Ya.V. Golubev, I. S. Makarov, M. I. Vinogradov, L. K. Golova, A. G. Smyslov
{"title":"基于亚麻纤维素的工业纤维作为轮胎帘子线原丝","authors":"Ya.V. Golubev, I. S. Makarov, M. I. Vinogradov, L. K. Golova, A. G. Smyslov","doi":"10.1007/s10692-023-10467-x","DOIUrl":null,"url":null,"abstract":"<p>Eco-unfriendliness of viscose process − the main producer of tire cord from wood cellulose − does not meet the growing need for creation of “green” tires. Alongside viscose cord fiber, production of a new cord fiber, Lyocell, from wood cellulose by eco-clean NMMO process is developing. Technical fibers were obtained from high-molecular flax cellulose by the method of its solid-phase dissolution in N-methylmorpholine-N-oxide. Comparative studies of the structure and mechanical and thermal properties of flax fibers and industrial cord fibers showed correspondence of their properties and that the stiffness of the flax fiber is almost 30 % higher than that of the cord fiber. Flax fibers are resistant to cyclic deformative actions and their deformation at high temperature is less than that of commercial samples. Water losses by the samples in the process of thermal studies at temperatures up to 170 °C have a reverse nature, which is confirmed by the stability of the mechanical properties of the samples under equilibrium conditions after thermal action. The obtained data set indicates sufficiently high fatigue strength of flax fibers and makes it possible to use them as cord fiber at par with cord fiber from wood cellulose.</p>","PeriodicalId":12230,"journal":{"name":"Fibre Chemistry","volume":"313 5 1","pages":""},"PeriodicalIF":0.5000,"publicationDate":"2023-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Technical Fiber Based on Flax Cellulose as Tire Cord Precursor\",\"authors\":\"Ya.V. Golubev, I. S. Makarov, M. I. Vinogradov, L. K. Golova, A. G. Smyslov\",\"doi\":\"10.1007/s10692-023-10467-x\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Eco-unfriendliness of viscose process − the main producer of tire cord from wood cellulose − does not meet the growing need for creation of “green” tires. Alongside viscose cord fiber, production of a new cord fiber, Lyocell, from wood cellulose by eco-clean NMMO process is developing. Technical fibers were obtained from high-molecular flax cellulose by the method of its solid-phase dissolution in N-methylmorpholine-N-oxide. Comparative studies of the structure and mechanical and thermal properties of flax fibers and industrial cord fibers showed correspondence of their properties and that the stiffness of the flax fiber is almost 30 % higher than that of the cord fiber. Flax fibers are resistant to cyclic deformative actions and their deformation at high temperature is less than that of commercial samples. Water losses by the samples in the process of thermal studies at temperatures up to 170 °C have a reverse nature, which is confirmed by the stability of the mechanical properties of the samples under equilibrium conditions after thermal action. The obtained data set indicates sufficiently high fatigue strength of flax fibers and makes it possible to use them as cord fiber at par with cord fiber from wood cellulose.</p>\",\"PeriodicalId\":12230,\"journal\":{\"name\":\"Fibre Chemistry\",\"volume\":\"313 5 1\",\"pages\":\"\"},\"PeriodicalIF\":0.5000,\"publicationDate\":\"2023-12-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Fibre Chemistry\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1007/s10692-023-10467-x\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Fibre Chemistry","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1007/s10692-023-10467-x","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Technical Fiber Based on Flax Cellulose as Tire Cord Precursor
Eco-unfriendliness of viscose process − the main producer of tire cord from wood cellulose − does not meet the growing need for creation of “green” tires. Alongside viscose cord fiber, production of a new cord fiber, Lyocell, from wood cellulose by eco-clean NMMO process is developing. Technical fibers were obtained from high-molecular flax cellulose by the method of its solid-phase dissolution in N-methylmorpholine-N-oxide. Comparative studies of the structure and mechanical and thermal properties of flax fibers and industrial cord fibers showed correspondence of their properties and that the stiffness of the flax fiber is almost 30 % higher than that of the cord fiber. Flax fibers are resistant to cyclic deformative actions and their deformation at high temperature is less than that of commercial samples. Water losses by the samples in the process of thermal studies at temperatures up to 170 °C have a reverse nature, which is confirmed by the stability of the mechanical properties of the samples under equilibrium conditions after thermal action. The obtained data set indicates sufficiently high fatigue strength of flax fibers and makes it possible to use them as cord fiber at par with cord fiber from wood cellulose.
期刊介绍:
Fibre Chemistry publishes original research and review articles in the field of man-made fibre production and application. The journal offers scientific and technical articles on the following aspects: chemistry, technology, machinery and economics of man-made production; the initial monomers and polymers; the properties of man-made fibres and their processing in various industry branches (textiles, rubber, composites, etc).