卤水:成因与全球可持续资源回收

IF 15.5 1区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Annual Review of Environment and Resources Pub Date : 2023-11-13 DOI:10.1146/annurev-environ-112621-094745
Chenglin Liu, Tim K. Lowenstein, Anjian Wang, Chunmiao Zheng, Jianguo Yu
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引用次数: 0

摘要

卤水中含有K +、ca2 +、Na +、Mg 2+、Li +、b3 +、Rb 2+、Cs 2+等阳离子,以及so4 2−、Cl−、HCO 3−、co32−、no3−、Br−、I−等阴离子,是有价元素。卤水在世界三大高原及其他地区的盐湖中分布广泛,分为硫酸盐型、氯化物型和碳酸盐型三种类型。硫酸盐型卤水形成于盐湖,碳酸盐型卤水则是岩浆和热液活动的产物。氯化物型卤水是深埋卤水还原转化形成的。卤水中的锂在清洁能源转型中起着关键作用,而卤水中的钾对钾肥生产很重要。近年来,从卤水中提取锂的新技术不断发展,卤水大规模、综合开发模式形成了循环经济模式的基础,有助于卤水高效利用钾肥和开发Li 2 CO 3,减少CO 2排放。本文综述了卤水的成因,重点介绍了新的利用技术、趋势和可持续发展。
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Brine: Genesis and Sustainable Resource Recovery Worldwide
Brine contains cations such as K + , Ca 2+ , Na + , Mg 2+ , Li + , B 3+ , Rb 2+ , and Cs 2+ , as well as anions such as SO 4 2− , Cl − , HCO 3 − , CO 3 2− , NO 3 − , Br − , and I − , which are valuable elements. Brines are widely distributed in salt lakes in the world's three enormous plateaus and beyond and are classified into three types: sulfate-, chloride-, and carbonate-type brines. Sulfate-type brine forms in salt lakes, whereas carbonate-type brine results from magmatic and hydrothermal activity. Chloride-type brine forms in deep basins due to the reduction and transformation of buried brine. Li in brine plays a critical role in clean energy transitions, and K in brine is important for potash production. Recently, new techniques for extracting Li from brine have been developed, and the large-scale, comprehensive development pattern of brines has formed the basis for a recycling economic model, which contributes to the efficient use of brines for potash and Li 2 CO 3 development and CO 2 emission reduction. This article reviews the genesis of brines and highlights new utilization techniques, trends, and sustainable development.
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来源期刊
Annual Review of Environment and Resources
Annual Review of Environment and Resources 环境科学-环境科学
CiteScore
24.10
自引率
1.80%
发文量
33
审稿时长
>24 weeks
期刊介绍: The Annual Review of Environment and Resources, established in 1976, offers authoritative reviews on key environmental science and engineering topics. It covers various subjects, including ecology, conservation science, water and energy resources, atmosphere, oceans, climate change, agriculture, living resources, and the human dimensions of resource use and global change. The journal's recent transition from gated to open access through Annual Reviews' Subscribe to Open program, with all articles published under a CC BY license, enhances the dissemination of knowledge in the field.
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