尼古拉-利哈乔夫收藏的弗兰肯堡的西格贝特印章综合研究

IF 0.8 Q3 Engineering Nanotechnologies in Russia Pub Date : 2023-12-26 DOI:10.1134/s2635167623600372
E. I. Nosova, D. I. Weber, L. A. Pyankova
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引用次数: 0

摘要

摘要该作品展示了对西欧一个独特的文字标本--弗兰肯堡伯爵西格贝特的印章(神圣罗马帝国,12 世纪)--的复杂研究结果。该样本以其独特的深酒红色从众多样本中脱颖而出。此外,它属于蜡质印章着色做法的起源时期,当时的技术正处于形成阶段。我们采用了一种综合方法来确定制作这件作品的材料,其中包括多种方法:光学显微镜、偏振显微镜、傅立叶变换红外光谱、X 射线荧光分析和 X 射线结构分析。研究发现,样品由纯蜜蜡组成,不含任何树脂混合物,这在 12 世纪就已为人所知。着色物质是由赤铁矿和石英组成的天然栓石。这种标本在西欧的sphragistics中非常罕见,14世纪末以后就不再出现了。由于这种颜料非常普遍,因此无法用其稀有性或完全不可获得性来解释为何拒绝使用这种颜料。原因可能是颜色太深,几乎成了棕色,对于喜欢鲜艳颜料的中世纪人来说不够美观。拒绝使用酚醛树脂的另一个原因是,当引入含有无色二氧化硅的酚醛树脂时,蜡块会变得松散易碎。这将导致印章的损坏和图像的丢失。在保护实践中,当计划工作的优先次序时,应特别小心地检查此类标本,如有必要,应完全加固。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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A Comprehensive Study of the Sigebert of Frankenburg Seal from the Collections of Nicolai Likhachev

Abstract

The work presents the results of a complex study of a unique specimen of Western European sphragistics: the seal of Count Sigebert of Frankenburg (Holy Roman Empire, 12th century). This specimen stands out from the general masses with its distinctive dark burgundy color. Furthermore, it belongs to the period when the practice of coloring wax seals originated and the technology was in its formative stages. A comprehensive approach is applied to identify the materials used to make this piece, which included several methods: optical microscopy, polarization microscopy, Fourier-transform infrared spectroscopy, X-ray fluorescence analysis, and X-ray structural analysis. It is found that the sample consists of pure beeswax, without any resin admixtures, which is already known from the 12th century. The coloring substance is natural bolus consisting of hematite and quartz. Such specimens are rare in Western European sphragistics and do not occur after the end of the 14th century. It is impossible to explain the refusal to use bolus by its rarity or complete inaccessibility, as the pigment is widespread. The reason is probably the dark, almost brown color, which was not beautiful enough from the point of view of medieval man, who appreciated bright pigments. The refusal to use bolus can also be explained by the fact that when bolus containing colorless SiO2 is introduced, the wax mass becomes loose and friable. This leads to deterioration of the seal and loss of the image. In conservation practice, when planning the priority of work, such specimens should be inspected with special care and, if necessary, strengthened entirely.

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来源期刊
Nanotechnologies in Russia
Nanotechnologies in Russia NANOSCIENCE & NANOTECHNOLOGY-
CiteScore
1.20
自引率
0.00%
发文量
0
期刊介绍: Nanobiotechnology Reports publishes interdisciplinary research articles on fundamental aspects of the structure and properties of nanoscale objects and nanomaterials, polymeric and bioorganic molecules, and supramolecular and biohybrid complexes, as well as articles that discuss technologies for their preparation and processing, and practical implementation of products, devices, and nature-like systems based on them. The journal publishes original articles and reviews that meet the highest scientific quality standards in the following areas of science and technology studies: self-organizing structures and nanoassemblies; nanostructures, including nanotubes; functional and structural nanomaterials; polymeric, bioorganic, and hybrid nanomaterials; devices and products based on nanomaterials and nanotechnology; nanobiology and genetics, and omics technologies; nanobiomedicine and nanopharmaceutics; nanoelectronics and neuromorphic computing systems; neurocognitive systems and technologies; nanophotonics; natural science methods in a study of cultural heritage items; metrology, standardization, and monitoring in nanotechnology.
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