评估儿童雪被和头发中的重金属含量

S. Shayakhmetov, A. Merinov, O. Zhurba, A. Alekseenko
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摘要

导言。环境污染导致需要定期监测和分析环境成分和人口生物基质中有毒元素的含量,以确定领土的污染程度、其在体内的积累情况以及评估健康疾病的风险。 材料和方法从功能区的 11 个不同地段采集了积雪样本,并对该市不同学校两组儿童的 52 份头发样本进行了检测。水溶性重金属和砷(HMAr)含量的测定是在 AAC-240 DUO "Agilent Technolgies "设备上通过原子吸收法进行的。 研究结果在斯维尔斯克个别功能区的积雪覆盖层中,发现铜、锌、锰、镉、铅和砷的含量与背景值相比明显超标,范围在 2-11 倍之间。确定了反映该市不同地区儿童头发中 HMAr 积累增加具体情况的指标元素(锰、铬、锌、镉、砷)。学校附近积雪中的 HMAr 含量与受检儿童群体头发中的 HMAr 含量之间存在很强的相关性(r = 0.78-0.83)。 局限性。在评估雪层和儿童毛发中的 HMs 含量时,没有确定元素在土壤中的积累和向植物培养物中的迁移。 结论由于工业企业、机动车辆和居民家庭排放的废气对人类产生了重大影响,斯维尔斯克市雪层和儿童头发中的 HMAr 积累水平较高,这表明该市的环境状况十分紧张,需要采取一系列措施加以改善。
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Assessment of the content of heavy metals in the snow cover and hair in children
Introduction. Environmental pollution leads to the need for regular monitoring and analysis of the content of toxic elements in the components of the environment and biosubstrates of the population to determine the degree of contamination of the territory, their accumulation in the body and assess the risk of health disorders. Materials and methods. Samples of snow cover were taken from eleven different sections of functional zones, and 52 hair samples were examined in two groups of children in different schools of the city. Determination of the content of water–soluble heavy metals and arsenic (HMAr) was carried out by atomic absorption method on the AAC-240 DUO “Agilent Technolgies” device. Results. In the snow cover of individual functional zones of Svirsk, a significant excess of Cu, Zn, Mn, Cd, Pb, and As content was found in comparison with background values in the range of 2–11 times. Indicator elements (Mn, Cr, Zn, Cd, As) reflecting the specifics of increased accumulation of HMAr in the hair of children in different areas of the city were identified. Strong correlations (r = 0.78–0.83) were established between the content of HMAr in the snow cover near schools and in the hair in the examined groups of children. Limitations. The assessment of content of HMs in the snow cover and in the hair in children population was evaluated without determining the accumulation of elements in the soil and migration to plant cultures. Conclusion. The revealed high levels of accumulation of HMAr in the snow cover and hair in children in Svirsk, due to the significant anthropogenic impact of emissions from industrial enterprises, motor vehicles, and residential households, indicate the tension of the environmental situation in the city and the need to implement a set of measures to improve it.
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