用于海洋脂质提取的疏水性天然深共晶溶剂

IF 1.9 4区 农林科学 Q3 CHEMISTRY, APPLIED Journal of the American Oil Chemists Society Pub Date : 2023-10-11 DOI:10.1002/aocs.12757
Taylan Topal, Asli Card, Andrew D. Mackenzie, Kirill Lagutin, Susan N. Marshall, Adam H. Cumming, Daniel P. Killeen
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引用次数: 0

摘要

第五类 "天然深共晶溶剂(TV NADES)是一类新型溶剂介质,具有许多潜在的 "绿色化学 "应用。在这里,我们评估了两种 TV NADES 的潜力:薄荷醇:香芹酚(M:C)和薄荷醇:百里酚(M:T),以及单一萜类提取介质香芹酚(C),作为介质对三种成分不同的冻干海洋组织进行总脂质提取的潜力,这三种海洋组织分别是梭子蟹(Macruronus novaezelandaiae)、竹荚鱼(Trachurus declivis)和绿唇贻贝(kuku, Perna canaliculus)。这些培养基的室温萃取率与氯仿-甲醇-水萃取的脂质萃取率进行了比较。使用 M:C 和 M:T 培养基的相对萃取率分别为:鲭鱼 87%、鳕鱼 85%-87%、绿唇贻贝 43%-47%。对 TV NADES 脂质提取物进行的综合化学分析表明,中性脂质的提取率高于磷脂,磷脂酰肌醇、溶血磷脂和(贻贝)神经酰胺乙基膦酸盐对 C、M:C 和 M:T 的提取特别敏感。C--一种百里酚异构体,与薄荷醇和百里酚不同,在室温下呈液态--似乎比 M:C 和 M:T 系统的性能要好(稍好),这意味着使用 TV NADES 可能比使用化学性质相似的单一萜类化合物提取总脂质没有优势。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Hydrophobic natural deep eutectic solvents for marine lipid extraction

‘Type V' natural deep eutectic solvents (TV NADES) are a novel class of solvent media with many potential ‘green chemistry’ applications. Here, we assess the potential of two TV NADES: menthol:carvacrol (M:C) and menthol:thymol (M:T), and a single terpenoid extraction media carvacrol (C), as media from total lipid extraction of three compositionally diverse, freeze-dried marine tissues: hoki (Macruronus novaezelandaiae), jack mackerel (Trachurus declivis) and green-lipped mussel (kuku, Perna canaliculus). Room temperature extraction yields into these media were benchmarked relative to lipid yields from chloroform-methanol-water extractions. Relative extraction yields using the M:C and M:T media were (both) 87% for jack mackerel, 85%–87% for hoki, and 43%–47% for green-lipped mussels. Comprehensive chemical analyses of TV NADES lipid extracts suggested that neutral lipids were extracted in greater yield than phospholipids, and that phosphatidylinositol, lysophospholipids and (in the case of mussels) ceramideaminoethylphosphonates were particularly resistant to extraction into C, M:C and M:T. C—a thymol isomer that, unlike menthol and thymol is a liquid at room temperature—appeared to perform (marginally) better than M:C and M:T systems, implying there may be no advantage to using the TV NADES over a single terpenoid with similar chemistry for total lipid extraction.

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来源期刊
CiteScore
4.10
自引率
5.00%
发文量
95
审稿时长
2.4 months
期刊介绍: The Journal of the American Oil Chemists’ Society (JAOCS) is an international peer-reviewed journal that publishes significant original scientific research and technological advances on fats, oils, oilseed proteins, and related materials through original research articles, invited reviews, short communications, and letters to the editor. We seek to publish reports that will significantly advance scientific understanding through hypothesis driven research, innovations, and important new information pertaining to analysis, properties, processing, products, and applications of these food and industrial resources. Breakthroughs in food science and technology, biotechnology (including genomics, biomechanisms, biocatalysis and bioprocessing), and industrial products and applications are particularly appropriate. JAOCS also considers reports on the lipid composition of new, unique, and traditional sources of lipids that definitively address a research hypothesis and advances scientific understanding. However, the genus and species of the source must be verified by appropriate means of classification. In addition, the GPS location of the harvested materials and seed or vegetative samples should be deposited in an accredited germplasm repository. Compositional data suitable for Original Research Articles must embody replicated estimate of tissue constituents, such as oil, protein, carbohydrate, fatty acid, phospholipid, tocopherol, sterol, and carotenoid compositions. Other components unique to the specific plant or animal source may be reported. Furthermore, lipid composition papers should incorporate elements of year­to­year, environmental, and/ or cultivar variations through use of appropriate statistical analyses.
期刊最新文献
Issue Information Issue Information Microfluidization outperforms homogenization: Optimizing stability and bioaccessibility in krill oil emulsions Issue Information JAOCS special issue on advancement in plant protein-based emulsions
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