碳化加热速率对掺杂 N 的柚木锯末废活性炭性能的影响

IF 1.2 Q3 MULTIDISCIPLINARY SCIENCES Journal of Physical Science Pub Date : 2023-12-06 DOI:10.21315/jps2023.34.3.1
D. N. K. Putra Negara, T. G. Tirta Nindhia, Cok Istri Putri Kusuma Kencanawati, I. G. A. K. Suriadi, I. Widiyarta, I. Lokantara, I. N. Budiarsa
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引用次数: 0

摘要

在活性炭生产过程中,生物质可以代替煤炭和石油残渣等不可再生的原材料。然而,由于化学成分不同,每种生物质需要不同的生产工艺参数才能获得理想的活性炭特性。本研究旨在探讨碳化加热速率(8°C/min、10°C/min 和 12°C/min)对柚木锯末衍生活性炭特性的影响。此外,找到合适的碳化加热速率以提供最佳特性也是本研究的独创之处。活化在 600°C 的温度下进行,同时以 200 mL/min 的速度掺入氮气。作为特性分析的一部分,还进行了热重分析(TGA)、扫描电子显微镜(SEM)和吸附等温线测试。结果表明,以 10°C/min 的速度碳化的活性炭具有最佳性能。这种活性炭含有 10.8% 的水分、15.26% 的挥发物、1.73% 的灰分和 72.43% 的固定碳。大部分结构为中孔,平均孔径为 2.43 nm,孔体积为 0.369 cm3 /g,比表面积为 409.698 m2 /g。其吸附氮的能力为 239.102 cm3 /g。从柚木锯末中提取的生物质废料成功制备出活性炭,为尚未开发的锯末废料带来了希望,并有可能用于许多需要吸附机制的应用领域。
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The Effect of Carbonisation Heating Rates on the Properties of N-Doped Teak Sawdust Waste Activated Carbon
Biomass can be utilised in place of non-renewable raw resources like coal and petroleum residue in the production of activated carbon. Each biomass, however, requires different manufacturing process parameters to obtain the desired activated carbon characteristics due to their different chemical compositions. This study aims to examine the effects of carbonisation heating rates (8°C/min, 10°C/min and 12°C/min) on the characteristics of teak sawdust-derived activated carbon. Furthermore, finding the proper carbonisation heating rate to provide the optimum characteristics is the originality of this study. Activation was carried out at a temperature of 600°C, and simultaneously, 200 mL/min of nitrogen was doped. Thermogravimetric analysis (TGA), scanning electron microscopy (SEM) and adsorption isotherm tests were performed as part of the characterisation. The results revealed that activated carbon carbonised at a rate of 10°C/min produced the best properties. This activated carbon contained 10.8% moisture, 15.26% volatile, 1.73% ash and 72.43% fixed carbon. The majority of the structure is mesopore, with an average pore diameter of 2.43 nm, a pore volume of 0.369 cm3 /g and a specific surface area of 409.698 m2 /g. Its ability to adsorb nitrogen was 239.102 cm3 /g. The successful production of activated carbon from biomass waste derived from teak sawdust offers hope for untapped sawdust waste and has the potential to be used in a number of applications that need adsorption mechanisms.
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来源期刊
Journal of Physical Science
Journal of Physical Science Physics and Astronomy-Physics and Astronomy (all)
CiteScore
1.70
自引率
0.00%
发文量
19
期刊介绍: The aim of the journal is to disseminate latest scientific ideas and findings in the field of physical sciences among scientists in Malaysia and international regions. This journal is devoted to the publication of articles dealing with research works in Chemistry, Physics and Engineering. Review articles will also be considered. Manuscripts must be of scientific value and will be submitted to independent referees for review. Contributions must be written in English and must not have been published elsewhere.
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