庆祝德·东德尔的化学亲和力的诞生(1922-2022):从没有补偿的热量到他的圣母颂

IF 1.8 3区 化学 Q1 HISTORY & PHILOSOPHY OF SCIENCE Foundations of Chemistry Pub Date : 2023-11-25 DOI:10.1007/s10698-023-09488-5
Alessio Rocci
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摘要

thachiile De Donder,一位出生于布鲁塞尔的比利时数学家,阐述了两个重要的思想,在热力学和化学动力学之间架起了一座桥梁。他发明了反应推进度的概念,并且在1922年,他通过将克劳修斯的无补偿热翻译成形式语言,为已知的化学亲和性提供了精确的数学形式。这些概念融合在一个重要的不等式中,这个不等式是形式化非平衡态热力学的起点。本文旨在通过探索德·东德尔的教学活动及其与科学成果的联系,重构他是如何阐述和发展他的思想的。此外,它强调与他的弟子讨论所起的作用,他们成为他的合作者。本文分析了德·唐德尔参加1925年第二届索尔维化学理事会的努力,以引起化学家对他的数学方法的注意。我们解释了为什么他的工作在当时没有受到太多关注,以及尽管如此,他的化学亲和的形式化如何成为所谓的布鲁塞尔热力学学派诞生的基础。
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Celebrating the birth of De Donder’s chemical affinity (1922–2022): from the uncompensated heat to his Ave Maria

Théophile De Donder, a Belgian mathematician born in Brussels, elaborated two important ideas that created a bridge between thermodynamics and chemical kinetics. He invented the concept of the degree of advancement of a reaction, and, in 1922, he provided a precise mathematical form to the already known chemical affinity by translating Clausius’s uncompensated heat into formal language. These concepts merge in an important inequality that was the starting point for the formalization of non-equilibrium thermodynamics. The present article aims to reconstruct how De Donder elaborated his ideas and developed them by exploring his teaching activity and its connection with his scientific production. Furthermore, it emphasizes the role played by the discussions with his disciples who became his collaborators. The paper analyzes De Donder’s efforts in participating in the second Solvay Chemistry Council in 1925 to call the attention of chemists to his mathematical approach. We explain why his work did not receive much attention at the time, and how, despite this, his formalization of chemical affinity became the basis for the birth of the so-called Brussels school of thermodynamics.

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Foundations of Chemistry
Foundations of Chemistry HISTORY & PHILOSOPHY OF SCIENCE-
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22.20%
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期刊介绍: Foundations of Chemistry is an international journal which seeks to provide an interdisciplinary forum where chemists, biochemists, philosophers, historians, educators and sociologists with an interest in foundational issues can discuss conceptual and fundamental issues which relate to the `central science'' of chemistry. Such issues include the autonomous role of chemistry between physics and biology and the question of the reduction of chemistry to quantum mechanics. The journal will publish peer-reviewed academic articles on a wide range of subdisciplines, among others: chemical models, chemical language, metaphors, and theoretical terms; chemical evolution and artificial self-replication; industrial application, environmental concern, and the social and ethical aspects of chemistry''s professionalism; the nature of modeling and the role of instrumentation in chemistry; institutional studies and the nature of explanation in the chemical sciences; theoretical chemistry, molecular structure and chaos; the issue of realism; molecular biology, bio-inorganic chemistry; historical studies on ancient chemistry, medieval chemistry and alchemy; philosophical and historical articles; and material of a didactic nature relating to all topics in the chemical sciences. Foundations of Chemistry plans to feature special issues devoted to particular themes, and will contain book reviews and discussion notes. Audience: chemists, biochemists, philosophers, historians, chemical educators, sociologists, and other scientists with an interest in the foundational issues of science.
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