K. A. Mahmoud, Mazen M. Binmujlli, M. W. Marashdeh, Mamduh J. Aljaafreh, Ahmad Saleh, M. Y. Hanfi
{"title":"利用掺杂硫酸铜(ii)的聚环氧树脂的实验测量结果进行伽马射线屏蔽分析","authors":"K. A. Mahmoud, Mazen M. Binmujlli, M. W. Marashdeh, Mamduh J. Aljaafreh, Ahmad Saleh, M. Y. Hanfi","doi":"10.1515/epoly-2023-0142","DOIUrl":null,"url":null,"abstract":"The present work aims to study the effect of the CuSO<jats:sub>4</jats:sub> additive on the physical and radiation-shielding properties of polyepoxide resins. As a result, a series of four samples with the chemical composition <jats:italic>x</jats:italic>CuSO<jats:sub>4</jats:sub> + (100 − <jats:italic>x</jats:italic>) (epoxy resin and hardener) was synthesized. The fabrication of samples was performed under atmospheric pressure and at room temperature. The density of the fabricated CuSO<jats:sub>4</jats:sub>-doped polyepoxides resin was measured experimentally using an MH-300A densimeter with an accuracy of 0.001 mg·cm<jats:sup>−3</jats:sup>. A narrow beam transmission method with an NaI (Tl) detector was used to evaluate and describe the effect of CuSO<jats:sub>4</jats:sub> on the linear attenuation coefficient of the fabricated composites in the γ-ray energy interval, which ranged between 33 and 1,332 keV. The estimated results showed a high enhancement in the <jats:italic>µ</jats:italic> values that increased from 0.259 to 1.749 cm<jats:sup>−1</jats:sup>, raising the CuSO<jats:sub>4</jats:sub> concentration from 0 to 40 wt% at a γ-photon energy of 33 keV. The enhancement in the <jats:italic>µ</jats:italic> values decreased with an increase in the γ-photon energy to 1,332 keV, whereas the <jats:italic>µ</jats:italic> values increased from 0.077 to 0.102 cm<jats:sup>−1</jats:sup> with an increase in the CuSO<jats:sub>4</jats:sub> concentration between 0 and 40 wt%, respectively. This showed that increased <jats:italic>µ</jats:italic> values positively affected the half-value thickness (<jats:italic>Δ</jats:italic> <jats:sub>0.5</jats:sub>, cm), mean free path (<jats:italic>λ</jats:italic>, cm), lead equivalent thickness (<jats:italic>Δ</jats:italic> <jats:sub>eq</jats:sub>, cm), and the transmission factor (%); all of the mentioned parameters suffer a considerable decrease with increasing CuSO<jats:sub>4</jats:sub> concentration between 0 and 40 wt%.","PeriodicalId":11806,"journal":{"name":"e-Polymers","volume":"45 1","pages":""},"PeriodicalIF":3.2000,"publicationDate":"2023-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Gamma-ray shielding analysis using the experimental measurements for copper(ii) sulfate-doped polyepoxide resins\",\"authors\":\"K. A. Mahmoud, Mazen M. Binmujlli, M. W. Marashdeh, Mamduh J. Aljaafreh, Ahmad Saleh, M. Y. Hanfi\",\"doi\":\"10.1515/epoly-2023-0142\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The present work aims to study the effect of the CuSO<jats:sub>4</jats:sub> additive on the physical and radiation-shielding properties of polyepoxide resins. As a result, a series of four samples with the chemical composition <jats:italic>x</jats:italic>CuSO<jats:sub>4</jats:sub> + (100 − <jats:italic>x</jats:italic>) (epoxy resin and hardener) was synthesized. The fabrication of samples was performed under atmospheric pressure and at room temperature. The density of the fabricated CuSO<jats:sub>4</jats:sub>-doped polyepoxides resin was measured experimentally using an MH-300A densimeter with an accuracy of 0.001 mg·cm<jats:sup>−3</jats:sup>. A narrow beam transmission method with an NaI (Tl) detector was used to evaluate and describe the effect of CuSO<jats:sub>4</jats:sub> on the linear attenuation coefficient of the fabricated composites in the γ-ray energy interval, which ranged between 33 and 1,332 keV. The estimated results showed a high enhancement in the <jats:italic>µ</jats:italic> values that