摩洛哥 Mohammedia 省地表水体的水质、重金属污染和健康风险评估

IF 9 Q1 ENVIRONMENTAL SCIENCES Environmental Chemistry and Ecotoxicology Pub Date : 2024-01-01 DOI:10.1016/j.enceco.2023.12.002
Rachida El Morabet , Larbi Barhazi , Soufiane Bouhafa , Mohammed Abdullah Dahim , Roohul Abad Khan , Abdullah Mohammed Dahim
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引用次数: 0

摘要

有关摩洛哥地表水体的研究工作大多局限于物理化学和生物浓度方面。因此,本研究通过评估摩洛哥穆罕默迪亚省地表水体的重金属污染及其相关风险评估,填补了现有的研究空白。共对 22 份水样进行了理化因素和重金属评估。分析的参数包括 pH 值、温度 (T)、电导率 (EC)、溶解固体总量 (TDS)、钙 (Ca2+)、钠 (Na+)、钾 (K+)、氨 (NH+)、溶解氧 (DO)、硫酸盐 (SO42-)、亚硝酸盐 (NO2-)、硝酸盐 (NO3-)、磷酸盐 (PO43-)、总磷酸盐 (TP)、总凯氏氮 (TKN)、镉 (Cd)、铜 (Cu)、铁 (Fe)、铅 (Pb) 和锌 (Zn)。总体水质(Ow)和污染状况定量展示了水质和污染情况。为进行健康风险评估,对致癌和非致癌风险进行了估算。Ca2+ 是含量最高的阳离子,SO43- 是含量最高的阴离子。重金属浓度在允许范围内。除 NH+ 外,其他参数均符合标准。这表明水质属于 "高度污染">2.5。污染指数(PI)显示,S3、S4、S5 和 S6 样点的污染程度较高(14-74)。此外,铅也是导致水质恶化的重要因素,在 S1、S2 和 S3 采样点,铅的单项污染指数从 1 到 12 不等。对于重金属危害,即对健康的不利影响,各样本点的危害商数(HQ)(0.0002-0.01)为 1,危害指数(HI)(0.007-0.01)也有类似趋势。推断其对消费者的健康没有重大的非致癌影响。发现 CD、Cu、Pb 和 Zn 的致癌风险 (CR) 在可接受范围内,即 10-4 至 10-6。在 S2、S3 和 S4 点,铁的致癌指数(CI)超过了可接受的限度,数值从 1 × 10-3 到 7.9 × 10-3 不等。因此,根据这项研究的结果,目前的水质不适合直接饮用。因此,研究建议在饮用之前对地表水体进行处理。
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Water quality, heavy metal contamination and health risk assessment of surface water bodies of Mohammedia prefecture, Morocco

Research work on surface water bodies in Morocco has been in majority restricted to physicochemical and biological concentration. Hence, this study was conducted to address the existing research gap by evaluating heavy metal contamination and its associated risk assessment in surface water bodies, in Mohammedia prefecture, Morocco. A total of 22 water samples were evaluated regarding physicochemical factors and heavy metals. The parameters analyzed are pH, temperature (T), electrical conductivity (EC), total dissolved solids (TDS), calcium (Ca2+), Sodium (Na+), Potassium (K+), Ammonia (NH+), dissolved oxygen (DO), Sulphate (SO42−), nitrite (NO2−), nitrate (NO3−), phosphate (PO43−), total phosphate (TP), total kjeldahl nitrogen (TKN), cadmium (Cd), copper (Cu), Iron (Fe), lead (Pb), and zinc (Zn). Overall water quality (Ow) and status of contamination presented the water quality and pollution quantitatively. Carcinogenic and noncarcinogenic risks were estimated for health risk assessment. Ca2+ was the most abundant cation, and SO43− was the most abundant anion. Heavy metal concentrations were within permissible limits. Ow was good in terms of being suitable for parameters, i.e., <1 except for NH+. Which indicated water quality in the category of “highly polluted” >2.5. Pollution index (PI) indicated high pollution (14–74) at S3, S4, S5, and S6 sample points. In addition, Pb was a significant contributor to deteriorating water quality, with individual contributions ranging from 1 to 12 at sites S1, S2, and S3. For heavy metal hazards, i.e., adverse health effects, Hazard Quotient (HQ) (0.0002–0.01) was <1 for sample points, and Hazard Index (HI) (0.007–0.01) had a similar trend. They were inferring no significant non-carcinogenic health impact on its consumers. Carcinogenic risk (CR) was found to be within acceptable limits for CD, Cu, Pb, and Zn, i.e., 10−4 to 10−6. At points S2, S3, and S4, the carcinogenic index (CI) was above the acceptable limit, with values ranging from 1 × 10−3 to 7.9 × 10−3 attributed to Fe. Therefore, according to the findings of this research, the water quality is not suitable for direct consumption in its current state. Hence the study recommends treatment of surface water bodies prior to consumption.

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