新西兰邓山蛇绿岩带岩浆演化的地质年代和地球化学制约因素

IF 1.8 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Lithosphere Pub Date : 2024-01-12 DOI:10.2113/2024/lithosphere_2023_283
Daniel Patias, Renjie Zhou, Jonathan C. Aitchison
{"title":"新西兰邓山蛇绿岩带岩浆演化的地质年代和地球化学制约因素","authors":"Daniel Patias, Renjie Zhou, Jonathan C. Aitchison","doi":"10.2113/2024/lithosphere_2023_283","DOIUrl":null,"url":null,"abstract":"New whole-rock major and trace element geochemical, zircon U-Pb geochronological, and Hf isotopic data from gabbroic rocks in New Zealand’s mid-Permian Dun Mountain ophiolite belt (DMO) provide insight into the evolution of subduction systems and early stages of intraoceanic arc development. Fe-oxide-bearing gabbros yielded high εHf(t) values (+10.3 to +13) and zircon U-Pb ages of 271.6 ± 0.6 Ma. In contrast, Fe-Ti-oxide-bearing gabbros of 268.1 ± 0.6 Ma show more enriched geochemical characteristics, including a wide range of εHf(t) values (+15.5 to +6.8). New findings strengthen the evolutionary model for the DMO and place constraints on its youngest known magmatic episode. We infer that late magmatism fingerprinted by these gabbros, including consistent negative Nb-Ta anomalies, reflects early stages of arc development and formation of island arc tholeiites on the DMO. Our model is consistent with other existing regional geochronological and geochemical data, implying that the DMO had an early stage of normal-mid-ocean ridge basalt crustal accretion followed by an influx of slab-derived components and maturity of the subducting system between ca. 271.6 and 268 Ma. These results extend our understanding of the evolution of distinct intraoceanic systems.Ophiolites are fragments of ancient oceanic lithosphere that have been incorporated into continental margins [1, 2]. They can be formed in distinct tectonic settings, including mid-ocean ridge, back-arc, and forearc [3, 4]. However, since the recognition of lava with island arc tholeiites (IAT) and calc-alkaline geochemical signatures in the Troodos ophiolite [5], a growing number of studies have associated these fragments of ancient oceanic lithosphere to intraoceanic convergent plate margins [6]. Such ophiolites, formed during sea-floor spreading above the subducting slab, are referred to as suprasubduction zone (SSZ) ophiolites [7]. They are widely interpreted to form during subduction initiation and early growth of island arcs [2, 7, 8]. As a result, studying their geochemical and geochronological signatures is crucial for understanding plate tectonic processes and intraoceanic systems [3, 9-12].Different geochemical signatures, such as forearc basalt (FAB), boninite, and IAT, can often be found in rocks from the ophiolitic crustal section. These signatures are widely used to identify different stages of the ophiolite and the evolution of the intraoceanic system [13, 14]. However, diverse processes can affect the geochemical characteristics of ophiolitic rocks, for example, the injection of fluids and melts from the slab [15, 16], distinct episodes of melt extraction from the mantle [17], and cumulate processes [18, 19]. Additionally, specific processes, such as colder, denser slabs descending more quickly or a thicker sedimentary cover of the slab, can also contribute to the geochemical heterogeneity of ophiolitic rocks [20-22]. This complexity can make it challenging to determine an ophiolite’s tectonic setting or evolutionary model, which is usually complicated by a limited amount of accurate geochronological data in mafic-ultramafic rocks. As a result, different interpretations of the same ophiolite are often proposed.The middle Permian Dun Mountain ophiolite belt (DMO) [23] in New Zealand’s South Island is a prime example of the difficulties in interpreting ophiolites with diverse geochemical signatures and limited geochronological data. The mantle section from the DMO has a depleted geochemical character and spinel Cr# (0.7, 0.8) and TiO2 (wt.% < 0.2%) values that resemble those of subduction-related ophiolites [24, 25]. The lava section, on the other hand, has geochemical signatures similar to mid-ocean ridge ophiolites, dominated by normal-mid-ocean ridge basalt (N-MORB) geochemical signatures, while dikes and uppermost lavas resemble FABs or IAT [26-28]. As a result of these heterogeneous geochemical signatures, several models have been proposed to explain the tectonic setting in which the DMO formed including: at a mid-ocean ridge [29, 30], back-arc [23], in association with slow-spreading ridges in a forearc [26, 31], or fast-spreading ridges [32]. In part, these differing models reflect the limited geochronological data available to support the interpretation of various magmatic rocks geochemical signatures [32-34]. Further geochemical and geochronological research is needed to better understand the magmatic stages of the DMO, particularly within the lower crustal plutonic rocks it contains.This study presents new petrographic, whole-rock geochemical, zircon U-Pb geochronological, Lu-Hf isotopic, and geochemical characteristics of the intrusive mafic rocks of the DMO. The youngest magmatic products reported here indicate associations with subduction processes and magma extraction during the early stages of arc development. When combined with previous research, these new findings improve our understanding of the magmatic evolution of the DMO and provide insight into various stages of the development of an associated intraoceanic system.The DMO consists of serpentinized peridotites, cumulate sequences, gabbros, volcanic rocks, and dikes (Figure 1(a) and (b)). It is overlain by forearc basin sediments of the Maitai Group and structurally overlies the Patuki and Croisilles mélanges [23, 31, 34, 35]. Outcrops of the ophiolite belt have been offset ~480 km dextrally by the Alpine Fault since the early Miocene Epoch, separating them into northern and southern sectors [35, 36].DMO mantle sections are characterized by harzburgite and dunite, with sparse occurrences of podiform chromitite and pyroxenite [23]. Petrogenetic and geochemical studies of the Red Hills complex (northern sector; Figure 1(b)) indicate at least three igneous events associated with distinct melting episodes and refertilization processes [25, 29, 30]. The first event was related to the production of MORB-like melts through 10%–15% partial melting of mantle sources within the garnet stability field (>55 km depth). A subsequent event is interpreted to have been associated with an additional 10% partial melting of the mantle sources, which produced boninite-like melts in the spinel-stability field (30, 50 km depth) in a forearc setting. This stage was associated with the progression of the subduction system [25]. It is assumed that a final stage of development recorded in the mantle rocks reflects the channeling of slab-enriched melts and fluids. This may be attributed to the formation of plagioclase-bearing ultramafic rocks, at shallow depths inside the plagioclase stability field (about 15 km) [25, 29].The DMO crustal segment comprises a dismembered cumulate sequence, isotropic gabbros, and mafic volcanic rocks, such as sheeted dikes, lava flows, pillow lavas, and dikes [23, 26, 32, 37]. Cumulate sequences include pyroxenite, wehrlite, and dunite, interlayered with