根据分光光度法数据得出的果树和浆果灌木叶粉的吸附能力

Evgenia Vladimirovna Tovstik, Andrey Vital'yevich Zakharov
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摘要

本文介绍了果树和浆果树叶粉末对水溶液中亚甲蓝的吸附研究结果。吸附能力是用为活性炭开发的方法测定的。线性和重复性评估结果证实了分光光度分析法适用于测定叶粉的吸附能力。分析了 Langmuir、Freundlich 和 BET 模型在描述粒径为 0.25 毫米的叶粉混合物上亚甲基蓝实验吸附等温线时的适用性。通过比较相关系数,结果表明 Langmuir 和 BET 模型比 Freundlich 模型能更好地描述染料在粉末上的吸附实验数据。利用图解法得出了 Langmuir 模型(KL=1.17 升/毫摩尔)和 BET 模型(KBET=319.75 克/毫摩尔)的吸附常数值。在所研究的果树中,樱桃叶粉的吸附容量最大(0.532±0.017 mmol/g),而在浆果灌木--秋海棠、黑醋栗和醋栗叶粉中,樱桃叶粉的吸附容量分别为(0.529±0.002;0.472±0.011 和 0.479±0.004 mmol/g)。根据对所得结果与活性炭吸附容量值(0.704 mmol/g)的比较评估,得出了果树和浆果树叶粉末适合从水溶液中去除亚甲基蓝的结论。
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ADSORPTION CAPACITY OF LEAF POWDER OF FRUIT TREES AND BERRY BUSHES ACCORDING TO SPECTROPHOTOMETRY DATA
The results of the study of the adsorption of methylene blue from aqueous solutions by the powder of the leaves of fruit trees and berry bushes are presented. The adsorption capacity was determined by the method developed for activated carbon. The suitability of the spectrophotometric analysis method for determining the adsorption capacity of leaf powder was confirmed by the results of linearity and repeatability assessment. The applicability of the Langmuir, Freundlich and BET models to describe experimental adsorption isotherms of methylene blue on a powder mixture of leaves with a particle size of 0.25 mm is analyzed. By comparing the correlation coefficients, it is shown that the Langmuir and BET model describe experimental data on dye adsorption on powder better than the Freundlich model. The values of adsorption constants for the Langmuir model (KL=1.17 l/mmol) and BET (KBET=319.75 g/mmol) were obtained using the graphical method. Among the studied fruit trees, cherry leaf powder had the greatest adsorption capacity (0.532±0.017 mmol/g), among berry bushes – aronia, blackcurrant and gooseberry leaf powder (0.529±0.002; 0.472±0.011 and 0.479±0.004 mmol/g). Based on a comparative assessment of the results obtained with the value of the adsorption capacity of activated carbon (0.704 mmol/g), a conclusion was made about the suitability of the powder of the leaves of fruit trees and berry bushes for the removal of methylene blue from aqueous solutions.
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