作为可持续性的一种应用:利用稻壳吸附去除水相中的镉离子 Cd (II)

Saja F. Rewaeh, H. Gzar, Marwaa K. Azeez
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摘要

这项研究的目标是降低昂贵的商业活性炭的重要性,同时使用廉价的、当地可获得的材料(稻壳)从废水中去除重金属。为了实现这一目标,我们对不同的pH值进行了测试,发现pH为5的批量研究对镉离子的去除效果最好。确定了180分钟为该工艺的理想接触时间,并发现随着接触时间的增加,吸附效果增加。考虑到搅拌速度对批量吸附的影响,建议采用180转/分的搅拌速度。评估了稻壳从水溶液中清除和吸收镉镉(II)的能力的有效性。研究表明,Cd的去除率为98%。该吸附剂对Cd的最大吸附能力为7.38 mg/g。三个模型- Freundlich, Temkin和langmuir -拟合各种平衡等温实验。对于该体系,Freundlich等温线模型的实验拟合最佳,拟合值为0.97。发现平衡等温线为有利型。对比四种模型各曲线的相关系数(R2)值,发现Elovich模型最能描述镉离子在稻壳上的吸附动力学。为Elovich>伪二阶>粒子内扩散>伪一阶。根据研究,稻壳可能有助于过滤废水中的污染物和杂质。因此,它是昂贵的活性炭的一个很好的替代品。
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As an Application of Sustainability: Utilizing Processed Rice Husk to Remove Cadmium Ions Cd (II) From Aqueous Phase by Adsorption
This study goals to reduce the importance of expensive commercial activated carbon while removing heavy metals from wastewater using cheap, locally available materials (rice husk). To accomplish this goal, a variety of pH values were tested, and it was found that batch studies at pH 5 had the best Cadmium ion removal effectiveness. 180 minutes was determined to be the ideal contact time for the process, and it was discovered that as contact time increased, adsorption effectiveness increased. 180 rpm is the recommended shaking speed, given studies on how agitation speed influences batch adsorption. The effectiveness of the rice husks capacity to eradicate Cadmium Cd (II) from aqueous solutions and absorb it, has assessed. The study revealed that Cd had a 98% effectiveness of removal. The recommended adsorbent's maximum Cd adsorption capability in a batch system was found to be 7.38 mg/g. Three models— Freundlich, Temkin, and Langmuir—were fitted to various equilibrium isothermal experiments. For this system, the experimental best fit was provided by the Freundlich isotherm model, with an value of 0.97. The equilibrium isotherms were discovered to be of a favorable type. When the correlation coefficient (R2) values of each curve for the four models are compared, it appears that the Elovich model best captures the kinetics of the Cadmium ions adsorption onto rice husk. Were the values (Elovich> pseudo-second order> intra-particle diffusion> Pseudo-First Order). According to the research, rice husk may be useful for filtering out wastewater from contaminants and impurities. So, It is a good alternative for expensive activated carbon.
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