研究在矿化水-油环境中抑制腐蚀过程的有效性

M.M. Kosmyna, Yuliia Nosachova
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引用次数: 0

摘要

腐蚀现象严重影响着许多行业。与冶金、造船或石油工业有关的一切都会受到腐蚀过程的负面影响。这是一个大问题,因为因腐蚀而导致的工业事故高达 75% 以上。因此,在这项工作中,我们详细研究了在矿化水-油环境中抑制腐蚀过程的有效性。文章的主要目的是研究不同成分和不同温度条件下水油介质中腐蚀过程的规律性,以便有效选择缓蚀机制和缓蚀剂类型。 目前,减少腐蚀过程影响的有效方法是使用缓蚀剂。不仅从作用效果的角度来看,而且从经济效益的角度来看,这也是一种权宜之计。在腐蚀环境中添加抑制剂是为了阻止或减少腐蚀过程。它们可以用作形成保护层的保护屏障,也可以用作防止氧化过程的吸收剂。今后,抑制剂类型的选择将取决于金属类型以及导致腐蚀发生和过程的反应条件。 目前,使用缓蚀剂被认为是降低金属结构腐蚀破坏强度的最有效方法。与此同时,要获得一种既能满足高效性、可制造性、毒理学安全性等要求,同时又在经济上可行的通用缓蚀剂是不可能的。在各种缓蚀剂中,有机缓蚀剂在保护石油工业设备的低合金钢方面显示出其有效性。 本研究使用了 St20 钢(最广泛用于制造石油管道和石油生产设备)作为腐蚀材料。通过添加醋酸溶液改变 pH 值。腐蚀程度用质量计量法测定。试验溶液的体积为 150 立方厘米,溶液的 pH 值用 5% 的醋酸溶液调节。烷基咪唑啉被用作抑制剂。 从研究结果来看,水溶液中的矿物成分在很大程度上影响着腐蚀速度。油的存在大大降低了腐蚀速度,这是由于油膜阻止了氧气进入系统,也是由于油中化学成分的腐蚀惰性。不过,研究还发现,随着羧酸含量的增加,油的存在丝毫不会影响腐蚀速度。可以说,烷基咪唑啉抑制剂在室温下显示出很强的保护能力,这与高温下的研究结果形成鲜明对比。
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Study of the effectiveness of inhibiting corrosion processes in mineralized water-oil environments
Corrosion is a phenomenon that strongly affects many industries. Everything related to metallurgy, shipbuilding, or the oil industry is negatively affected by corrosion processes. This is a big problem, because the number of industrial accidents due to corrosion reaches more than 75%. Therefore, in this work, the effectiveness of inhibition of corrosion processes in mineralized water-oil environments was investigated in detail. The main goal of the article is to study the regularity of corrosion processes in water-oil media of different composition and at different temperature regimes for effective selection of the inhibition mechanism and type of corrosion inhibitor. An effective method of reducing the impact of corrosion processes today is the use of inhibitors. This is expedient not only from the point of view of the effectiveness of the action, but also from the point of view of economic expediency. Inhibitors are added to corrosive environments in order to stop or reduce corrosion processes. They can be used as protective barriers that form a protective layer, and as absorbers that prevent oxidation processes. In the future, the type of inhibitor is selected depending on the type of metal and the conditions of the reactions responsible for the occurrence and course of corrosion. Currently, the use of corrosion inhibitors is recognized as the most effective way to reduce the intensity of corrosion destruction of metal structures. At the same time, it is impossible to obtain a universal inhibitor that meets the requirements of high efficiency, manufacturability, toxicological safety, and at the same time is obtained in an economically feasible way. Among various corrosion inhibitors, organic ones have shown their effectiveness in protecting low-alloy steels of oil industry equipment. Metal samples of St20 steel, the most widely used for the manufacture of oil pipelines and oil production equipment, were used as corroding materials in the study. The pH was changed by adding a solution of acetic acid. The degree of corrosion was determined by the massometric method. The volume of the test solution was 150 cm3, the pH of the solution was adjusted with a 5% acetic acid solution. Alkylimidozoline was used as an inhibitor. Judging by the research results, the mineral composition of the aqueous solution largely affects the rate of corrosion. The presence of oil significantly reduces the rate of corrosion due to both blocking the access of oxygen to the system by the oil film and due to the corrosion inertness of the chemical components of the oil. However, it was also found that with an increase in the content of carboxylic acids, the presence of oil does not affect the corrosion rate in any way. Arguably, the alkylamidazoline inhibitor showed a high degree of protection at room temperature, in contrast to studies at high temperatures.
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