化学活化二氧化硅镁的造粒效果

IF 0.5 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY International Journal of Self-Propagating High-Temperature Synthesis Pub Date : 2024-01-18 DOI:10.3103/s1061386223040106
D. I. Abzalov, T. G. Akopdzhanyan, N. I. Abzalov, R. A. Kochetkov, V. V. Grachev
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引用次数: 0

摘要

摘要 利用铝、氧化铝、氧化镁和高氯酸镁的粉末和颗粒混合物,通过自蔓延高温合成(SHS)制备了镁铝硼。研究了 Al + Al2O3 + MgO + Mg(ClO4)2 粉末混合物起始颗粒的粒化对燃烧产物的微观结构和相组成的影响。结果表明,混合物的造粒降低了燃烧温度和燃烧速度。研究发现,颗粒状混合物的燃烧产物最多由四相(MgAlON、氧化铝、氮化铝和未反应的铝)组成,而粉末状混合物的产物只有单一的 MgAlON 相。
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Granulation Effect on Chemically Activated SHS of MgAlON

Abstract

MgAlON were prepared by self-propagation high temperature synthesis (SHS) using powder and granular mixtures of aluminum, aluminum oxide, magnesium oxide, and magnesium perchlorate. The influence of granulation of starting particles of Al + Al2O3 + MgO + Mg(ClO4)2 powder mixtures on the microstructure and phase composition of combustion products was studied. It was revealed that the granulation of mixtures reduces the combustion temperature and burning velocity. It was found that the combustion products derived from granular mixtures consists of up to four phases (MgAlON, aluminum oxide, aluminum nitride, and unreacted aluminum), while the products of powder mixtures are represented by single MgAlON phase.

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来源期刊
CiteScore
1.00
自引率
33.30%
发文量
27
期刊介绍: International Journal of Self-Propagating High-Temperature Synthesis  is an international journal covering a wide range of topics concerned with self-propagating high-temperature synthesis (SHS), the process for the production of advanced materials based on solid-state combustion utilizing internally generated chemical energy. Subjects range from the fundamentals of SHS processes, chemistry and technology of SHS products and advanced materials to problems concerned with related fields, such as the kinetics and thermodynamics of high-temperature chemical reactions, combustion theory, macroscopic kinetics of nonisothermic processes, etc. The journal is intended to provide a wide-ranging exchange of research results and a better understanding of developmental and innovative trends in SHS science and applications.
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