动态镍配位交联是提高高性能聚合物强度、韧性和循环利用的一种简便方法

IF 1.8 4区 化学 Q3 POLYMER SCIENCE High Performance Polymers Pub Date : 2023-09-30 DOI:10.1177/09540083231204218
Lei Li, Rui Yuan, Sucheng Yang, Li Yang, Guanjun Chang, Ying Huang
{"title":"动态镍配位交联是提高高性能聚合物强度、韧性和循环利用的一种简便方法","authors":"Lei Li, Rui Yuan, Sucheng Yang, Li Yang, Guanjun Chang, Ying Huang","doi":"10.1177/09540083231204218","DOIUrl":null,"url":null,"abstract":"It is of great significance to enhance mechanical properties and thermal stability of high-performance polymers. A new coordination polymer film (Ni/PPy) with high tensile strength and excellent heat resistance has been successfully prepared via a palladium-catalyzed C-C coupling reaction. For newly synthesized polymer film, bipyridine is incorporated into polymer chains during the synthesis process and subsequently crosslinked by nickel acetate. More importantly, Ni-coordination can be removed by external pyrophosphate to recover the linear polymer, which endows the polymer with recyclability. This strategy is expected to be an effective means for increasing the mechanical properties and recyclability of high-performance polymer materials.","PeriodicalId":12932,"journal":{"name":"High Performance Polymers","volume":null,"pages":null},"PeriodicalIF":1.8000,"publicationDate":"2023-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A facile strategy to improve the strength and toughness of high-performance polymer and recycle by dynamic Ni-coordination crosslinking\",\"authors\":\"Lei Li, Rui Yuan, Sucheng Yang, Li Yang, Guanjun Chang, Ying Huang\",\"doi\":\"10.1177/09540083231204218\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"It is of great significance to enhance mechanical properties and thermal stability of high-performance polymers. A new coordination polymer film (Ni/PPy) with high tensile strength and excellent heat resistance has been successfully prepared via a palladium-catalyzed C-C coupling reaction. For newly synthesized polymer film, bipyridine is incorporated into polymer chains during the synthesis process and subsequently crosslinked by nickel acetate. More importantly, Ni-coordination can be removed by external pyrophosphate to recover the linear polymer, which endows the polymer with recyclability. This strategy is expected to be an effective means for increasing the mechanical properties and recyclability of high-performance polymer materials.\",\"PeriodicalId\":12932,\"journal\":{\"name\":\"High Performance Polymers\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2023-09-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"High Performance Polymers\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1177/09540083231204218\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"High Performance Polymers","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1177/09540083231204218","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0

摘要

提高高性能聚合物的力学性能和热稳定性具有重要意义。通过钯催化的C-C偶联反应,成功制备了一种具有高抗拉强度和优异耐热性的新型配位聚合物(Ni/PPy)。对于新合成的聚合物薄膜,联吡啶在合成过程中被掺入到聚合物链中,随后被醋酸镍交联。更重要的是,外用焦磷酸盐可以去除镍配位,使线性聚合物回收,使聚合物具有可回收性。该策略有望成为提高高性能高分子材料机械性能和可回收性的有效手段。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
A facile strategy to improve the strength and toughness of high-performance polymer and recycle by dynamic Ni-coordination crosslinking
It is of great significance to enhance mechanical properties and thermal stability of high-performance polymers. A new coordination polymer film (Ni/PPy) with high tensile strength and excellent heat resistance has been successfully prepared via a palladium-catalyzed C-C coupling reaction. For newly synthesized polymer film, bipyridine is incorporated into polymer chains during the synthesis process and subsequently crosslinked by nickel acetate. More importantly, Ni-coordination can be removed by external pyrophosphate to recover the linear polymer, which endows the polymer with recyclability. This strategy is expected to be an effective means for increasing the mechanical properties and recyclability of high-performance polymer materials.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
High Performance Polymers
High Performance Polymers 化学-高分子科学
CiteScore
4.20
自引率
14.30%
发文量
106
审稿时长
1.2 months
期刊介绍: Health Services Management Research (HSMR) is an authoritative international peer-reviewed journal which publishes theoretically and empirically rigorous research on questions of enduring interest to health-care organizations and systems throughout the world. Examining the real issues confronting health services management, it provides an independent view and cutting edge evidence-based research to guide policy-making and management decision-making. HSMR aims to be a forum serving an international community of academics and researchers on the one hand and healthcare managers, executives, policymakers and clinicians and all health professionals on the other. HSMR wants to make a substantial contribution to both research and managerial practice, with particular emphasis placed on publishing studies which offer actionable findings and on promoting knowledge mobilisation toward theoretical advances. All papers are expected to be of interest and relevance to an international audience. HSMR aims at enhance communication between academics and practitioners concerned with developing, implementing, and analysing health management issues, reforms and innovations primarily in European health systems and in all countries with developed health systems. Papers can report research undertaken in a single country, but they need to locate and explain their findings in an international context, and in international literature.
期刊最新文献
Analysis of the impact of exfoliated graphene oxide on the mechanical performance and in-plane fracture resistance of epoxy-based nanocomposite Preparation of halogen-free flame retardant curing agent and its application in epoxy resin Bio-based phthalonitrile resin derived from quercetin as a sustainable molecular scaffold: Synthesis, curing reaction and comparison with petroleum-based counterparts Copolymerization of novel self-promoted curing phthalonitrile with epoxy resin and its thermal property Aromatic (Co)polycarbonates bearing pendant norbornenyl groups: Synthesis, characterization and post-polymerization modification
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1