对城市固体废物形态成分和模型类似物的热化学处理过程进行研究

Oleksandr Snihur, Yurii Marchuk, Oleksii Sezonenko, Viktoriia Kovbasyuk, Olena Ivanenko, Kyryl Nosachov
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引用次数: 0

摘要

文章强调,生活垃圾的处理和处置主要涉及人口稠密的大城市,这些城市每年都会积累数百万立方米的固体生活垃圾(MSW)。文章指出,固体废物的热处理方法是最先进的处理方法之一。这些方法的优点是可以显著减少处理材料的体积。当垃圾被焚烧时,其重量会减少 85-90%。除了减少垃圾的体积和质量,焚烧生活垃圾还可以获得额外的能源资源。城市生活垃圾的燃烧热量指标与褐煤的指标类似--从 1000 千卡/千克到 3000 千卡/千克不等。 迄今为止,现有的垃圾焚烧厂有许多缺点,其中最主要的是效率低。即使使用更先进的设备,热能的有效利用率也不超过 65%。 燃烧过程本身、灰渣的形成和组成受到很多因素的影响,首先是燃料的性质和特点、原材料的物理和化学性质、燃烧过程的参数、燃料的分散大小、反应器的类型以及工作区的氧气水平。 因此,选择热重法处理含碳废物的温度和压力范围、气体介质的加热速度对克服这种方法的缺点起着决定性作用。 文章的目的是开发一种热重装置,用于研究城市固体废物样品燃烧过程中动力学过程流的特殊性。 文章介绍了用于研究含碳替代燃料热化学处理过程的实验热重装置的开发情况,该装置具有广泛的可能性,可以研究技术参数对燃烧过程的影响。文中介绍了主要节点和测量系统、实验方法以及对所获数据的分析。 对固体废弃物的所有主要成分进行了一系列实验:木材、食物垃圾(土豆、肉类)、办公用纸和图表用纸、皮革、花园垃圾、Tetrapak、塑料。实验表明,各种成分的质量变化曲线的性质实际上并不取决于它们的化学成分,而主要取决于燃烧过程的阶段性进程,后者又取决于样品的加热速度,唯一的例外是塑料的燃烧。除塑料外,所有成分在达到开始燃烧的温度(~ 200-250,有时 300°С)后的氧化时间为 5-7 至 40-50 分钟,而塑料的强化燃烧在 1 分钟内结束。 据测定,灰烬的成分和热物理性质在对城市固体废物进行热化学处理的过程中起着重要作用,影响着城市固体废物作为燃料的比热值和该过程中气体产物的绝热温度值。
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Research of processes of thermochemical disposal of components of the morphological composition and model analogs of MSW
The article emphasizes that processing and disposal of household waste mainly concerns large densely populated cities, where millions of cubic meters of solid household waste (MSW) are accumulated annually. It was noted that thermal methods of solid waste disposal are among the most advanced methods of their processing. The advantage of these methods is a significant reduction in the volume of processed material. When waste is burned, its weight is reduced by 85-90%. In addition to reducing the volume and mass of waste, incineration of household waste allows you to obtain additional energy resources. Indicators of the amount of heat of combustion of MSW are similar to indicators of brown coal - from 1000 to 3000 kcal/kg. To date, existing waste incineration plants have a number of disadvantages, the main of which is low efficiency. The rate of useful use of thermal energy does not exceed 65%, even with the use of a more advanced property. The combustion processes themselves, the formation and composition of ash residues are affected by a large number of factors, starting with the properties and characteristics of the fuel, the physical and chemical properties of the raw materials, the parameters of the combustion process, the dispersed size of the fuel, the type of reactor, and the level of oxygen in the working area. Thus, the selection of the range of temperatures and pressures, the rate of heating of the gas medium for the thermogravimetric method of disposal of carbon-containing waste plays a decisive role in overcoming the shortcomings of this method. The purpose of the article is the development of a thermogravitational installation for studying the peculiarities of the flow of kinetic processes during the combustion of MSW samples. The article presents the development of an experimental thermogravitational unit for researching processes of thermochemical processing of carbon-containing alternative fuels with wide possibilities, which allows to study the influence of technological parameters on the combustion process. A description of the main nodes and the measurement system, the methodology of the experiment and the analysis of the obtained data is given. A series of experiments was conducted with all the main components of solid waste: wood, food waste (potatoes, meat), office and chart paper, leather, garden waste, tetrapak, plastic. It is shown that the nature of the mass change curves of various components practically does not depend on their chemical composition and is determined mainly by the staged course of the combustion process, and the latter, in turn, by the rate of heating of the sample, the only exception being the combustion of plastic. The oxidation time of all components, except plastic, after reaching the temperature of the beginning of combustion (~ 200-250, sometimes 300 °С) is from 5-7 to 40-50 minutes, while the intensive combustion of plastic ends in 1 minute. It was determined that the composition and thermophysical properties of ash play an important role in the processes of thermochemical disposal of MSW, affecting the value of the specific calorific value of MSW as a fuel and the value of the adiabatic temperature of the gaseous products of the process.
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