[Me3N(C6H3(CF3)2)][BF4]和[Me3N(C6H3(CH3)2)][BF4]，作为非共价超分子组装的潜在合成物

Zeitschrift für Naturforschung B Pub Date : 2024-01-01 DOI:10.1515/znb-2023-0095

J. R. Schmid, Anja Wiesner, P. Voßnacker, Martin Jansen, Sebastian Riedel

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引用次数: 0

摘要

摘要利用市售起始材料合成了[Me3N(C6H3(CF3)2)][BF4]和[Me3N(C6H3(CH3)2)][BF4]化合物，并通过单晶 X 射线衍射、核磁共振、红外光谱和拉曼光谱以及质谱对其进行了全面表征。由于这两种铵阳离子在固态下的结构引导特性，它们在晶体工程中都显示出了应用潜力。

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[Me3N(C6H3(CF3)2)][BF4] and [Me3N(C6H3(CH3)2)][BF4], as potential synthons for non-covalent supramolecular assembly

Abstract The compounds [Me3N(C6H3(CF3)2)][BF4] and [Me3N(C6H3(CH3)2)][BF4] were synthesized from commercially available starting materials and fully characterized by single-crystal X-ray diffraction, NMR, IR and Raman spectroscopy, as well as mass spectrometry. Both ammonium cations show potential for applications in crystal engineering due to their structure directing properties in the solid state.

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Zeitschrift für Naturforschung B

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