揭开用于先进传感应用的 CdSnO3 纳米粒子的多面性面纱

P. Usha, S. Ramesh, J. P, Mariappan R
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引用次数: 0

摘要

本研究介绍了在 400、500 和 600°C 不同沉积温度下薄膜 CdSnO3 纳米粒子的合成和表征。制备的样品分别通过 X 射线衍射 (XRD)、傅立叶变换红外光谱 (FTIR)、扫描电子显微镜 (SEM)、能量色散 X 射线 (EDX) 光谱、透射电子显微镜 (TEM) 以及光学和氨气传感特性进行了表征。X 射线衍射证实了其正方晶体结构,其突出的峰值分别对应于 (111)、(112)、(103)、(130) 和 (133) 平面。平均晶粒大小为 84 纳米。扫描电子显微镜显示了随着基底温度的变化而发生的形态变化。EDX 光谱显示了元素组成的变化,突出显示了 CdSnO3 的非全度性。TEM 图像显示了较大的球形纳米颗粒,具有清晰的晶格边缘。傅立叶变换红外光谱证实了 Cd-O 和 Sn-O 键的存在。光学特性表明,计算得出的带隙随温度升高而减小。气体传感测试表明其对氨气浓度非常敏感,反应受氨气浓度的影响。总之,CdSnO3 纳米粒子因其可调整的特性和定制性能的潜力,有望应用于各种领域。
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Unveiling the Versatile Realm of CdSnO3 Nanoparticles for Advanced Sensing Applications
This study presents the synthesis and characterization of thin-film CdSnO3 nanoparticles at different deposition temperatures of 400, 500, and 600°C. The prepared samples were characterized by X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), energy-dispersive X-ray (EDX) spectroscopy, transmission electron microscopy (TEM) and optical and ammonia gas sensing properties, respectively. XRD confirms the orthorhombic crystal structure, with prominent peaks corresponding to the (111), (112), (103), (130), and (133) planes. The mean crystallite size is determined to be 84 nm. SEM reveals morphological changes with varying substrate temperatures. EDX spectroscopy shows elemental composition variations, highlighting non-stoichiometric CdSnO3. TEM images depict larger spherical nanoparticles with clear lattice fringes. FTIR spectra confirm the presence of Cd-O and Sn-O bonds. Optical properties yield a calculated band gap was decreased with increase in temperature. Gas sensing tests demonstrate significant sensitivity to ammonia gas concentrations, with responses affected by ammonia concentrations. Overall, CdSnO3 nanoparticles show promise for applications in diverse fields due to their tunable properties and potential for tailored performance.
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