{"title":"嵌钛纳米复合材料激发离子交换特性，应对水生环境中的有毒重金属污染物","authors":"T. Kodispathi, K. J. Mispa","doi":"10.1080/01496395.2023.2280507","DOIUrl":null,"url":null,"abstract":"ABSTRACT Nano-sized composite ion-exchanger can be applied as an electrochemically switchable ion-exchanger for waste water treatment, especially in the separation of heavy metal ions from the polluted aquatic system. Advanced polyaniline/Ti(IV) iodomolybdate nanocomposite ion-exchanger have been synthesized by in-situ chemical oxidation polymerization shows better ion-exchange capacity than individual inorganic counterpart. The physico-chemical characterization was done by FT-IR, XRD, simultaneous TGA-DTA, SEM, HR-TEM and electrochemical impedance studies. According to impedance/dielectrical study, it has high resistivity in the low-frequency region. The distribution studies and binary separation revealed that the ion-exchange material is highly selective for Pb2+, which is a most important environmental pollutant. Thus, PANI/TIM nanocomposite ion-exchanger can be used for Pb(II) ion-selective membrane for the treatment of aquatic pollutants in future.","PeriodicalId":21680,"journal":{"name":"Separation Science and Technology","volume":"1 1","pages":"2932 - 2949"},"PeriodicalIF":2.3000,"publicationDate":"2023-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Titanium-embedded nanocomposite material stimulates ion-exchange characteristics to deal with toxic heavy metal pollutants in aquatic environment\",\"authors\":\"T. Kodispathi, K. J. Mispa\",\"doi\":\"10.1080/01496395.2023.2280507\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"ABSTRACT Nano-sized composite ion-exchanger can be applied as an electrochemically switchable ion-exchanger for waste water treatment, especially in the separation of heavy metal ions from the polluted aquatic system. Advanced polyaniline/Ti(IV) iodomolybdate nanocomposite ion-exchanger have been synthesized by in-situ chemical oxidation polymerization shows better ion-exchange capacity than individual inorganic counterpart. The physico-chemical characterization was done by FT-IR, XRD, simultaneous TGA-DTA, SEM, HR-TEM and electrochemical impedance studies. According to impedance/dielectrical study, it has high resistivity in the low-frequency region. The distribution studies and binary separation revealed that the ion-exchange material is highly selective for Pb2+, which is a most important environmental pollutant. Thus, PANI/TIM nanocomposite ion-exchanger can be used for Pb(II) ion-selective membrane for the treatment of aquatic pollutants in future.\",\"PeriodicalId\":21680,\"journal\":{\"name\":\"Separation Science and Technology\",\"volume\":\"1 1\",\"pages\":\"2932 - 2949\"},\"PeriodicalIF\":2.3000,\"publicationDate\":\"2023-11-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Separation Science and Technology\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1080/01496395.2023.2280507\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Separation Science and Technology","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1080/01496395.2023.2280507","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Titanium-embedded nanocomposite material stimulates ion-exchange characteristics to deal with toxic heavy metal pollutants in aquatic environment
ABSTRACT Nano-sized composite ion-exchanger can be applied as an electrochemically switchable ion-exchanger for waste water treatment, especially in the separation of heavy metal ions from the polluted aquatic system. Advanced polyaniline/Ti(IV) iodomolybdate nanocomposite ion-exchanger have been synthesized by in-situ chemical oxidation polymerization shows better ion-exchange capacity than individual inorganic counterpart. The physico-chemical characterization was done by FT-IR, XRD, simultaneous TGA-DTA, SEM, HR-TEM and electrochemical impedance studies. According to impedance/dielectrical study, it has high resistivity in the low-frequency region. The distribution studies and binary separation revealed that the ion-exchange material is highly selective for Pb2+, which is a most important environmental pollutant. Thus, PANI/TIM nanocomposite ion-exchanger can be used for Pb(II) ion-selective membrane for the treatment of aquatic pollutants in future.
期刊介绍：
This international journal deals with fundamental and applied aspects of separation processes related to a number of fields. A wide range of topics are covered in the journal including adsorption, membranes, extraction, distillation, absorption, centrifugation, crystallization, precipitation, reactive separations, hybrid processes, continuous separations, carbon capture, flocculation and magnetic separations. The journal focuses on state of the art preparative separations and theoretical contributions to the field of separation science. Applications include environmental, energy, water, and biotechnology. The journal does not publish analytical separation papers unless they contain new fundamental contributions to the field of separation science.
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