环保型聚苯乙烯基氧化锌-石墨(PS/ZnO-G)的制备与特性分析

IF 0.8 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Journal of Nano Research Pub Date : 2023-12-22 DOI:10.4028/p-tr2t1h
H. Aldosari
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引用次数: 0

摘要

当今最重大的环境挑战之一是聚苯乙烯等不可生物降解的聚合物废物的生产量不断增加。为了制造易于分解的环保型聚苯乙烯,我们采用溶剂方法制造了基于氧化锌和石墨的聚苯乙烯复合材料。通过扫描电子显微镜-能量色散 X 射线分析评估了改性聚苯乙烯的表面形态和所含材料,通过扫描电子显微镜验证了纳米颗粒的分散和分布,通过能量色散 X 射线分析验证了材料的含量。通过 X 射线衍射和傅立叶变换红外线测定了晶体结构、化学键和功能,聚苯乙烯的化学结构没有发生变化。热重分析用于评估热分解。结果发现,氧化锌和石墨基聚苯乙烯复合材料的分解温度比纯聚苯乙烯低 46.78°。结果表明,纳米氧化锌的存在会导致相分离,从而影响石墨基聚苯乙烯复合材料的热性能。热重曲线显示了两个降解步骤,证明了相分离的存在。这满足了人们对合成环保、易热分解、易回收的聚苯乙烯的迫切需求,对环境和商业都有利。
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Fabrication and Characterization of Eco-Friendly Polystyrene Based Zinc Oxide-Graphite (PS/ZnO-G)
One of the most significant environmental challenges nowadays is the rising manufacturing of non-biodegradable polymer wastes like polystyrene. In order purpose of manufacture environmentally friendly polystyrene that easily decomposes, a solvent approach was used to create polystyrene based zinc oxide- graphite composites. The surface morphology and materials contained in the modified polystyrene were evaluated by scanning electron microscopy-energy dispersive X-ray analysis to verify the dispersion and distribution of the nanoparticles by scanning electron microscopy and the material contents by energy dispersive X-ray analysis. While the crystal structure, chemical bonds, and functions were determined by X-ray Diffraction and Fourier transform infrared, no change in the chemical structure occurred in polystyrene. Thermogravimetric analysis was used to assess the thermal decomposition. And its results found that the temperature of the decomposition was 46.78° lower in zinc oxide and graphite-based polystyrene composites than in pure polystyrene. It came to light that the presence of zinc oxide nanoparticles causes phase separation and consequently impacts the thermal behaviour of graphite-based polystyrene composites. The phase separation was demonstrated by the Thermogravimetric curves showing two degrading steps. This satisfies the urgent demand to synthesize polystyrene that is eco-friendly and easy to thermally decomposition, as well as easy to recycle, which benefits both the environment and the commercial side.
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来源期刊
Journal of Nano Research
Journal of Nano Research 工程技术-材料科学:综合
CiteScore
2.40
自引率
5.90%
发文量
55
审稿时长
4 months
期刊介绍: "Journal of Nano Research" (JNanoR) is a multidisciplinary journal, which publishes high quality scientific and engineering papers on all aspects of research in the area of nanoscience and nanotechnologies and wide practical application of achieved results. "Journal of Nano Research" is one of the largest periodicals in the field of nanoscience and nanotechnologies. All papers are peer-reviewed and edited. Authors retain the right to publish an extended and significantly updated version in another periodical.
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