碳纳米管增强丙烯腈-丁二烯-苯乙烯/聚对苯二甲酸丁二醇酯共混物的增韧行为和形态研究

Milad Aghalari, Farshad Heidari, K. Shelesh‐Nezhad, T. Chakherlou
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摘要

丙烯腈-丁二烯-苯乙烯(ABS)和聚对苯二甲酸丁二醇酯(PBT)聚合物是塑料工业中广泛使用的聚合物。在本研究中,由于 PBT 聚合物具有良好的流动性和一些优越的机械特性,因此将其作为第二相添加到 ABS 聚合物中。在 ABS/PBT 聚合物混合物(80/20)中加入碳纳米管(CNT)作为增强材料。拉伸、弯曲和冲击等力学测试的标准样品采用注塑成型法制作,断裂测试的标准样品采用热压法制作。采用基本断裂功(EWF)法检测断裂韧性。在 ABS 中加入 PBT 提高了其拉伸和弯曲强度,但降低了 ABS 的冲击强度和断裂韧性。在 ABS/PBT 混合物中添加碳纳米管提高了其拉伸和弯曲强度、抗冲击性以及断裂韧性。显微测试结果表明,碳纳米管在聚合物混合物中的分布相对均匀。此外,形态观察结果表明,碳纳米管与聚合物基体之间的粘附性相当好。重要的是,对断裂试样断裂部分的研究表明,与 ABS/PBT 聚合物混合物相比,含有碳纳米管的纳米复合材料更倾向于韧性破坏。
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An investigation on the toughening behavior and morphology of acrylonitrile butadiene styrene/polybutylene terephthalate blends reinforced by carbon nanotubes
Acrylonitrile butadiene styrene (ABS) and polybutylene terephthalate (PBT) polymers are widely exploited polymers in the plastics industry. In this research, PBT polymer is added into ABS polymer as a second phase due to its good fluidity and some superior mechanical characteristics. Carbon nanotubes (CNTs) are added as a reinforcement into the ABS/PBT polymer blend (80/20). Standard samples of mechanical tests including tensile, flexural, and impact were made by injection molding and standard samples of fracture tests were made by hot press method. The essential work of fracture (EWF) method was used to check fracture toughness. The presence of PBT into ABS improved its tensile and flexural strength while it diminished the impact strength and fracture toughness of ABS. The addition of carbon nanotubes into ABS/PBT blends increased its tensile and flexural strength, impact resistance as well as fracture toughness. The results of microscopic tests demonstrate a relatively uniform distribution of carbon nanotubes in the polymer blend. In addition, the morphological observations illustrate a rather proper adhesion between carbon nanotubes and the polymeric matrix. As importantly, investigations on the fractured sections of fracture specimens revealed that the nanocomposites containing CNTs have a tendency toward a ductile failure in comparison with ABS/PBT polymer blend.
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