革命性的碳量子点支撑钴催化剂实现破纪录的氢气生产率

IF 1.8 4区 材料科学 Q2 MATERIALS SCIENCE, CERAMICS Journal of the Australian Ceramic Society Pub Date : 2024-01-05 DOI:10.1007/s41779-023-00988-3
Erhan Onat, Sabit Horoz, Ömer Şahin, Mehmet Sait İzgi
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引用次数: 0

摘要

在本研究中,我们通过合成和表征一种碳量子点支撑的钴(Co-B_CQDs)催化剂,在制氢领域引入了一种开创性的方法。我们的研究结果表明,这种最先进的催化剂在水解 KBH4 的过程中表现出卓越的性能,制氢率达到破纪录的 23,019.97 mL*gcat-1*min-1,活化能低至 19.36 kJ/mol。这是首次使用这种催化剂取得如此出色的成果。该研究凸显了碳量子点作为分散金属催化剂的支撑材料的巨大潜力,为制氢领域的研究开辟了新途径。利用各种分析技术,如 X 射线衍射 (XRD)、紫外线和可见光 (UV-Vis)、光致发光 (PL) 和电感耦合等离子体光发射光谱 (ICP-OES) 测量,对合成的催化剂进行了广泛的表征,进一步证实了其卓越的性能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Revolutionary carbon quantum dot supported-Co catalyst for record-breaking hydrogen production rate

In this study, we introduce a groundbreaking approach in the field of hydrogen production by synthesizing and characterizing a carbon quantum dot supported-Co (Co-B_CQDs) catalyst. Our results demonstrate that this state-of-the-art catalyst exhibits exceptional performance in the hydrolysis of KBH4, resulting in a record-breaking hydrogen production rate of 23,019.97 mL*gcat−1*min−1 and a remarkably low activation energy of 19.36 kJ/mol. This is the first time that this type of catalyst has been used to achieve such outstanding results. The study highlights the remarkable potential of carbon quantum dots as a support material for dispersing metal catalysts, which opens up new avenues for research in the field of hydrogen production. The synthesized catalyst was extensively characterized using various analytical techniques such as X-ray diffraction (XRD), ultraviolet and visible light (UV–Vis), photoluminescence (PL), and inductively coupled plasma optical emission spectrometry (ICP-OES) measurements, which further confirmed its superior performance.

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来源期刊
Journal of the Australian Ceramic Society
Journal of the Australian Ceramic Society Materials Science-Materials Chemistry
CiteScore
3.70
自引率
5.30%
发文量
123
期刊介绍: Publishes high quality research and technical papers in all areas of ceramic and related materials Spans the broad and growing fields of ceramic technology, material science and bioceramics Chronicles new advances in ceramic materials, manufacturing processes and applications Journal of the Australian Ceramic Society since 1965 Professional language editing service is available through our affiliates Nature Research Editing Service and American Journal Experts at the author''s cost and does not guarantee that the manuscript will be reviewed or accepted
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