用废丙烯腈-丁二烯-苯乙烯进行三维印刷:加工和表征

Vishal Mishra, S. Negi, Simanchal Kar
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摘要

对丙烯腈-丁二烯-苯乙烯(ABS)等废旧塑料进行三维(3D)打印具有挑战性,因为多次加热循环和不规则冷却会导致 3D 打印结构中的应力累积,从而严重影响中间结构和纤维间的结合强度。因此,本研究展示了利用 ABS 废料通过 3D 打印技术打印高质量部件的能力。实验选择了不同重量比例(100、90/10、80/20、70/30、60/40、50/50)的回收 ABS(RABS)/原始 ABS(VABS)。实验发现,在 RABS 中增加 VABS 的含量可明显改善样品的物理性能。与 100% 的 RABS 样品相比,由于在 RABS 中掺入了 VABS,弯曲强度(Sf)、弯曲模量(Ef)和断裂功(WOF)的平均值分别提高了 11.49%、5.45% 和 17.31%。同样,杨氏模量(E)、屈服拉伸强度(Ty)和极限拉伸强度(UTS)的平均增幅分别为 7.71%、5.19% 和 3.51%。用 50% RABS/50% VABS 混合物印制的样品显示出比其他样品更优越的机械性能,90% RABS/10% VABS 和 80% RABS/20% VABS 的性能也非常接近 100% VABS 样品。因此,这项研究为利用 3D 打印技术可持续地利用废弃 ABS 提供了独特的机会。
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Three-dimensional printing with waste acrylonitrile butadiene styrene: Processing and characterization
Three-dimensional (3D) printing of waste plastic such as acrylonitrile butadiene styrene (ABS) is challenging because multiple heating cycles and irregular cooling cause accumulation of stress in 3D-printed structures, which significantly affects mesostructured and fiber-to-fiber bond strength. Hence, this study demonstrates the ability to print high-quality parts via 3D printing using ABS waste. The different weight proportions (100, 90/10, 80/20, 70/30, 60/40, 50/50) of recycled ABS (RABS)/virgin ABS (VABS) are selected for experimentation. It is found that increasing VABS content in RABS significantly improved the physical properties of samples. Due to VABS blending in RABS, the average enhancement in flexural strength (Sf), flex modulus (Ef), and work of fracture (WOF) are 11.49%, 5.45%, and 17.31%, respectively, when compared with 100% RABS samples. Similarly, the average increase in Young’s modulus (E), tensile strength at yield (Ty), and ultimate tensile strength (UTS) are 7.71%, 5.19%, and 3.51%, respectively. The samples printed with 50% RABS/50% VABS blends show superior mechanical properties than others, also the properties of 90% RABS/10% VABS and 80% RABS/20% VABS are very close to 100% VABS samples. Hence, this study provides unique opportunities for the sustainable use of waste ABS using 3D printing technology.
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