Ali Wang, Yoshiaki Shuku, R. Suizu, Neil Robertson, K. Awaga
{"title":"合成三核混合配体金属二硫环戊烯配合物的新型三联苯衍生保护二硫环戊烯配体前体","authors":"Ali Wang, Yoshiaki Shuku, R. Suizu, Neil Robertson, K. Awaga","doi":"10.1093/chemle/upad051","DOIUrl":null,"url":null,"abstract":"\n We synthesized a novel triptycene analogue, 3,3',3'',3''',3'''',3'''''-((triptycene-2,3,6,7,14,15-hexayl)hexakis(sulfanediyl))hexapropanenitrile (3), which served as a valuable precursor for the triptycene-derived tris-bidentate bridging dithiolene ligand, triptycene-2,3,6,7,14,15-hexakis(thiolate) (4), following the removal of the cyanoethyl moiety protection group. We determined the molecular and crystal structures of compound 3 and confirmed its capacity to yield compound 4. By reacting 3 with [NiCl2(BPY)] and [PtCl2(BPY)] (BPY: 2,2'-bipyridine) in methanol, we obtained crude samples of [Ni3(4)(BPY)3] and [Pt3(4)(BPY)3], respectively.","PeriodicalId":9862,"journal":{"name":"Chemistry Letters","volume":"3 2","pages":""},"PeriodicalIF":1.4000,"publicationDate":"2024-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of a Novel Triptycene-derived Protected Dithiolene Ligand Precursor for Tri-nuclear Mixed Ligand Metal Dithiolene Complexes\",\"authors\":\"Ali Wang, Yoshiaki Shuku, R. Suizu, Neil Robertson, K. Awaga\",\"doi\":\"10.1093/chemle/upad051\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"\\n We synthesized a novel triptycene analogue, 3,3',3'',3''',3'''',3'''''-((triptycene-2,3,6,7,14,15-hexayl)hexakis(sulfanediyl))hexapropanenitrile (3), which served as a valuable precursor for the triptycene-derived tris-bidentate bridging dithiolene ligand, triptycene-2,3,6,7,14,15-hexakis(thiolate) (4), following the removal of the cyanoethyl moiety protection group. We determined the molecular and crystal structures of compound 3 and confirmed its capacity to yield compound 4. By reacting 3 with [NiCl2(BPY)] and [PtCl2(BPY)] (BPY: 2,2'-bipyridine) in methanol, we obtained crude samples of [Ni3(4)(BPY)3] and [Pt3(4)(BPY)3], respectively.\",\"PeriodicalId\":9862,\"journal\":{\"name\":\"Chemistry Letters\",\"volume\":\"3 2\",\"pages\":\"\"},\"PeriodicalIF\":1.4000,\"publicationDate\":\"2024-01-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemistry Letters\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1093/chemle/upad051\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry Letters","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1093/chemle/upad051","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Synthesis of a Novel Triptycene-derived Protected Dithiolene Ligand Precursor for Tri-nuclear Mixed Ligand Metal Dithiolene Complexes
We synthesized a novel triptycene analogue, 3,3',3'',3''',3'''',3'''''-((triptycene-2,3,6,7,14,15-hexayl)hexakis(sulfanediyl))hexapropanenitrile (3), which served as a valuable precursor for the triptycene-derived tris-bidentate bridging dithiolene ligand, triptycene-2,3,6,7,14,15-hexakis(thiolate) (4), following the removal of the cyanoethyl moiety protection group. We determined the molecular and crystal structures of compound 3 and confirmed its capacity to yield compound 4. By reacting 3 with [NiCl2(BPY)] and [PtCl2(BPY)] (BPY: 2,2'-bipyridine) in methanol, we obtained crude samples of [Ni3(4)(BPY)3] and [Pt3(4)(BPY)3], respectively.
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