以离子液体和深共晶溶剂为电解质的钛石墨电极电池的效率

Bassam Baqer Hasan, Taghried Ali Salman, Asmaa Kadim Ayal
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引用次数: 0

摘要

在开始生产之前,必须考虑几个因素,包括电池的价格、有效性和环保性。离子液体和深共晶溶剂在用作钛石墨电池的电解质时取得了巨大成功,尤其是与添加剂结合使用时,添加剂可通过降低这些液体的高粘度来增强其导电性。以 DCM 作为添加剂评估 AlCl3-氯乙酰胺 IL 的放电电压时发现,电压为 1.16V,内阻为 11 欧姆。这些电化学电池表现出了耐人寻味的反应。此外,当使用以去离子水为添加剂的 CaCl2.2H2O:乙酰胺 DES 时,电池电压为 0.97V,内阻为 23 欧姆。此外,这些电池在充电和放电过程中都表现出了热稳定性,这可归因于离子物种的浓度和质量。此外,还使用 FESEM 和 EDXA 设备检查了钛电极的表面,以评估离子液体和 DES 对这些电极的影响。
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The Efficiency of Titanium-Graphite Electrode Cells in the Presence of Ionic Liquids and Deep Eutectic Solvents as Electrolytes
Prior to the start of production, several factors must be considered, including the price, effectiveness, and environmental friendliness of batteries. Ionic liquids and deep eutectic solvents have shown significant success when employed as electrolytes with Titanium-graphite cells, especially when combined with additives that enhance their conductivity by reducing the high viscosity of these liquids. Evaluating the discharge voltage of the AlCl3-chloroacetamide IL with DCM as an additive revealed a voltage of 1.16V and an internal resistance of 11 Ohm. These electrochemical cells exhibited an intriguing response. Otherwise, when utilizing CaCl2.2H2O: Acetamide DES with DI water as an additive, the cell voltage measured 0.97V,with an internal resistance of 23 Ohm. Moreover, these cells demonstrated thermal stability during both charging and discharging processes, which can be attributed to the concentration and quality of the ionic species. Furthermore, the surfaces of the Titanium electrodes were examined using FESEM and EDXA equipment to assess the impact of the ionic liquid and DES on these electrodes.
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