gabbros, including isotropic hornblende- and clinopyroxene-gabbros [26, 28, 37]. Volcanic rocks are predominantly basaltic and exhibit an upward transition to basaltic-andesites and, rarely, andesites [26, 32]. Early lavas are characterized by MORB-type signatures, with IAT becoming increasingly common up-section [26, 27, 32]. The DMO also contains a complicated network of dikes with varying lithologies and geochemical signatures [27, 32], with a predominance of FAB affinity.Due to earlier efforts to determine the ages of magmatic zircons using the Thermal ionization mass spectrometry(TIMS) method, the DMO has long been considered to have formed during the late Early Permian Period (ca. 280 ± 5 Ma [34]). In a later study, Jugum et al. [31] reanalyzed the same samples using the LA-ICP-MS method, which is also employed in this work, facilitating age comparisons. To maintain data consistency, this study predominantly utilizes the U-Pb zircon ages reported by Jugum et al. [31] to compare and constrain various stages of magmatic evolution within the DMO.Based on zircon U-Pb ages from both mafic and felsic rocks, the genesis and geochemical evolution of the DMO are considered to have taken place during an interval of 9 ± 3 Ma [28, 32, 33]. Samples from the southern sector (i.e., south of the Alpine Fault) tend to yield older ages than those from the northern sector (Figure 1(c)) with plagiogranite and anorthosite dikes yielding concordant Kungurian Age (middle Permian Period) age determinations (206Pb/238U vs. 207Pb/235U) of 277.6 ± 3.3 (MSWD = 1.4) and 277.4 ± 3.4 Ma (MSWD = 5.5), respectively [32]. When interpreted together with zircon geochemical data, these ages are considered representative of episodes of early N-MORB (plagiogranite) and middle MORB-IAT (anorthosite) crustal formation. In the northern sector, a plagiogranite dike cross-cutting the mantle flow foliation in peridotites of the Red Hills ultramafic complex has yielded a Kungurian Age (middle Permian Period) zircon U-Pb age determination of 274.5 ± 0.4 Ma (MSWD = 0.26) [33]. This is deemed the youngest age prior to cessation of deformation in the peridotite complex of the Red Hills massif [25].DMO formation remains a topic of discussion among researchers. Some suggest that it is a mid-ocean ridge (MOR)-type ophiolite that was subsequently exposed to a subduction system based on analyses of whole-rock and mineral geochemistry from mantle and crustal rocks [27, 29, 30]. However, others argue that it formed in a forearc setting [24, 25, 32], citing typical Penrose “stratigraphy,” the refractory nature of the mantle rocks, characteristics of some crustal rocks, and a conformably overlying succession of forearc sediments (Maitai Group). Among the forearc interpretations, DMO is considered to represent both a slow-spreading ridge [31] and a fast-spreading and short-lived ophiolite, similar to the modern Izu-Bonin-Mariana (IBM) forearc system [32].In the northern sector of the DMO, gabbro samples were collected both in situ and from float (Figure 1(b)). In the Roding River, a foliated Fe-oxide gabbro (RR-04; 41.37467°S, 173.29011°E; Figures 2(a) and (e)) with subophitic texture was sampled in situ. Two km SW of the RR-04 site, an isotropic Fe-Ti-oxide gabbro (RR-07; 41.36678°S, 173.30453°E) intruded by thin (<10 cm) dolerite dikes (Figure 2(b)), was collected from a ~20 m wide outcrop. Near the same locality (4 km to NW of RR-07), a pegmatitic gabbro (RR-02B; 41.35869°S, 173.25853°E) was collected from boulders in the Roding River (Figure 2(d)). Given the quantity of peridotite and gabbro boulders in the riverbed and the presence of gabbroic rock outcrops upstream, the sample is considered to be derived from the DMO. Another isotropic Fe-Ti-oxide gabbro (Figure 2(f)), 500 m W of the contact between the DMO and Maitai Group, was collected from boulders in the Miner River (HT-04; 41.39433°S, 173.23656°E). Considering the occurrence of peridotite boulders and that upstream areas of the Miner River are mapped as a component of the ophiolite crustal segment with their genesis considered to be related to the DMO (Figure 1) [38]. Within the Red Hills ultramafic massif, a gabbroic dike (sample LC-03; -41.64775, 173.00594) was collected from an outcrop in Lowther Creek (Figure 2(c) and (g)). This dike is 2 m wide, shallow-dipping, and intrudes an upper mantle peridotite with steeply dipping compositional banding of orthopyroxene and olivine-rich layers. Samples were prepared for petrography, geochemistry, and zircon isotopic analyses. Table 1 provides an overview of sample petrographic characteristics that are detailed in online Supplementary Material 1.Whole-rock major and trace element analysis was conducted at the Australian Laboratory Services facilities in Brisbane, Australia. The samples were first prepared in a series of steps including washing, drying, crushing, splitting, and pulverizing. The concentration of major element oxides was determined using an X-ray fluorescence spectrometer with a precision of ±2%–5%. Additionally, thirty trace elements were measured using an inductively coupled plasma mass spectrometer (ICP-MS) with a precision of better than ±5% for most elements. Quality control measures were implemented, and all standards were found to be within the target range, indicating highly accurate analyses. The detection limit for major oxides is 0.01%, while it varies for trace elements (online Supplementary Material 2).Zircon separation was performed using standard methods (gravimetric, magnetic, and heavy liquid separation) at the Hebei Geological Survey, Langfang, China. The cores of the grains were exposed by mounting the zircons in epoxy and then polishing them. They were imaged using a Hitachi SU3500 scanning electron microscope that was equipped with backscatter, secondary electron, and cathodoluminescence (CL) detectors. The images were used to identify mineral fractures, zoning, internal structures, and CL characteristics (see online Supplementary Material 1 for CL images).Isotopic and trace element analyses of zircon grains (91Zr, 45Sc, 49Ti, 88Sr, 89Y, 93Nb, 139La, 140Ce, 146Nd, 147Sm, 153Eu, 157Gd, 172Yb, 175Lu, 178Hf, 206Pb, 207Pb, 208Pb, 232Th, and 238U) were conducted using a Thermo Fisher iCAP RQ quadrupole ICP-MS equipped with an ASI RESOlution SE 193 nm laser at The University of Queensland. U-Pb isotopes and trace elements were collected in the same analytical session. The laser spot size was adjusted based on the size of the grains. For larger zircon crystals (samples RR-04, HT-04), data were collected with a 30 µm spot size in thirty cycles of 1 second at a repetition rate of 7 Hz and a fluence of 3 J/cm3. Sample RR-2B was analyzed using a 24 µm spot size, with the same laser and ICP-MS settings as the 30 µm spot size session. U-Pb age analyses on zircons were performed using the 91,500 zircon standard [39] for background, and instrumental bias [40] and TEMORA2 grains [41] were used as secondary standards to monitor precision and accuracy. Data obtained indicate precision and accuracy better than 0.5% for U-Pb age measurements (see online Supplementary Material 1). Uncertainties associated with U-Pb isotope ratios and standard deviation of primary and secondary zircon standards were propagated