研究添加纳米粒子对汽油断裂指数和密度的影响

M. Gökmen, Mehmet Fatih Parlak, Hasan Aydoğan
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摘要

本研究探讨了将粒径为 12 纳米、纯度为 99.9% 的 Al2O3 和 TiO2 纳米粒子用作汽油燃料添加剂的问题。采用 3 级因子设计技术制备了燃料混合物,并测定了密度和折射率值。由于 Al2O3 纳米粒子的表面积大,其密度增加了 0.17%(3.5 ppm)和 1.22%(7 ppm),而 TiO2 纳米粒子的密度增加了 0.22%(3.5 ppm)和 1.26%(7 ppm)。据观察,表面积较大的纳米粒子对密度的影响较小。Al2O3 纳米粒子的折射率值降低了 0.11%(3.5 ppm)和 0.14%(7 ppm),TiO2 纳米粒子的折射率值降低了 0.21%(3.5 ppm)和 0.24%(7 ppm)。这项研究强调了粒度、纯度和表面积在纳米颗粒选择中的重要性。根据评估和初步测试,纳米颗粒含量超过 15 ppm 时,在燃料中会出现团聚趋势。将总浓度限制在百万分之 15 至关重要,尤其是像 Al2O3 这样具有高表面积的纳米颗粒,这样才能获得均匀的燃料。
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NANOPARTİKÜL İLAVESİNİN BENZİNİN KIRILMA İNDİSİ VE YOĞUNLUĞU ÜZERİNDEKİ ETKİSİNİN ARAŞTIRILMASI
In this study, the use of Al2O3 and TiO2 nano particles with a size of 12 nm and a purity of 99.9% as gasoline fuel additives was investigated. Fuel mixtures were prepared using a 3-level factorial design technique, and density and refractive index values were determined. Al2O3 nano particles, due to their high surface area, increased the density by 0.17% (3.5 ppm) and 1.22% (7 ppm), while TiO2 nano particles increased the density by 0.22% (3.5 ppm) and 1.26% (7 ppm). It was observed that the nano particle with a higher surface area had a less significant effect on density. The refractive index values decreased by 0.11% (3.5 ppm) and 0.14% (7 ppm) for Al2O3 nano particles, and by 0.21% (3.5 ppm) and 0.24% (7 ppm) for TiO2 nano particles. This study highlighted the importance of particle size, purity, and surface area in the selection of nano particles. Based on the evaluations and preliminary tests, nano particle levels above 15 ppm exhibited a tendency for agglomeration in the fuel. It is crucial to limit the total concentration to 15 ppm, especially for nano particles with a high surface area like Al2O3, to achieve homogeneous fuel.
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