克拉通(EDC)东北部阿穆尔花岗岩中富钾花岗岩的矿物学和地球化学特征。为了了解其物理化学条件,从生物岩化学和地球化学系统学解释了花岗岩的成岩过程。矿物化学研究表明,阿穆尔花岗岩中的K长石和斜长石成分范围分别为An0, Ab3-5.9, Or94-96.9和An5-29, Ab71.9-94.9, Or0-1.5。生物岩晶体的矿物化学成分从原生生物岩到再平衡原生生物岩各不相同。虽然阿穆尔花岗岩中的生物岩一般呈现 I 型趋势,但其母岩岩浆为俯冲环境中的钙碱性岩浆。花岗岩的生物岩化学成分显示出磁铁矿(氧化)系列性质,在高氧化条件下,其氧富集度(fO2)= - 15.1 至 - 16.7(log10 bar)。根据生物岩成分估算的阿穆尔花岗岩结晶温度和压力分别为 T = 612-716 °C 和 1.0-0.4 千巴。从地球化学角度看,这些岩石为金属铝质至轻微高铝质和镁质,富含钙碱钾花岗岩。在软玉归一化 REE 图上,这些花岗岩具有正的铕异常;丰富的 Sr/Y、(Dy/Yb)N 比率和减少的 Mg#、Rb/Sr、Rb、Sr 表明,早期岩石的熔融、晶体堆积和残余石榴石源是在高压下形成的。所研究的花岗岩表明,它们是由地壳源熔化产生的。因此,对所述阿穆尔花岗岩进行的大量分析表明,它们是由地壳源产生的,并在俯冲环境中的氧化条件下形成。
Geochemistry and mineral chemistry of the armoor granitoids, eastern dharwar craton: implications for the redox conditions and tectono-magmatic environment
The mineralogical and geochemical characteristics of the K-rich granites from the Armoor granitic rocks in the northeastern portion of the Eastern Dharwar Craton (EDC) are presented. In order to understand its physicochemical conditions, the petrogenesis of the granitoid was explained from biotite chemistry and geochemical systematics. Studies of mineral chemistry expose that compositionally, K-feldspar and plagioclase in Armoor granite rocks range from An0, Ab3−5.9, Or94−96.9 and An5−29, Ab71.9−94.9, Or0−1.5, respectively. The mineral chemistry of biotite crystals exhibits composition that varies from primary to re-equilibrated primary biotites. Although biotites from the Armoor granites generally exhibit an I-type trend, with calc-alkaline parental magma in a subduction setting. Biotite chemistry of granites displays magnetite (oxidized) series nature, which has oxygen fugacity (fO2) = − 15.1 to − 16.7(log10 bar), under high oxidizing conditions. Temperature and pressure estimates for the crystallization of Armoor granites based on biotite composition are T = 612–716 °C and 1.0−0.4 kbar, respectively. Geochemically, these rocks are metaluminous to slightly peraluminous and magnesian, with calc-alkaline potassium-rich granite. On the chondrite normalized REE diagram, the granites have positive europium anomalies; rich Sr/Y, (Dy/Yb)N ratios and reduced Mg#, Rb/Sr, Rb, Sr indicate that the melting of earlier rocks, crystal accumulation and residual garnet source formed at high pressures. The examined granites show that they are produced from the melting of crustal sources. Thus, the extensive analyses of the described Armoor granite suggest that they were produced by crust sources and developed under oxidizing conditions in subduction setting.
期刊介绍:
Acta Geochimica serves as the international forum for essential research on geochemistry, the science that uses the tools and principles of chemistry to explain the mechanisms behind major geological systems such as the Earth‘s crust, its oceans and the entire Solar System, as well as a number of processes including mantle convection, the formation of planets and the origins of granite and basalt. The journal focuses on, but is not limited to the following aspects:
• Cosmochemistry
• Mantle Geochemistry
• Ore-deposit Geochemistry
• Organic Geochemistry
• Environmental Geochemistry
• Computational Geochemistry
• Isotope Geochemistry
• NanoGeochemistry
All research articles published in this journal have undergone rigorous peer review. In addition to original research articles, Acta Geochimica publishes reviews and short communications, aiming to rapidly disseminate the research results of timely interest, and comprehensive reviews of emerging topics in all the areas of geochemistry.