烯酰胺自由基转化的最新进展

IF 1.7 4区化学 Q3 CHEMISTRY, ORGANIC Current organic synthesis Pub Date : 2024-01-04 DOI:10.2174/0115701794269961231027054854

Yongchun Liu, Zimin Wang, Rui Li, Yinhai Yao, Zhichuan Shi, Qin Sun, Guowei Deng

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引用次数: 0

摘要

:烯酰胺是一种特殊的烯烃，人们对烯酰胺独特的反应性、选择性（立体选择性和区域选择性）和稳定性进行了广泛的研究。在本综述中，将总结过去几年来烯酰胺自由基转化的发展情况。本综述将分三个部分进行详细讨论：C- X（X = N、S、O、Se）键的分子间自由基加成、金属盐介导的烯酰胺环化以及烯酰胺的光催化环化。此外，还提供了绝大多数转化过程的合理机制细节。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Recent progress in free radical transformations of allenamides

: Allenamides are special allenes, and the unique reactivity, selectivity (both stereoselective and regionally selective) and stability of allenamides have been widely studied. In this review, the development of the free radical transformation of allenamides over the last few years will be summarized. This review discusses in detail in three parts: intermolecular radical addition to C- X (X = N, S, O, Se) bonds, metal salt mediated cyclization of allenamides, and photocatalytic cyclization of allenamides. In addition, reasonable details of the mechanisms are provided for the vast majority of these transformations.

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来源期刊

Current organic synthesis 化学-有机化学

CiteScore

3.40

自引率

5.60%

发文量

审稿时长

6-12 weeks

期刊介绍： Current Organic Synthesis publishes in-depth reviews, original research articles and letter/short communications on all areas of synthetic organic chemistry i.e. asymmetric synthesis, organometallic chemistry, novel synthetic approaches to complex organic molecules, carbohydrates, polymers, protein chemistry, DNA chemistry, supramolecular chemistry, molecular recognition and new synthetic methods in organic chemistry. The frontier reviews provide the current state of knowledge in these fields and are written by experts who are internationally known for their eminent research contributions. The journal is essential reading to all synthetic organic chemists. Current Organic Synthesis should prove to be of great interest to synthetic chemists in academia and industry who wish to keep abreast with recent developments in key fields of organic synthesis.