{"title":"(E)-N′(3,5-二叔丁基-2-羟基苯齐亚烯)-2-羟基苯甲酰肼铜 (II) 复合物及其杀菌和杀真菌活性","authors":"Perizad Amrulla Fatullayeva, Ajdar Akper Medjidov, Rayyat Huseyn Ismayilov, Asim Sabri Abdullayev, Sevinc Rafiq Lahicova, Gulu Qanimet Abbasova, Esmira Arif Aga Quliyeva, Mahammad Allahverdi Bayramov","doi":"10.1007/s11243-023-00568-1","DOIUrl":null,"url":null,"abstract":"<div><p>Mononuclear complexes of Copper(II) with (<i>E)-N′</i>(3,5-di-tert-butyl-2-hydroxybenzili- dene)-2-hydroxybenzohydrazide (H<sub>3</sub>sahz)<sub>2</sub>, Cu(Hsahz)(H<sub>2</sub>O) and Cu(Hsahz)(DMF) were synthesized. The structure of the complexes was studied by elemental analysis, IR and EPR spectroscopy, and single-crystal X-ray analysis. It was shown that the complexes have a square-planar structure, in which the ligand is tridentate and dianionic. The coordination of Cu(II) ion is formed by the oxygen atom of the phenol group of 3,5-di-tert-butyl salicylic aldehyde, amidic oxygen atom is in enolic form, the oxygen atom of the DMF molecule and the nitrogen atom of the azomethine group. When recrystallizing from DMF/acetonitrile/ethanol = 1:2:4 solution, the water molecule in the complex is easily exchanged with the DMF molecule. The results of these studies showed that the complexes have a stronger antibacterial and antifungal effect than the ligand.</p></div>","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2024-01-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Copper (II) complexes with (E)-N′(3,5-di-tert-butyl-2-hydroxybenzilidene)-2-hydroxybenzohydrazide, their bactericidal and fungicidal activity\",\"authors\":\"Perizad Amrulla Fatullayeva, Ajdar Akper Medjidov, Rayyat Huseyn Ismayilov, Asim Sabri Abdullayev, Sevinc Rafiq Lahicova, Gulu Qanimet Abbasova, Esmira Arif Aga Quliyeva, Mahammad Allahverdi Bayramov\",\"doi\":\"10.1007/s11243-023-00568-1\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Mononuclear complexes of Copper(II) with (<i>E)-N′</i>(3,5-di-tert-butyl-2-hydroxybenzili- dene)-2-hydroxybenzohydrazide (H<sub>3</sub>sahz)<sub>2</sub>, Cu(Hsahz)(H<sub>2</sub>O) and Cu(Hsahz)(DMF) were synthesized. The structure of the complexes was studied by elemental analysis, IR and EPR spectroscopy, and single-crystal X-ray analysis. It was shown that the complexes have a square-planar structure, in which the ligand is tridentate and dianionic. The coordination of Cu(II) ion is formed by the oxygen atom of the phenol group of 3,5-di-tert-butyl salicylic aldehyde, amidic oxygen atom is in enolic form, the oxygen atom of the DMF molecule and the nitrogen atom of the azomethine group. When recrystallizing from DMF/acetonitrile/ethanol = 1:2:4 solution, the water molecule in the complex is easily exchanged with the DMF molecule. The results of these studies showed that the complexes have a stronger antibacterial and antifungal effect than the ligand.</p></div>\",\"PeriodicalId\":1,\"journal\":{\"name\":\"Accounts of Chemical Research\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":16.4000,\"publicationDate\":\"2024-01-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Accounts of Chemical Research\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11243-023-00568-1\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11243-023-00568-1","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Copper (II) complexes with (E)-N′(3,5-di-tert-butyl-2-hydroxybenzilidene)-2-hydroxybenzohydrazide, their bactericidal and fungicidal activity
Mononuclear complexes of Copper(II) with (E)-N′(3,5-di-tert-butyl-2-hydroxybenzili- dene)-2-hydroxybenzohydrazide (H3sahz)2, Cu(Hsahz)(H2O) and Cu(Hsahz)(DMF) were synthesized. The structure of the complexes was studied by elemental analysis, IR and EPR spectroscopy, and single-crystal X-ray analysis. It was shown that the complexes have a square-planar structure, in which the ligand is tridentate and dianionic. The coordination of Cu(II) ion is formed by the oxygen atom of the phenol group of 3,5-di-tert-butyl salicylic aldehyde, amidic oxygen atom is in enolic form, the oxygen atom of the DMF molecule and the nitrogen atom of the azomethine group. When recrystallizing from DMF/acetonitrile/ethanol = 1:2:4 solution, the water molecule in the complex is easily exchanged with the DMF molecule. The results of these studies showed that the complexes have a stronger antibacterial and antifungal effect than the ligand.
期刊介绍：
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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