into sample uncertainties following procedures suggested by Horstwood et al. [42]. For zircon trace elements, a NIST612 glass standard was used as a primary reference material. Data were processed using the Iolite software [43], and Zr was used for internal normalization of the trace elements.Isotopic analysis of Lu-Hf in zircon (masses 171–180) was conducted using a Nu Plasma II multicollector ICP-MS (MC-ICP-MS) equipped with an ASI RESOlution SE 193 nm laser at the Center for Geoanalytical Mass Spectrometry, School of Earth and Environmental Sciences at The University of Queensland. Measurements were carried out using a larger spot size of 50 µm, in thirty-five cycles of 1 second at a repetition rate of 8 Hz and an on-sample fluence of 3 J/cm3 for the same spot where the grains were analyzed for U-Pb isotopes and trace elements. Analytical procedures followed Zhou et al. [44]. Primary and secondary zircon standards were the same as those used for the U-Pb age sessions. Accuracy and precision achieved were better than 0.1% for the primary standard (91,500) and monitoring standard (TEMORA2). Additional information on the analytical procedures, data quality, geochemical analyses, zircon trace elements, and isotopic data are available in online Supplementary Materials 1 and 2.Major and trace element values are presented in Table 2. In discrimination diagrams, samples plot within gabbro or gabbro diorite fields, with a subalkaline tendency (online Supplementary Material 1). Notably, geochemistry allows samples to be separated into two distinct categories according to their elemental abundances, with Fe-oxide gabbro (RR-04) and gabbroic dike (LC-03) having more depleted character than Fe-Ti-oxide isotropic gabbros (HT-04 and RR-07; Figures 3 and 4).Sample LC-03 exhibits high SiO2 (52.6 wt.%) and MgO (10.9 wt.%) and low TiO2 (0.23 wt.%) abundance. Fe-oxide gabbro (RR-04) also has low TiO2 (0.24 wt.%) abundance but lower values of SiO2 (49.59 wt.%) and MgO (7.72 wt.%). These samples exhibit higher MgO, CaO, and Cr (440, 870 ppm) values than the Fe-Ti-oxide gabbros. In contrast, more geochemically enriched samples (HT-04, RR-07) have higher concentrations of SiO2 (51.19, 54.24 wt.%) and TiO2 (0.86, 0.94 wt.%) and lower MgO (6.03, 7.26 wt.%) and Cr (150, 340 ppm). Notably, more depleted samples exhibit lower Ti/V (1–25) and Nb/Ta (1–3) ratios, while Fe-Ti-oxide gabbros tend to exhibit higher values for Ti/V (32–40) and Nb/Ta (11–13) ratios. In major oxide geochemical diagrams (MgO vs. TiO2 and SiO2 vs. MgO; Figures 3(a) and (b)), samples are plotted within fields associated with subduction processes (island arc and FAB).On primitive mantle-normalized trace and chondrite-normalized REE plots (Figures 4(a) and (b)), dike (LC-03) and Fe-oxide gabbro (RR-04) exhibit greater depletion of trace elements compared with Fe-Ti-oxide gabbro samples. These samples have notably lower abundances of some high-field-strength elements (HFSEs), such as Nb, Zr, Hf, and Ti, and positive anomalies among large-ion lithophile elements (LILEs; e.g., Ba, K, Rb, Cs, and Sr). In contrast, more enriched samples (Fe-Ti-oxide gabbros) resemble N- or E-MORBs and exhibit enrichment in LILE but minimal depletion in HFSE (Figure 4(a)). Similar patterns are observed in chondrite-normalized REE plot in which gabbroic dike and Fe-oxide gabbro exhibit greater depletion in REEs (Figure 4(b)) compared with Fe-Ti-oxide gabbro samples, which display REE contents similar to E- or N-MORB. Despite having distinct signatures, all samples show an overall enrichment in fluid-mobile/LILE (Cs, Rb, Ba, Th, K, and Sr) and discernible depletion of more immobile/HFSE (Nb, Ta, and Ti) compared with N-MORB lavas (Figures 4(a) and (b)).Zircons from samples RR-04 (Fe-oxide gabbro), HT-04 (Fe-Ti-oxide gabbro), and RR-2B (pegmatite) were analyzed to determine U-Pb ages, Lu-Hf isotopes, and trace elements abundances. Samples RR-07 and LC-03 did not yield zircons of sufficient abundance or size for analysis. Recovered zircon grains exhibit, generally, low length-to-width ratios (1:1 to 3:1) and are between 15 and 250 µm long. Most crystals have weak oscillatory and sector zoning under CL light (refer to supplementary material for CL images), typically observed in mafic igneous rocks [45]. The analyzed samples contain variable U (18, 940 ppm), Th (3, 706 ppm) contents, and Th/U ratios between 0.17 and 0.86. They show an increase in average U and Th content and Th/U ratios from RR-04 (190 and 88 ppm, 0.35) and HT-04 (200 and 90 ppm, 0.41) to pegmatitic gabbro (209 and 122 ppm, 0.54). These values are consistent with U and Th concentrations and Th/U ratios expected for magmatic zircons from gabbroic rocks [46].Zircon U-Pb Concordia ages (206Pb/238U vs. 207Pb/206Pb) are from the middle Permian Period (Roadian Age), ranging from 271.6 ± 0.6 to 267.6 ± 0.9 Ma. Of the samples measured, the oldest age was found in the Fe-oxide gabbro (RR-04; 271.6 ± 0.6 Ma), while the Fe-Ti-oxide (HT-04) and pegmatitic gabbro samples (RR-02B) are slightly younger at 268.1 ± 0.6 and 267.6 ± 0.9 Ma (2σ), respectively (Figure 5). Zircon-weighted mean plots show individual grains ages. Zircon Hf isotopes exhibit variations between samples, with values ranging between +6.8 and +15.5 (Figure 6). The Fe-oxide gabbro samples have the highest median value of εHf(t) at +12.2, and a more consistent εHf(t) values (+10.8 and +13), compared with the Fe-Ti-oxide samples (+11.1) and pegmatitic gabbro (+11.5). It is worth noting that the Fe-Ti-oxide gabbro samples exhibit a wider range of εHf(t) values, with the most and least juvenile zircon samples analyzed having values of +15.5 and +6.8, respectively.Zircon geochemical characteristics from gabbroic samples exhibit similarities with those observed in SSZ-ophiolite and plot between the continental arc and MOR fields (Figure 7(a); U/Yb vs. Nb/Yb diagram). A contrast between samples is better observed on primitive mantle-normalized trace and REE plots (Figures 7(b) and (c)). Fe-oxide gabbro zircons (RR-04) tend to exhibit lower trace and REE elemental abundances compared with zircons from Fe-Ti-oxide (HT-04) and pegmatitic (RR-2B) gabbros, especially for Y, Ce, Nd, Sm, Eu, Gd, Yb, and Lu concentrations and Th/U ratios.Gabbro compositions together with zircon geochronological and geochemical data constrain the timing and evolution of the youngest magmatic products described from the DMO. Analyzed gabbros exhibit low TiO2 contents and general depletion in HFSEs. Such compositions are usually unexpected in MOR ophiolites [47], which sources commonly exhibit smaller degrees of partial melting [3, 7]. Fe-Ti-oxide samples (RR-07, HT-04), Fe-oxide gabbro (RR-04), and gabbroic dike (LC-03) plot near or within the oceanic/island arc fields (Figure 8a), indicating a potential origin related to subduction processes. Furthermore, the AFM discrimination diagram (Figure 8b) exhibits Fe-Ti-oxide gabbros plotting within the arc-related noncumulate gabbros and diorites fields, while Fe-oxide gabbro falls near the arc-related ultramafic and mafic cumulates field. Thus, geochemically depleted Fe-oxide gabbro (RR-04) is likely to reflect fractional crystallization processes of melts formed in an intraoceanic system, whereas the high-Mg gabbroic dike (LC-03) probably fingerprints melt extraction from depleted mantle sources. Despite variances, the consistently low Ti, Zr, Hf, Nb, Ta, and Ti/V values across all analyzed samples indicate their classification as IAT. Furthermore, zircon U-Pb ages from these samples, ranging between 271.6 and 268 Ma, alongside positive εHf(t) values (+6.8 and +15.5), constrain an important episode of oceanic crust formation in the DMO in an island arc tectonic setting.New findings further elaborate on differences between early and late magmatic episodes in the DMO, as previously observed [32, 48]. Zircon U-Pb ages from crustal rocks indicate magmatic evolution of the DMO occurred over a ca. 10 Myr interval ([31, 32]; this study). The oldest magmatic episode (~ 277.5 Ma) is recorded from the southern sector of the DMO (Figure 1(c)), in which geochemical signatures of zircons recovered from anorthositic and plagiogranitic dikes indicate similarities to those observed in MOR and/or IAT settings [32]. This early magmatism is usually associated with lavas with MOR signatures [31, 32], which are considered to be products of deep fertile melt extraction from mantle sources [25, 30, 32].In contrast, younger crustal rocks are mostly observed in the northern sector and yield zircon U-Pb ages between 274.5 and 267.6 Ma ([31, 32]; this study). This younger magmatism is interpreted as a product of melts associated with an intraoceanic setting and is fingerprinted by studies in the crustal and mantle sections [24, 25, 31, 32]. Gabbros analyzed as part of this study exhibits subduction-related signatures, with ages ranging between 271.6 and 268.1 Ma. These findings contribute to a better understanding of the timing of younger magmatism and indicate the establishment of an intraoceanic system. Additionally, data presented herein contribute to the understanding of the temporal dynamics of fluid and melt circulation in the subduction system associated with the DMO.The combination of new geochemical and geochronological data together with existing data results in a refinement of understanding of the magmatic evolution of the DMO (Figures 9(a)–(e)). Zircon U-Pb ages ranging from approximately 277.5 to 267.6 Ma are reported from a diverse range of lithologies and geochemical compositions, distributed across a wide geographic area ([31, 32]; this study]. This age interval is associated with a complex spatial and temporal magmatic evolution that involves rocks from both the southern and northern sectors.Early magmatic episodes in the DMO have traditionally been associated with a mid-ocean ridge setting and deep-fertile melts [30]. Our research suggests that the early magmatic products in the DMO may have been triggered by the upwelling of fertile asthenospheric melts due to decompression processes in the mantle-wedge (Figure 9(b)). These processes may have occured before revented the influx of slab-derived components into the system. This interpretation is supported by considerations that MOR-like lavas can form approximately 1–10 Myr after subduction initiation [20]. This magmatic episode is likely characterized by plagiogranites and anorthosites containing zircon with geochemical signatures similar to those MORB and/or IAT dated at around 277.5 Ma [32]. In this scenario, a progressive evolution of the DMO in a subduction-related setting is preferred (Figure 9(b)–(c)).Following the evolution of the subduction system, FAB and IAT geochemical signatures appear in gabbros, mafic dikes, and lavas, indicating the establishment of an intraoceanic subduction system (Figure 9(d)). Mafic dikes with depleted geochemical characteristics suggest that melts were extracted from a refractory mantle source (Figure 9(d)). Other studies of petrology and geochemistry in the DMO mantle section have revealed the presence of depleted sources, including harzburgite and chromitite, which exhibit signatures comparable to those found in subduction-related settings [25, 29, 30]. Furthermore, these sources display fO2 (above MORB field) in Cr-spinels [25, 30] typical of oxidizing and fluid-rich environments [49].The presence of IAT signatures in the uppermost lava sequence [26] and gabbroic samples (Figures 3 and 8) indicates a more evolved intraoceanic system. Zircon U-Pb ages ranging from 271.6 to 268.1 Ma, occurring approximately 6–9 Myr years after the oldest recorded zircon U-Pb age from IAT-like gabbros in the DMO, could fingerprint the timing of pervasive formation of melts derived from the slab. These ages could also correlate with mantle refertilization [25, 30], potentially triggered by an influx of slab-derived melts into the mantle wedge, resulting in the combination of new fertile melts with previously depleted melts.The magmatic evolution of the DMO shares similarities with that of the IBM forearc system [8] in terms of the progression of its crust from FAB-boninitic rocks to IAT. However, there are notable differences in the timing and distribution of subduction-related signatures. Unlike the DMO, where subducting-related rocks are mostly confined to intrusive rocks and the uppermost lavas, rocks affected by slab-derived components are widespread and were formed shortly after subduction initiation (around 1–2 Myr) in the IBM system [8, 14]. The DMO exhibits a lava sequence largely unaffected by any significant SSZ influence, and subduction-related rocks are mostly recognizable approximately 6–9 Myr after subduction initiation. This suggests slow and protracted evolution in a forearc setting for the DMO, with significant differences from the fast- and short-lived system observed in the IBM forearc system.Petrographic and geochemical data, as well as zircon U-Pb ages, Hf isotopic, and trace element geochemical signatures from gabbroic rocks of the DMO, provide valuable insights into the evolution of an ancient intraoceanic system. Fe-oxide cumulate gabbro with zircon U-Pb ages of ca. 271.6 Ma and Fe-Ti-oxide gabbros (ca. 268.1 Ma) with IAT-like geochemical characteristics indicates evolution toward embryonic arc stage and constrain the DMO youngest magmatic episode. Our findings, when combined with previous geochronological and geochemical results, suggest that the DMO experienced an early stage of N-MORB crust evolution (ca. 277.5 Ma) before a pervasive influx of slab-derived components and refertilization of the mantle wedge resulted in the formation of arc-like rocks at 271.5–268 Ma. Results presented in this study contribute to a better understanding of the magmatic evolution of the DMO and allow comparison with other intraoceanic systems.We thank Dr. David Kimbrough for his comments on geochronological data at our study site, which enriched our research. We also thank Dr. Gültekin Topuz, two anonymous reviewers, and handling editor Professor Bo Wang for their valuable comments and suggestions, which greatly improved our manuscript. The authors acknowledge funding support from the Australian Research Council discovery project Diamonds in ophiolites: Recycling deep mantle into suprasubduction zones (ARC DP190100814).The authors declare no conflicts of interest.The original contributions and data presented in this study are included in the article and the supplementary