increased from 0.259 to 1.749 cm<jats:sup>−1</jats:sup>, raising the CuSO<jats:sub>4</jats:sub> concentration from 0 to 40 wt% at a γ-photon energy of 33 keV. The enhancement in the <jats:italic>µ</jats:italic> values decreased with an increase in the γ-photon energy to 1,332 keV, whereas the <jats:italic>µ</jats:italic> values increased from 0.077 to 0.102 cm<jats:sup>−1</jats:sup> with an increase in the CuSO<jats:sub>4</jats:sub> concentration between 0 and 40 wt%, respectively. This showed that increased <jats:italic>µ</jats:italic> values positively affected the half-value thickness (<jats:italic>Δ</jats:italic> <jats:sub>0.5</jats:sub>, cm), mean free path (<jats:italic>λ</jats:italic>, cm), lead equivalent thickness (<jats:italic>Δ</jats:italic> <jats:sub>eq</jats:sub>, cm), and the transmission factor (%); all of the mentioned parameters suffer a considerable decrease with increasing CuSO<jats:sub>4</jats:sub> concentration between 0 and 40 wt%.\",\"PeriodicalId\":11806,\"journal\":{\"name\":\"e-Polymers\",\"volume\":\"45 1\",\"pages\":\"\"},\"PeriodicalIF\":3.2000,\"publicationDate\":\"2023-12-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"e-Polymers\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1515/epoly-2023-0142\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"e-Polymers","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1515/epoly-2023-0142","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
Gamma-ray shielding analysis using the experimental measurements for copper(ii) sulfate-doped polyepoxide resins
The present work aims to study the effect of the CuSO4 additive on the physical and radiation-shielding properties of polyepoxide resins. As a result, a series of four samples with the chemical composition xCuSO4 + (100 − x) (epoxy resin and hardener) was synthesized. The fabrication of samples was performed under atmospheric pressure and at room temperature. The density of the fabricated CuSO4-doped polyepoxides resin was measured experimentally using an MH-300A densimeter with an accuracy of 0.001 mg·cm−3. A narrow beam transmission method with an NaI (Tl) detector was used to evaluate and describe the effect of CuSO4 on the linear attenuation coefficient of the fabricated composites in the γ-ray energy interval, which ranged between 33 and 1,332 keV. The estimated results showed a high enhancement in the µ values that increased from 0.259 to 1.749 cm−1, raising the CuSO4 concentration from 0 to 40 wt% at a γ-photon energy of 33 keV. The enhancement in the µ values decreased with an increase in the γ-photon energy to 1,332 keV, whereas the µ values increased from 0.077 to 0.102 cm−1 with an increase in the CuSO4 concentration between 0 and 40 wt%, respectively. This showed that increased µ values positively affected the half-value thickness (Δ0.5, cm), mean free path (λ, cm), lead equivalent thickness (Δeq, cm), and the transmission factor (%); all of the mentioned parameters suffer a considerable decrease with increasing CuSO4 concentration between 0 and 40 wt%.
期刊介绍:
e-Polymers is a strictly peer-reviewed scientific journal. The aim of e-Polymers is to publish pure and applied polymer-science-related original research articles, reviews, and feature articles. It includes synthetic methodologies, characterization, and processing techniques for polymer materials. Reports on interdisciplinary polymer science and on applications of polymers in all areas are welcome.
The present Editors-in-Chief would like to thank the authors, the reviewers, the editorial staff, the advisory board, and the supporting organization that made e-Polymers a successful and sustainable scientific journal of the polymer community. The Editors of e-Polymers feel very much engaged to provide best publishing services at the highest possible level.