{"title":"室温固化超高岭土基地聚合物砂浆力学与微观结构性能研究","authors":"Cyriaque Rodrigue Kaze, Özgür Cengiz, Séverin Bidias Keumeka Jiofack, Charles Eugene Makone, Bharat Bhushan Jindal, Gisèle Laure Lecomte-Nana","doi":"10.1007/s41779-023-00977-6","DOIUrl":null,"url":null,"abstract":"<div><p>In this study, meta-halloysite (MH) mixed with an alkaline solution (8, 10, and 12 M) was used as a binder phase to produce geopolymer mortars with alkaline solution/MH ratios of 0.6, 0.7, and 0.8. The flow slump behaviour, setting time, and mechanical properties of the end products were studied at room temperature. The microstructural properties of the geopolymer mortars were evaluated using scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy. The matching slump values of fresh geopolymer mortars dropped as the alkaline solution concentration increased. The initial setting time increased as the alkaline solution/MH ratio grew (from 0.6 to 0.8). Increasing the alkaline content above 0.6 was averse to the development of strength and densification of the structure. The geopolymer mortar sample made with 0.6 and 12 M NaOH had a high compressive strength (65 MPa), low porosity, and low water absorption. According to the current study findings, geopolymer mortar has demonstrated great practicality and application potential for usage as an environmentally friendly building material, which may be a viable alternative for typical cement mortar in the future.</p></div>","PeriodicalId":673,"journal":{"name":"Journal of the Australian Ceramic Society","volume":"60 1","pages":"249 - 262"},"PeriodicalIF":1.8000,"publicationDate":"2023-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Investigation on the mechanical and microstructural properties of meta-halloysite-based geopolymer mortars cured at room temperature\",\"authors\":\"Cyriaque Rodrigue Kaze, Özgür Cengiz, Séverin Bidias Keumeka Jiofack, Charles Eugene Makone, Bharat Bhushan Jindal, Gisèle Laure Lecomte-Nana\",\"doi\":\"10.1007/s41779-023-00977-6\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In this study, meta-halloysite (MH) mixed with an alkaline solution (8, 10, and 12 M) was used as a binder phase to produce geopolymer mortars with alkaline solution/MH ratios of 0.6, 0.7, and 0.8. The flow slump behaviour, setting time, and mechanical properties of the end products were studied at room temperature. The microstructural properties of the geopolymer mortars were evaluated using scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy. The matching slump values of fresh geopolymer mortars dropped as the alkaline solution concentration increased. The initial setting time increased as the alkaline solution/MH ratio grew (from 0.6 to 0.8). Increasing the alkaline content above 0.6 was averse to the development of strength and densification of the structure. The geopolymer mortar sample made with 0.6 and 12 M NaOH had a high compressive strength (65 MPa), low porosity, and low water absorption. According to the current study findings, geopolymer mortar has demonstrated great practicality and application potential for usage as an environmentally friendly building material, which may be a viable alternative for typical cement mortar in the future.</p></div>\",\"PeriodicalId\":673,\"journal\":{\"name\":\"Journal of the Australian Ceramic Society\",\"volume\":\"60 1\",\"pages\":\"249 - 262\"},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2023-11-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of the Australian Ceramic Society\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s41779-023-00977-6\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the Australian Ceramic Society","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s41779-023-00977-6","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
引用次数: 0
摘要
在本研究中,将超高岭土(MH)与碱性溶液(8、10和12 M)混合作为粘合剂相,生产出碱性溶液/MH比分别为0.6、0.7和0.8的地聚合物砂浆。在室温条件下研究了终产物的流动坍落度、凝固时间和力学性能。利用扫描电子显微镜和能量色散x射线能谱对地聚合物砂浆的微观结构性能进行了评价。新鲜地聚合物砂浆的匹配坍落度值随着碱性溶液浓度的增加而下降。初始凝固时间随着碱液/MH比的增加而增加(从0.6增加到0.8)。当碱含量高于0.6时,不利于结构强度和致密化的发展。以0.6和12 M NaOH配制的地聚合物砂浆试样具有抗压强度高(65 MPa)、孔隙率低、吸水率低的特点。根据目前的研究结果,地聚合物砂浆作为一种环保建筑材料已经显示出巨大的实用性和应用潜力,在未来可能成为典型水泥砂浆的可行替代品。
Investigation on the mechanical and microstructural properties of meta-halloysite-based geopolymer mortars cured at room temperature
In this study, meta-halloysite (MH) mixed with an alkaline solution (8, 10, and 12 M) was used as a binder phase to produce geopolymer mortars with alkaline solution/MH ratios of 0.6, 0.7, and 0.8. The flow slump behaviour, setting time, and mechanical properties of the end products were studied at room temperature. The microstructural properties of the geopolymer mortars were evaluated using scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy. The matching slump values of fresh geopolymer mortars dropped as the alkaline solution concentration increased. The initial setting time increased as the alkaline solution/MH ratio grew (from 0.6 to 0.8). Increasing the alkaline content above 0.6 was averse to the development of strength and densification of the structure. The geopolymer mortar sample made with 0.6 and 12 M NaOH had a high compressive strength (65 MPa), low porosity, and low water absorption. According to the current study findings, geopolymer mortar has demonstrated great practicality and application potential for usage as an environmentally friendly building material, which may be a viable alternative for typical cement mortar in the future.
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Journal of the Australian Ceramic Society since 1965
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