materials.","PeriodicalId":18147,"journal":{"name":"Lithosphere","volume":null,"pages":null},"PeriodicalIF":1.8000,"publicationDate":"2024-01-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Geochronological and Geochemical Constraints on the Magmatic Evolution of the Dun Mountain Ophiolite Belt, New Zealand\",\"authors\":\"Daniel Patias, Renjie Zhou, Jonathan C. Aitchison\",\"doi\":\"10.2113/2024/lithosphere_2023_283\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"New whole-rock major and trace element geochemical, zircon U-Pb geochronological, and Hf isotopic data from gabbroic rocks in New Zealand’s mid-Permian Dun Mountain ophiolite belt (DMO) provide insight into the evolution of subduction systems and early stages of intraoceanic arc development. Fe-oxide-bearing gabbros yielded high εHf(t) values (+10.3 to +13) and zircon U-Pb ages of 271.6 ± 0.6 Ma. In contrast, Fe-Ti-oxide-bearing gabbros of 268.1 ± 0.6 Ma show more enriched geochemical characteristics, including a wide range of εHf(t) values (+15.5 to +6.8). New findings strengthen the evolutionary model for the DMO and place constraints on its youngest known magmatic episode. We infer that late magmatism fingerprinted by these gabbros, including consistent negative Nb-Ta anomalies, reflects early stages of arc development and formation of island arc tholeiites on the DMO. Our model is consistent with other existing regional geochronological and geochemical data, implying that the DMO had an early stage of normal-mid-ocean ridge basalt crustal accretion followed by an influx of slab-derived components and maturity of the subducting system between ca. 271.6 and 268 Ma. These results extend our understanding of the evolution of distinct intraoceanic systems.Ophiolites are fragments of ancient oceanic lithosphere that have been incorporated into continental margins [1, 2]. They can be formed in distinct tectonic settings, including mid-ocean ridge, back-arc, and forearc [3, 4]. However, since the recognition of lava with island arc tholeiites (IAT) and calc-alkaline geochemical signatures in the Troodos ophiolite [5], a growing number of studies have associated these fragments of ancient oceanic lithosphere to intraoceanic convergent plate margins [6]. Such ophiolites, formed during sea-floor spreading above the subducting slab, are referred to as suprasubduction zone (SSZ) ophiolites [7]. They are widely interpreted to form during subduction initiation and early growth of island arcs [2, 7, 8]. As a result, studying their geochemical and geochronological signatures is crucial for understanding plate tectonic processes and intraoceanic systems [3, 9-12].Different geochemical signatures, such as forearc basalt (FAB), boninite, and IAT, can often be found in rocks from the ophiolitic crustal section. These signatures are widely used to identify different stages of the ophiolite and the evolution of the intraoceanic system [13, 14]. However, diverse processes can affect the geochemical characteristics of ophiolitic rocks, for example, the injection of fluids and melts from the slab [15, 16], distinct episodes of melt extraction from the mantle [17], and cumulate processes [18, 19]. Additionally, specific processes, such as colder, denser slabs descending more quickly or a thicker sedimentary cover of the slab, can also contribute to the geochemical heterogeneity of ophiolitic rocks [20-22]. This complexity can make it challenging to determine an ophiolite’s tectonic setting or evolutionary model, which is usually complicated by a limited amount of accurate geochronological data in mafic-ultramafic rocks. As a result, different interpretations of the same ophiolite are often proposed.The middle Permian Dun Mountain ophiolite belt (DMO) [23] in New Zealand’s South Island is a prime example of the difficulties in interpreting ophiolites with diverse geochemical signatures and limited geochronological data. The mantle section from the DMO has a depleted geochemical character and spinel Cr# (0.7, 0.8) and TiO2 (wt.% < 0.2%) values that resemble those of subduction-related ophiolites [24, 25]. The lava section, on the other hand, has geochemical signatures similar to mid-ocean ridge ophiolites, dominated by normal-mid-ocean ridge basalt (N-MORB) geochemical signatures, while dikes and uppermost lavas resemble FABs or IAT [26-28]. As a result of these heterogeneous geochemical signatures, several models have been proposed to explain the tectonic setting in which the DMO formed including: at a mid-ocean ridge [29, 30], back-arc [23], in association with slow-spreading ridges in a forearc [26, 31], or fast-spreading ridges [32]. In part, these differing models reflect the limited geochronological data available to support the interpretation of various magmatic rocks geochemical signatures [32-34]. Further geochemical and geochronological research is needed to better understand the magmatic stages of the DMO, particularly within the lower crustal plutonic rocks it contains.This study presents new petrographic, whole-rock geochemical, zircon U-Pb geochronological, Lu-Hf isotopic, and geochemical characteristics of the intrusive mafic rocks of the DMO. The youngest magmatic products reported here indicate associations with subduction processes and magma extraction during the early stages of arc development. When combined with previous research, these new findings improve our understanding of the magmatic evolution of the DMO and provide insight into various stages of the development of an associated intraoceanic system.The DMO consists of serpentinized peridotites, cumulate sequences, gabbros, volcanic rocks, and dikes (Figure 1(a) and (b)). It is overlain by forearc basin sediments of the Maitai Group and structurally overlies the Patuki and Croisilles mélanges [23, 31, 34, 35]. Outcrops of the ophiolite belt have been offset ~480 km dextrally by the Alpine Fault since the early Miocene Epoch, separating them into northern and southern sectors [35, 36].DMO mantle sections are characterized by harzburgite and dunite, with sparse occurrences of podiform chromitite and pyroxenite [23]. Petrogenetic and geochemical studies of the Red Hills complex (northern sector; Figure 1(b)) indicate at least three igneous events associated with distinct melting episodes and refertilization processes [25, 29, 30]. The first event was related to the production of MORB-like melts through 10%–15% partial melting of mantle sources within the garnet stability field (>55 km depth). A subsequent event is interpreted to have been associated with an additional 10% partial melting of the mantle sources, which produced boninite-like melts in the spinel-stability field (30, 50 km depth) in a forearc setting. This stage was associated with the progression of the subduction system [25]. It is assumed that a final stage of development recorded in the mantle rocks reflects the channeling of slab-enriched melts and fluids. This may be attributed to the formation of plagioclase-bearing ultramafic rocks, at shallow depths inside the plagioclase stability field (about 15 km) [25, 29].The DMO crustal segment comprises a dismembered cumulate sequence, isotropic gabbros, and mafic volcanic rocks, such as sheeted dikes, lava flows, pillow lavas, and dikes [23, 26, 32, 37]. Cumulate sequences include pyroxenite, wehrlite, and