将工业副产品中的浓缩蛋白质升级再造为聚氨酯木材粘合剂

Alex Mary, Pierre Blanchet, S. Pepin, Julien Chamberland, V. Landry
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引用次数: 0

摘要

木结构通常依靠合成粘合剂来获得强度和多功能性。然而,与这些粘合剂的化学成分有关的环境问题促使人们寻找更环保的粘合剂。研究人员探索用木质素、单宁酸和蛋白质等天然原料来替代石油基成分。在这些替代品中,蛋白质作为生物大分子,因其能够增强与木材基材的粘合力而得到认可。本研究考虑开发基于蛋白质的粘合剂,其来源多种多样,包括大豆粉、微酿酒厂废谷物、虾壳和脱脂奶粉。将这些原料置于弱碱性条件下可产生浓缩蛋白质。所得粘合剂的蛋白质含量分别为 5%、10%、15% 和 20%。研究结果表明,在聚氨酯粘合剂系统中加入蛋白质不仅能保持粘合剂的性能,还能提高粘合剂的性能。这种增强包括更深入地渗透到木材基材中,并全面提高机械强度。这些结果表明,蛋白质有望成为粘合剂配方中石油基多元醇的可持续替代品。
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Upcycling of protein concentrates from industrial byproducts into polyurethane wood adhesives
Wood structures generally rely on synthetic adhesives for their strength and versatility. However, environmental concerns linked to the chemical composition of these adhesives have stimulated the search for more environmentally friendly adhesives. Researchers have explored replacing petroleum-based constituents with natural raw materials such as lignins, tannins, and proteins. Of these alternatives, proteins, being biological macromolecules, are recognized for their capacity to enhance adhesion to wood substrates. This study considered the development of protein-based adhesives derived from diverse sources, including soybean meal, microbrewery spent grains, shrimp shells, and skim milk powder. These raw materials were subjected to mild alkaline conditions to yield protein concentrates. The resulting adhesives were formulated at various protein content levels: 5%, 10%, 15%, and 20%. The study’s findings showed that the incorporation of proteins into the polyurethane adhesive system not only can preserve but also augment adhesive performance. This enhancement encompasses deeper penetration into wood substrates and an overall improvement in mechanical strength. These results underscore the promise of proteins as a sustainable alternative to petroleum-based polyols in adhesive formulations.
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