用橘皮作为低成本吸附剂去除水溶液中的甲基橙

Ahmed Lawal, Abdulhafeez Abdulsalam
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摘要

本研究旨在评估使用橘子皮作为低成本吸附剂去除水溶液中甲基橙(MO)的可行性。通过扫描电子显微镜(SEM)和傅立叶变换红外光谱(FTIR)对橘子皮吸附剂进行表征,以确定其吸附前后的特性。为了研究接触时间、吸附剂用量、粒度和初始染料浓度等各种参数对吸附过程的影响,进行了一系列批量吸附实验。在每种情况下,在保持所有其他参数不变的情况下,改变相关参数的值。结果表明,当接触时间为 90 分钟、吸附剂用量为 0.5 克、粒径小于 63 微米、初始浓度为 300 毫克/升时,吸附剂对染料的去除率最高。此外,吸附率随着接触时间、吸附剂用量和初始浓度的增加而增加,但随着吸附剂粒度的增加而降低。使用紫外可见分光光度计分析了甲基橙的浓度。实验平衡数据使用 Langmuir 和 Freundlich 等温线模型进行分析。Langmuir 等温线对实验数据的拟合效果最好,相关系数为 0.9964,最大吸附容量为 17.69 毫克/克。
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Removal of Methyl Orange from Aqueous Solution Using Orange Peel as a Low Cost Adsorbent
The objective of this research was to evaluate the feasibility of using orange peels as a low-cost adsorbent to remove methyl orange (MO) from water solutions. The orange peel adsorbent underwent characterization through Scanning Electron Microscopy (SEM) and Fourier Transform Infrared (FTIR) Spectroscopy to determine its properties before and after adsorption. A series of batch adsorption experiments were carried out to investigate the effects of various parameters such as contact time, adsorbent dosage, particle size, and initial dye concentration on the adsorption process. In each case, varying the value of the parameter of interest while keeping all other parameters constant. Results revealed that the highest removal of the dye from the adsorbent was achieved at a contact time of 90 min, the adsorbent dosage of 0.5 g, a particle size of less than 63 µm, and an initial concentration of 300 mg/L. Furthermore, the adsorption rate increased with increasing contact time, adsorbent dosage, and initial concentration, while it decreased with increasing particle size of the adsorbent. Concentrations of methyl orange were analyzed using a UV-Vis spectrophotometer. The experimental equilibrium data was analyzed using Langmuir and Freundlich isotherm models. The Langmuir isotherm provided the best fit for the experimental data with a correlation coefficient value of 0.9964 and a maximum adsorption capacity of 17.69 mg/g.
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