dunite, interlayered with gabbros, including isotropic hornblende- and clinopyroxene-gabbros [26, 28, 37]. Volcanic rocks are predominantly basaltic and exhibit an upward transition to basaltic-andesites and, rarely, andesites [26, 32]. Early lavas are characterized by MORB-type signatures, with IAT becoming increasingly common up-section [26, 27, 32]. The DMO also contains a complicated network of dikes with varying lithologies and geochemical signatures [27, 32], with a predominance of FAB affinity.Due to earlier efforts to determine the ages of magmatic zircons using the Thermal ionization mass spectrometry(TIMS) method, the DMO has long been considered to have formed during the late Early Permian Period (ca. 280 ± 5 Ma [34]). In a later study, Jugum et al. [31] reanalyzed the same samples using the LA-ICP-MS method, which is also employed in this work, facilitating age comparisons. To maintain data consistency, this study predominantly utilizes the U-Pb zircon ages reported by Jugum et al. [31] to compare and constrain various stages of magmatic evolution within the DMO.Based on zircon U-Pb ages from both mafic and felsic rocks, the genesis and geochemical evolution of the DMO are considered to have taken place during an interval of 9 ± 3 Ma [28, 32, 33]. Samples from the southern sector (i.e., south of the Alpine Fault) tend to yield older ages than those from the northern sector (Figure 1(c)) with plagiogranite and anorthosite dikes yielding concordant Kungurian Age (middle Permian Period) age determinations (206Pb/238U vs. 207Pb/235U) of 277.6 ± 3.3 (MSWD = 1.4) and 277.4 ± 3.4 Ma (MSWD = 5.5), respectively [32]. When interpreted together with zircon geochemical data, these ages are considered representative of episodes of early N-MORB (plagiogranite) and middle MORB-IAT (anorthosite) crustal formation. In the northern sector, a plagiogranite dike cross-cutting the mantle flow foliation in peridotites of the Red Hills ultramafic complex has yielded a Kungurian Age (middle Permian Period) zircon U-Pb age determination of 274.5 ± 0.4 Ma (MSWD = 0.26) [33]. This is deemed the youngest age prior to cessation of deformation in the peridotite complex of the Red Hills massif [25].DMO formation remains a topic of discussion among researchers. Some suggest that it is a mid-ocean ridge (MOR)-type ophiolite that was subsequently exposed to a subduction system based on analyses of whole-rock and mineral geochemistry from mantle and crustal rocks [27, 29, 30]. However, others argue that it formed in a forearc setting [24, 25, 32], citing typical Penrose “stratigraphy,” the refractory nature of the mantle rocks, characteristics of some crustal rocks, and a conformably overlying succession of forearc sediments (Maitai Group). Among the forearc interpretations, DMO is considered to represent both a slow-spreading ridge [31] and a fast-spreading and short-lived ophiolite, similar to the modern Izu-Bonin-Mariana (IBM) forearc system [32].In the northern sector of the DMO, gabbro samples were collected both in situ and from float (Figure 1(b)). In the Roding River, a foliated Fe-oxide gabbro (RR-04; 41.37467°S, 173.29011°E; Figures 2(a) and (e)) with subophitic texture was sampled in situ. Two km SW of the RR-04 site, an isotropic Fe-Ti-oxide gabbro (RR-07; 41.36678°S, 173.30453°E) intruded by thin (<10 cm) dolerite dikes (Figure 2(b)), was collected from a ~20 m wide outcrop. Near the same locality (4 km to NW of RR-07), a pegmatitic gabbro (RR-02B; 41.35869°S, 173.25853°E) was collected from boulders in the Roding River (Figure 2(d)). Given the quantity of peridotite and gabbro boulders in the riverbed and the presence of gabbroic rock outcrops upstream, the sample is considered to be derived from the DMO. Another isotropic Fe-Ti-oxide gabbro (Figure 2(f)), 500 m W of the contact between the DMO and Maitai Group, was collected from boulders in the Miner River (HT-04; 41.39433°S, 173.23656°E). Considering the occurrence of peridotite boulders and that upstream areas of the Miner River are mapped as a component of the ophiolite crustal segment with their genesis considered to be related to the DMO (Figure 1) [38]. Within the Red Hills ultramafic massif, a gabbroic dike (sample LC-03; -41.64775, 173.00594) was collected from an outcrop in Lowther Creek (Figure 2(c) and (g)). This dike is 2 m wide, shallow-dipping, and intrudes an upper mantle peridotite with steeply dipping compositional banding of orthopyroxene and olivine-rich layers. Samples were prepared for petrography, geochemistry, and zircon isotopic analyses. Table 1 provides an overview of sample petrographic characteristics that are detailed in online Supplementary Material 1.Whole-rock major and trace element analysis was conducted at the Australian Laboratory Services facilities in Brisbane, Australia. The samples were first prepared in a series of steps including washing, drying, crushing, splitting, and pulverizing. The concentration of major element oxides was determined using an X-ray fluorescence spectrometer with a precision of ±2%–5%. Additionally, thirty trace elements were measured using an inductively coupled plasma mass spectrometer (ICP-MS) with a precision of better than ±5% for most elements. Quality control measures were implemented, and all standards were found to be within the target range, indicating highly accurate analyses. The detection limit for major oxides is 0.01%, while it varies for trace elements (online Supplementary Material 2).Zircon separation was performed using standard methods (gravimetric, magnetic, and heavy liquid separation) at the Hebei Geological Survey, Langfang, China. The cores of the grains were exposed by mounting the zircons in epoxy and then polishing them. They were imaged using a Hitachi SU3500 scanning electron microscope that was equipped with backscatter, secondary electron, and cathodoluminescence (CL) detectors. The images were used to identify mineral fractures, zoning, internal structures, and CL characteristics (see online Supplementary Material 1 for CL images).Isotopic and trace element analyses of zircon grains (91Zr, 45Sc, 49Ti, 88Sr, 89Y, 93Nb, 139La, 140Ce, 146Nd, 147Sm, 153Eu, 157Gd, 172Yb, 175Lu, 178Hf, 206Pb, 207Pb, 208Pb, 232Th, and 238U) were conducted using a Thermo Fisher iCAP RQ quadrupole ICP-MS equipped with an ASI RESOlution SE 193 nm laser at The University of Queensland. U-Pb isotopes and trace elements were collected in the same analytical session. The laser spot size was adjusted based on the size of the grains. For larger zircon crystals (samples RR-04, HT-04), data were collected with a 30 µm spot size in thirty cycles of 1 second at a repetition rate of 7 Hz and a fluence of 3 J/cm3. Sample RR-2B was analyzed using a 24 µm spot size, with the same laser and ICP-MS settings as the 30 µm spot size session. U-Pb age analyses on zircons were performed using the 91,500 zircon standard [39] for background, and instrumental bias [40] and TEMORA2 grains [41] were used as secondary standards to monitor precision and accuracy. Data obtained indicate precision and accuracy better than 0.5% for U-Pb age measurements (see online Supplementary Material 1). Uncertainties associated with U-Pb isotope ratios and standard deviation of primary and secondary