壳聚糖基氧化石墨烯/ WO3复合材料在超级电容器中的应用

IF 0.9 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Journal of Ovonic Research Pub Date : 2023-10-01 DOI:10.15251/jor.2023.195.597
V. Thennarasu, A. Prabakaran
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引用次数: 0

摘要

不可再生能源的使用给地球带来了严重的环境问题。随着化石燃料燃烧的增加,温室气体的数量立即增加。结果,海平面稳步上升,地球变暖。人们对可再生能源进行了广泛的研究,以提供解决方案。然而,为了最大限度地利用能源,可再生能源需要一个能量存储系统,比如超级电容器。对于未来能源系统可持续超级电容器的开发,电极材料是一个有前景的目标。在电子应用中,为了制造比二次电池具有更高功率密度和更长的寿命周期的超级电容器,电极材料的形成是必不可少的。在本研究中,从蟹壳中分离出壳聚糖(CS),并采用改进的Hummers工艺合成氧化石墨烯(GO),然后进行化学还原。结果表明,与单步改进Hummers方法合成的氧化石墨烯相比,合成的氧化石墨烯具有更高的电容。为了进一步提高氧化石墨烯/WO3纳米复合材料的电化学性能,研究人员不断努力,选择最佳的WO3含量。通过对仲钨酸铵(APT)的负载、水热温度和反应时间等参数的综合考察,研究了氧化石墨烯/WO3纳米复合材料的形成。采用简单的水热合成法成功合成了WO3和GO/WO3纳米复合材料。
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Development of chitosan base graphene oxide/ WO3 hybrid composite for supercapacitor application
The use of non-renewable energy has brought to serious environmental problems for the planet. The amount of greenhouse gases rose immediately as the combustion of fossil fuels increased. As a result, sea levels are steadily rising and the Earth is becoming warmer. Research on renewable energy sources has been done extensively to provide a solution. However, in order to maximise energy utilisation, renewable energy needs an energy storage system, such as a super capacitor. For the development of sustainable supercapacitors for future energy systems, electrode material is a prospective target. The formation of desired electrode material is essential in order to fabricate supercapacitor with higher power density and longer life cycle than secondary batteries in electronic application. In this study, chitosan (CS) was isolated from crab shells, and graphene oxide (GO) was synthesized using a modified Hummers' process, followed by a chemical reduction approach. Based on the results, the synthesized GO exhibited higher capacitance as compared to GO that synthesized through single-step modified Hummers’ method. Continuous efforts have been exerted to further improve the electrochemical performance of GO/WO3 nanocomposite by incorporating an optimum content of WO3. In this manner, comprehensive investigations on different parameters, such as loadings of ammonium paratungstate (APT), hydrothermal temperature and reaction time were conducted in order to study the formation of GO/WO3 nanocomposite. WO3 and GO/WO3 nanocomposite were successfully synthesized through a simple hydrothermal method.
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来源期刊
Journal of Ovonic Research
Journal of Ovonic Research MATERIALS SCIENCE, MULTIDISCIPLINARY-PHYSICS, APPLIED
CiteScore
1.90
自引率
20.00%
发文量
77
期刊介绍: Journal of Ovonic Research (JOR) appears with six issues per year and is open to the reviews, papers, short communications and breakings news inserted as Short Notes, in the field of ovonic (mainly chalcogenide) materials for memories, smart materials based on ovonic materials (combinations of various elements including chalcogenides), materials with nano-structures based on various alloys, as well as semiconducting materials and alloys based on amorphous silicon, germanium, carbon in their various nanostructured forms, either simple or doped/alloyed with hydrogen, fluorine, chlorine and other elements of high interest for applications in electronics and optoelectronics. Papers on minerals with possible applications in electronics and optoelectronics are encouraged.
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