利用固定化生物质吸附剂生物吸附污水中的有毒活性蓝色纺织染料

Q3 Environmental Science Environment and Natural Resources Journal Pub Date : 2023-12-13 DOI:10.32526/ennrj/21/20230192
Tanjore Ramachandran Sundararaman, Sivamani Sivalingam, Melvin Millicent Mabel, Trisha Gobinath
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引用次数: 0

摘要

本研究采用了固定化坎那籼珠(CIBs)来最大程度地降解主要用于纺织工业的剧毒活性蓝染料(RBD)。利用傅立叶变换红外光谱和 SEM-EDX 分析对 CIBs 进行了表征。进行了批量吸附研究,以测量有害 RBD 染料的去除率。在生物吸附技术中研究了不同的因素,如吸附剂-溶液相互作用时间(5-120 分钟)、溶液 pH 值(2-10)、吸附剂剂量(25-250 毫克/100 毫升)、RBD 浓度(50-250 毫克/升)和温度(30-60°C),以达到最大程度地去除有毒染料。在最佳 pH 值为 7、RBD 浓度为 50 毫克/升、吸附剂用量为 150 毫克/100 毫升、温度为 303 K 和作用时间为 60 分钟的条件下,成功去除了 99.96% 的 RBD。与 Freundlich 等温线和伪一阶动力学模型相比,Langmuir 等温线和伪二阶动力学模型的数据更为理想。发现 CIBs 生物吸附剂的最大吸附容量为 70.49 毫克/克。研究人员注意到,化学反应是自然发生的,并在反应过程中释放出热量,这表明反应是放热反应。这些结果表明,使用从番泻叶块根中制备的吸附剂可以有效地吸附去除 RBD。因此,这些 CIBs 可用于去除工业废水中的其他有毒染料和重金属。
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Biosorption of Toxic Reactive Blue Textile Dye from Effluent Water Using Immobilized Biomass Based Adsorbent
The present research employed immobilized Canna indica beads (CIBs) to obtain maximum degradation of highly toxic Reactive Blue Dye (RBD), predominantly used in textile industry. The CIBs were characterized using FTIR and SEM-EDX analysis. A batch adsorption study was conducted to measure the removal of harmful RBD dye. Different factors were examined in the biosorption technique to achieve the maximum level of toxic dye elimination, such as adsorbent-solute interaction time (5-120 min), solution pH (2-10), adsorbent dose (25 to 250 mg/100 mL), RBD concentration (50-250 mg/L), and temperature (30-60°C). Removal of 99.96% of RBD was successfully achieved at the optimum pH 7, RBD concentration of 50 mg/L, adsorbent dosage of 150 mg/100 mL, a temperature of 303 K, and 60 min of interaction time. The Langmuir isotherm and pseudo-second-order (PSO) kinetic model data have been found to be an ideal match compared to the Freundlich isotherm and pseudo-first-order (PFO) kinetic model. The maximum adsorption capacity onto CIBs biosorbent was found to be 70.49 mg/g. It was noticed that the chemical reaction occurred naturally and released heat during the process which denoted an exothermic reaction. These results shown that the adsorption of RBD removal is efficient using prepared adsorbent from Canna indica root tubers. Therefore, these CIBs could be used for other toxic dyes and heavy metals from industrial wastewater.
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来源期刊
Environment and Natural Resources Journal
Environment and Natural Resources Journal Environmental Science-Environmental Science (all)
CiteScore
1.90
自引率
0.00%
发文量
49
审稿时长
8 weeks
期刊介绍: The Environment and Natural Resources Journal is a peer-reviewed journal, which provides insight scientific knowledge into the diverse dimensions of integrated environmental and natural resource management. The journal aims to provide a platform for exchange and distribution of the knowledge and cutting-edge research in the fields of environmental science and natural resource management to academicians, scientists and researchers. The journal accepts a varied array of manuscripts on all aspects of environmental science and natural resource management. The journal scope covers the integration of multidisciplinary sciences for prevention, control, treatment, environmental clean-up and restoration. The study of the existing or emerging problems of environment and natural resources in the region of Southeast Asia and the creation of novel knowledge and/or recommendations of mitigation measures for sustainable development policies are emphasized. The subject areas are diverse, but specific topics of interest include: -Biodiversity -Climate change -Detection and monitoring of polluted sources e.g., industry, mining -Disaster e.g., forest fire, flooding, earthquake, tsunami, or tidal wave -Ecological/Environmental modelling -Emerging contaminants/hazardous wastes investigation and remediation -Environmental dynamics e.g., coastal erosion, sea level rise -Environmental assessment tools, policy and management e.g., GIS, remote sensing, Environmental -Management System (EMS) -Environmental pollution and other novel solutions to pollution -Remediation technology of contaminated environments -Transboundary pollution -Waste and wastewater treatments and disposal technology
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