zircon standards were propagated into sample uncertainties following procedures suggested by Horstwood et al. [42]. For zircon trace elements, a NIST612 glass standard was used as a primary reference material. Data were processed using the Iolite software [43], and Zr was used for internal normalization of the trace elements.Isotopic analysis of Lu-Hf in zircon (masses 171–180) was conducted using a Nu Plasma II multicollector ICP-MS (MC-ICP-MS) equipped with an ASI RESOlution SE 193 nm laser at the Center for Geoanalytical Mass Spectrometry, School of Earth and Environmental Sciences at The University of Queensland. Measurements were carried out using a larger spot size of 50 µm, in thirty-five cycles of 1 second at a repetition rate of 8 Hz and an on-sample fluence of 3 J/cm3 for the same spot where the grains were analyzed for U-Pb isotopes and trace elements. Analytical procedures followed Zhou et al. [44]. Primary and secondary zircon standards were the same as those used for the U-Pb age sessions. Accuracy and precision achieved were better than 0.1% for the primary standard (91,500) and monitoring standard (TEMORA2). Additional information on the analytical procedures, data quality, geochemical analyses, zircon trace elements, and isotopic data are available in online Supplementary Materials 1 and 2.Major and trace element values are presented in Table 2. In discrimination diagrams, samples plot within gabbro or gabbro diorite fields, with a subalkaline tendency (online Supplementary Material 1). Notably, geochemistry allows samples to be separated into two distinct categories according to their elemental abundances, with Fe-oxide gabbro (RR-04) and gabbroic dike (LC-03) having more depleted character than Fe-Ti-oxide isotropic gabbros (HT-04 and RR-07; Figures 3 and 4).Sample LC-03 exhibits high SiO2 (52.6 wt.%) and MgO (10.9 wt.%) and low TiO2 (0.23 wt.%) abundance. Fe-oxide gabbro (RR-04) also has low TiO2 (0.24 wt.%) abundance but lower values of SiO2 (49.59 wt.%) and MgO (7.72 wt.%). These samples exhibit higher MgO, CaO, and Cr (440, 870 ppm) values than the Fe-Ti-oxide gabbros. In contrast, more geochemically enriched samples (HT-04, RR-07) have higher concentrations of SiO2 (51.19, 54.24 wt.%) and TiO2 (0.86, 0.94 wt.%) and lower MgO (6.03, 7.26 wt.%) and Cr (150, 340 ppm). Notably, more depleted samples exhibit lower Ti/V (1–25) and Nb/Ta (1–3) ratios, while Fe-Ti-oxide gabbros tend to exhibit higher values for Ti/V (32–40) and Nb/Ta (11–13) ratios. In major oxide geochemical diagrams (MgO vs. TiO2 and SiO2 vs. MgO; Figures 3(a) and (b)), samples are plotted within fields associated with subduction processes (island arc and FAB).On primitive mantle-normalized trace and chondrite-normalized REE plots (Figures 4(a) and (b)), dike (LC-03) and Fe-oxide gabbro (RR-04) exhibit greater depletion of trace elements compared with Fe-Ti-oxide gabbro samples. These samples have notably lower abundances of some high-field-strength elements (HFSEs), such as Nb, Zr, Hf, and Ti, and positive anomalies among large-ion lithophile elements (LILEs; e.g., Ba, K, Rb, Cs, and Sr). In contrast, more enriched samples (Fe-Ti-oxide gabbros) resemble N- or E-MORBs and exhibit enrichment in LILE but minimal depletion in HFSE (Figure 4(a)). Similar patterns are observed in chondrite-normalized REE plot in which gabbroic dike and Fe-oxide gabbro exhibit greater depletion in REEs (Figure 4(b)) compared with Fe-Ti-oxide gabbro samples, which display REE contents similar to E- or N-MORB. Despite having distinct signatures, all samples show an overall enrichment in fluid-mobile/LILE (Cs, Rb, Ba, Th, K, and Sr) and discernible depletion of more immobile/HFSE (Nb, Ta, and Ti) compared with N-MORB lavas (Figures 4(a) and (b)).Zircons from samples RR-04 (Fe-oxide gabbro), HT-04 (Fe-Ti-oxide gabbro), and RR-2B (pegmatite) were analyzed to determine U-Pb ages, Lu-Hf isotopes, and trace elements abundances. Samples RR-07 and LC-03 did not yield zircons of sufficient abundance or size for analysis. Recovered zircon grains exhibit, generally, low length-to-width ratios (1:1 to 3:1) and are between 15 and 250 µm long. Most crystals have weak oscillatory and sector zoning under CL light (refer to supplementary material for CL images), typically observed in mafic igneous rocks [45]. The analyzed samples contain variable U (18, 940 ppm), Th (3, 706 ppm) contents, and Th/U ratios between 0.17 and 0.86. They show an increase in average U and Th content and Th/U ratios from RR-04 (190 and 88 ppm, 0.35) and HT-04 (200 and 90 ppm, 0.41) to pegmatitic gabbro (209 and 122 ppm, 0.54). These values are consistent with U and Th concentrations and Th/U ratios expected for magmatic zircons from gabbroic rocks [46].Zircon U-Pb Concordia ages (206Pb/238U vs. 207Pb/206Pb) are from the middle Permian Period (Roadian Age), ranging from 271.6 ± 0.6 to 267.6 ± 0.9 Ma. Of the samples measured, the oldest age was found in the Fe-oxide gabbro (RR-04; 271.6 ± 0.6 Ma), while the Fe-Ti-oxide (HT-04) and pegmatitic gabbro samples (RR-02B) are slightly younger at 268.1 ± 0.6 and 267.6 ± 0.9 Ma (2σ), respectively (Figure 5). Zircon-weighted mean plots show individual grains ages. Zircon Hf isotopes exhibit variations between samples, with values ranging between +6.8 and +15.5 (Figure 6). The Fe-oxide gabbro samples have the highest median value of εHf(t) at +12.2, and a more consistent εHf(t) values (+10.8 and +13), compared with the Fe-Ti-oxide samples (+11.1) and pegmatitic gabbro (+11.5). It is worth noting that the Fe-Ti-oxide gabbro samples exhibit a wider range of εHf(t) values, with the most and least juvenile zircon samples analyzed having values of +15.5 and +6.8, respectively.Zircon geochemical characteristics from gabbroic samples exhibit similarities with those observed in SSZ-ophiolite and plot between the continental arc and MOR fields (Figure 7(a); U/Yb vs. Nb/Yb diagram). A contrast between samples is better observed on primitive mantle-normalized trace and REE plots (Figures 7(b) and (c)). Fe-oxide gabbro zircons (RR-04) tend to exhibit lower trace and REE elemental abundances compared with zircons from Fe-Ti-oxide (HT-04) and pegmatitic (RR-2B) gabbros, especially for Y, Ce, Nd, Sm, Eu, Gd, Yb, and Lu concentrations and Th/U ratios.Gabbro compositions together with zircon geochronological and geochemical data constrain the timing and evolution of the youngest magmatic products described from the DMO. Analyzed gabbros exhibit low TiO2 contents and general depletion in HFSEs. Such compositions are usually unexpected in MOR ophiolites [47], which sources commonly exhibit smaller degrees of partial melting [3, 7]. Fe-Ti-oxide samples (RR-07, HT-04), Fe-oxide gabbro (RR-04), and gabbroic dike (LC-03) plot near or within the oceanic/island arc fields (Figure 8a), indicating a potential origin related to subduction processes. Furthermore, the AFM discrimination diagram (Figure 8b) exhibits Fe-Ti-oxide gabbros plotting within the arc-related noncumulate gabbros and diorites fields, while Fe-oxide gabbro falls near the arc-related ultramafic and mafic cumulates field. Thus, geochemically depleted Fe-oxide gabbro (RR-04) is likely to reflect fractional crystallization processes of melts formed in an intraoceanic system, whereas