柑桔皮活性炭吸附亚甲基蓝染料的制备及表征

Esther Baba, Gideon Wyasu, Ayoola Joseph Adefila, Nathan A. Dikko, Jamila B. Yakasa
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引用次数: 0

摘要

以柑桔皮为原料,以H2SO4和ZnCl2为活化剂,在400℃的温度下制备活性炭。浸渍比例为1:1 (wt/v)。前驱体和活性炭的FTIR分析表明前驱体和活性炭中存在不同的官能团。FTIR光谱还显示前驱体和活性炭之间的波段变化和波数变化,表明在活化和碳化过程中发生了化学转变。利用扫描电镜分析了活性炭的内部结构和孔隙发育情况。采用标准方法测定了活性炭对亚甲基蓝的吸附能力。采用Langmuir吸附等温线和Freundlich吸附等温线测定吸附过程,采用准一级动力学和准二级动力学测定吸附剂的吸附速率。
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Production and characterization of activated carbon derived from orange peel for the adsorption of methylene blue dye
Activated carbon was produced from orange peel using H2SO4 and ZnCl2 as activating agents at a temperature of 400 oC. The impregnation was done in 1:1 (wt/v). FTIR analysis of the precursor and activated carbon shows different functional groups present in the precursor and activated carbon. The FTIR spectral also shows shifts in bands and changes in wave number between the precursor and activated carbon indicating chemical transformation during activation and carbonization. SEM analysis was used to study the internal structure and pores development of the activated carbon. The methylene blue adsorption capacity of the activated carbon was determined using standard methods. Langmuir and Freundlich adsorption isotherms were employed in determining the adsorption process and Pseudo first-order and Pseudo secondorder kinetics were employed in determining the rate of adsorption by the adsorbents.
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