将 PPY-CuO 加入 GO 作为 OLED 应用的电子传输层材料的性能评估

IF 1 4区 化学 Q4 POLYMER SCIENCE Polymer Science, Series B Pub Date : 2023-10-29 DOI:10.1134/S1560090423701208
Rimpi, R. Kandulna, U. Das, B. Kachhap
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引用次数: 0

摘要

实验室采用化学氧化聚合(COP)法制备了纳米复合材料聚吡咯(PPY)、还原氧化石墨烯(rGO)、聚吡咯-氧化铜(PPY-CuO)和聚吡咯-氧化铜-氧化石墨烯(PPY-CuO-GO)。通过分析 X 射线衍射(XRD)结果发现,CuO 成功地被吸收到 PPY 表面,其平均结晶尺寸为 38 nm。CuO 的各向异性加速了 PPY 聚合物链的聚集。PPY-CuO-GO 纳米复合材料的导电性得到了显著改善,电流密度也得到了提高。与原始 PPY 相比,PPY-CuO-rGO 纳米复合材料的电流密度提高了 49.20 A/cm2,带隙降低了 1.92 eV。PPY-CuO-rGO 纳米复合材料的电流密度增大,电子-空穴重组率增高,因此可用作有机发光二极管(OLED)的电子传输层(ETL)材料。
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Properties Evaluation of PPY-CuO Incorporated GO as Electron Transporting Layer Material for OLED Application

The chemical oxidative polymerization (COP) method was used in the lab to create the nanocomposite materials polypyrrole (PPY), reduced graphene oxide (rGO), polypyrrole-copper oxide (PPY-CuO), and polypyrrole-copper oxide-graphene oxide (PPY-CuO-GO). It was discovered by analysis of the X-Ray diffraction (XRD) results that CuO was successfully absorbed into the surface of PPY with an average crystallite size of 38 nm. The aggregation in the PPY polymer chain was accelerated by the anisotropic behavior of CuO. The conductivity of the PPY-CuO-GO nanocomposite was considerably improved, and the current density was enriched. When compared to the original PPY, the PPY-CuO-rGO nanocomposite was shown to have an improved current density of 49.20 A/cm2 and reduced band gap 1.92 eV. The PPY-CuO-rGO nanocomposite can be employed as an electron transporting layer (ETL) material for organic light emitting diodes (OLED) application due to the increased current density and high electron-hole recombination rate.

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来源期刊
Polymer Science, Series B
Polymer Science, Series B 化学-高分子科学
CiteScore
1.80
自引率
8.30%
发文量
58
审稿时长
>0 weeks
期刊介绍: Polymer Science, Series B is a journal published in collaboration with the Russian Academy of Sciences. Series B experimental and theoretical papers and reviews dealing with the synthesis, kinetics, catalysis, and chemical transformations of macromolecules, supramolecular structures, and polymer matrix-based composites (6 issues a year). All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed
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