激光诱导等离子体制备的氧化锆:氧化锌纳米粒子的合成与表征

Marwa A. Mohammed, Hassan N. Hashim
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摘要

在这项研究中,我们利用脉冲激光沉积技术(PLD)观察了激光能量如何影响混合比(0.1、0.2、0.3 和 0.4)的 ZrO2:ZnO 薄膜的结构和光学特性。使用的掺钕钇钕石榴石(Nd:YAG)激光波长为 1064 nm,脉宽为 9 ns,能量为 320 mJ。X 射线衍射图样显示,所有薄膜都具有多晶六方晶体结构。用原子力显微镜测量了薄膜表面的形貌,结果显示平均粗糙度和晶粒尺寸都有所增加。对每种薄膜的光学特性进行分析后发现,当激光能量为 320 mJ 时,薄膜在 200-1000 nm 波长范围内的吸收系数增大,间接允许跃迁的光学能隙值在 3.58 和 3.4eV 之间减小。
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Synthesis and Characterization ofZrO2:ZnO Nanoparticles Prepared by Laser Induced Plasma
n this research, we looked at how laser energy affected the structural and optical characteristics of ZrO2:ZnO thin films at mixing ratios(0.1, 0.2, 0.3and0.4) that were applied on glass slides using the pulse laser deposition technique (PLD). Nd:YAG laser was utilized with a wavelength of 1064 nm, a pulse width of 9 ns, and an energy of 320 mJ. The X-ray diffraction patterns revealed that all the films had a polycrystalline hexagonal crystal structure. AFM was used to measure the topography of the film's surface, and the results revealed that the average roughness and grain size increased. After analyzing the optical characteristics of each film, it was discovered that the absorption coefficient in the 200–1000 nm wavelength range increases at 320 mJ of laser energy and that the optical energy gap value for indirect permitted transitions decreases between 3.58 and 3.4eV
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