Oleg Kolodiazhnyi , Olga Kolodiazhna , Evgen Grishkun , Anastasy Kolodiazhna , Sergei Sheiko
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Generation of tert-butyl-λ5-phosphanedione and its chemical properties
Tert-butyl-λ5-phosphanedione was generated by flash vacuum thermolysis (FVT) of trimethylsilyl tert-butyl phosphonohalidates. The structure of tert-butyl-λ5-phosphanedione was confirmed by chemical reactions. Tert-butyl-λ5-phosphandione readily undergoes trimerization, enters into the [2 + 3] - cycloaddition reaction with 2-phenyloxirane and adds alcohols.
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Phosphorus, Sulfur, and Silicon and the Related Elements is a monthly publication intended to disseminate current trends and novel methods to those working in the broad and interdisciplinary field of heteroatom chemistry.
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