用于降解废水中有机污染物的光催化剂纳米复合材料的合成与表征

IF 1.3 Q4 ENGINEERING, ENVIRONMENTAL Journal of Ecological Engineering Pub Date : 2023-12-01 DOI:10.12911/22998993/172352
R. Ratnawulan, Detty Rahmadhani, Ahmad Fauzi, R. Jonuarti, F. L. Supian, Fadhila Ulfa Jhora
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引用次数: 0

摘要

利用半导体技术,可以做出各种努力,以获得环境中的清洁水。研究了二氧化锰/CuO/ fe2o3光催化剂在废水中降解结晶紫的合成与表征。采用溶胶-凝胶法制备了三种半导体材料的纳米复合材料。采用x射线衍射(XRD)分析了纳米复合材料的结构,确定了晶体尺寸。利用傅里叶变换红外(FTIR)对纳米复合材料中的官能团进行了表征。扫描电子显微镜(SEM)可以表征表面形貌和颗粒大小。SEM结果表明,随着烧结温度的升高,颗粒尺寸最小可达54.79 nm。利用紫外可见分光光度法(Uv-Vis)分析表征结果,光催化剂活性的最有效带隙值为1.36 eV。样品在400℃的温度下,光照6小时,mno2 /CuO/ fe2o3催化剂的最佳降解率为50.40%。实验结果表明,烧结温度升高,光催化活性提高。
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Synthesis and Characterization of Photocatalyst Nanocomposite for the Degradation of Organic Pollutants in Wastewater
Various efforts can be made to obtain clean water in the environment by utilizing semiconductor technology. This study aims to inform the synthesis and characterization of MnO 2 /CuO/Fe 2 O 3 photocatalyst for crystal violet degradation in wastewater. Nanocomposite was synthesized through a sol-gel process with three semiconductor materials doped. X-ray diffraction (XRD) was employed to analyze the nanocomposite structure and determine crystal size. Fourier transform infrared (FTIR) was used to provide functional groups in the nanocomposite. A scanning electron microscope (SEM) can characterize surface morphology and particle size. The results of the SEM show that an increase in sintering temperature causes the smallest particle sizes to be 54.79 nm. The result of characterization using the ultraviolet-visible (Uv-Vis) spectrophotometry analysis the most effective band gap value in photocatalyst activity was 1.36 eV. The optimum percent of degradation MnO 2 /CuO/Fe 2 O 3 catalyst was 50.40% for the sample at a temperature of 400 °C under irradiation with sunlight for six hours. Test results show that increased sintering temperature increased the photocatalytic activity.
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来源期刊
Journal of Ecological Engineering
Journal of Ecological Engineering ENGINEERING, ENVIRONMENTAL-
CiteScore
2.60
自引率
15.40%
发文量
379
审稿时长
8 weeks
期刊介绍: - Industrial and municipal waste management - Pro-ecological technologies and products - Energy-saving technologies - Environmental landscaping - Environmental monitoring - Climate change in the environment - Sustainable development - Processing and usage of mineral resources - Recovery of valuable materials and fuels - Surface water and groundwater management - Water and wastewater treatment - Smog and air pollution prevention - Protection and reclamation of soils - Reclamation and revitalization of degraded areas - Heavy metals in the environment - Renewable energy technologies - Environmental protection of rural areas - Restoration and protection of urban environment - Prevention of noise in the environment - Environmental life-cycle assessment (LCA) - Simulations and computer modeling for the environment
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