the high-Mg gabbroic dike (LC-03) probably fingerprints melt extraction from depleted mantle sources. Despite variances, the consistently low Ti, Zr, Hf, Nb, Ta, and Ti/V values across all analyzed samples indicate their classification as IAT. Furthermore, zircon U-Pb ages from these samples, ranging between 271.6 and 268 Ma, alongside positive εHf(t) values (+6.8 and +15.5), constrain an important episode of oceanic crust formation in the DMO in an island arc tectonic setting.New findings further elaborate on differences between early and late magmatic episodes in the DMO, as previously observed [32, 48]. Zircon U-Pb ages from crustal rocks indicate magmatic evolution of the DMO occurred over a ca. 10 Myr interval ([31, 32]; this study). The oldest magmatic episode (~ 277.5 Ma) is recorded from the southern sector of the DMO (Figure 1(c)), in which geochemical signatures of zircons recovered from anorthositic and plagiogranitic dikes indicate similarities to those observed in MOR and/or IAT settings [32]. This early magmatism is usually associated with lavas with MOR signatures [31, 32], which are considered to be products of deep fertile melt extraction from mantle sources [25, 30, 32].In contrast, younger crustal rocks are mostly observed in the northern sector and yield zircon U-Pb ages between 274.5 and 267.6 Ma ([31, 32]; this study). This younger magmatism is interpreted as a product of melts associated with an intraoceanic setting and is fingerprinted by studies in the crustal and mantle sections [24, 25, 31, 32]. Gabbros analyzed as part of this study exhibits subduction-related signatures, with ages ranging between 271.6 and 268.1 Ma. These findings contribute to a better understanding of the timing of younger magmatism and indicate the establishment of an intraoceanic system. Additionally, data presented herein contribute to the understanding of the temporal dynamics of fluid and melt circulation in the subduction system associated with the DMO.The combination of new geochemical and geochronological data together with existing data results in a refinement of understanding of the magmatic evolution of the DMO (Figures 9(a)–(e)). Zircon U-Pb ages ranging from approximately 277.5 to 267.6 Ma are reported from a diverse range of lithologies and geochemical compositions, distributed across a wide geographic area ([31, 32]; this study]. This age interval is associated with a complex spatial and temporal magmatic evolution that involves rocks from both the southern and northern sectors.Early magmatic episodes in the DMO have traditionally been associated with a mid-ocean ridge setting and deep-fertile melts [30]. Our research suggests that the early magmatic products in the DMO may have been triggered by the upwelling of fertile asthenospheric melts due to decompression processes in the mantle-wedge (Figure 9(b)). These processes may have occured before revented the influx of slab-derived components into the system. This interpretation is supported by considerations that MOR-like lavas can form approximately 1–10 Myr after subduction initiation [20]. This magmatic episode is likely characterized by plagiogranites and anorthosites containing zircon with geochemical signatures similar to those MORB and/or IAT dated at around 277.5 Ma [32]. In this scenario, a progressive evolution of the DMO in a subduction-related setting is preferred (Figure 9(b)–(c)).Following the evolution of the subduction system, FAB and IAT geochemical signatures appear in gabbros, mafic dikes, and lavas, indicating the establishment of an intraoceanic subduction system (Figure 9(d)). Mafic dikes with depleted geochemical characteristics suggest that melts were extracted from a refractory mantle source (Figure 9(d)). Other studies of petrology and geochemistry in the DMO mantle section have revealed the presence of depleted sources, including harzburgite and chromitite, which exhibit signatures comparable to those found in subduction-related settings [25, 29, 30]. Furthermore, these sources display fO2 (above MORB field) in Cr-spinels [25, 30] typical of oxidizing and fluid-rich environments [49].The presence of IAT signatures in the uppermost lava sequence [26] and gabbroic samples (Figures 3 and 8) indicates a more evolved intraoceanic system. Zircon U-Pb ages ranging from 271.6 to 268.1 Ma, occurring approximately 6–9 Myr years after the oldest recorded zircon U-Pb age from IAT-like gabbros in the DMO, could fingerprint the timing of pervasive formation of melts derived from the slab. These ages could also correlate with mantle refertilization [25, 30], potentially triggered by an influx of slab-derived melts into the mantle wedge, resulting in the combination of new fertile melts with previously depleted melts.The magmatic evolution of the DMO shares similarities with that of the IBM forearc system [8] in terms of the progression of its crust from FAB-boninitic rocks to IAT. However, there are notable differences in the timing and distribution of subduction-related signatures. Unlike the DMO, where subducting-related rocks are mostly confined to intrusive rocks and the uppermost lavas, rocks affected by slab-derived components are widespread and were formed shortly after subduction initiation (around 1–2 Myr) in the IBM system [8, 14]. The DMO exhibits a lava sequence largely unaffected by any significant SSZ influence, and subduction-related rocks are mostly recognizable approximately 6–9 Myr after subduction initiation. This suggests slow and protracted evolution in a forearc setting for the DMO, with significant differences from the fast- and short-lived system observed in the IBM forearc system.Petrographic and geochemical data, as well as zircon U-Pb ages, Hf isotopic, and trace element geochemical signatures from gabbroic rocks of the DMO, provide valuable insights into the evolution of an ancient intraoceanic system. Fe-oxide cumulate gabbro with zircon U-Pb ages of ca. 271.6 Ma and Fe-Ti-oxide gabbros (ca. 268.1 Ma) with IAT-like geochemical characteristics indicates evolution toward embryonic arc stage and constrain the DMO youngest magmatic episode. Our findings, when combined with previous geochronological and geochemical results, suggest that the DMO experienced an early stage of N-MORB crust evolution (ca. 277.5 Ma) before a pervasive influx of slab-derived components and refertilization of the mantle wedge resulted in the formation of arc-like rocks at 271.5–268 Ma. Results presented in this study contribute to a better understanding of the magmatic evolution of the DMO and allow comparison with other intraoceanic systems.We thank Dr. David Kimbrough for his comments on geochronological data at our study site, which enriched our research. We also thank Dr. Gültekin Topuz, two anonymous reviewers, and handling editor Professor Bo Wang for their valuable comments and suggestions, which greatly improved our manuscript. The authors acknowledge funding support from the Australian Research Council discovery project Diamonds in ophiolites: Recycling deep mantle into suprasubduction zones (ARC DP190100814).The authors declare no conflicts of interest.The original contributions and data presented in this study are included in the article and the supplementary materials.\",\"PeriodicalId\":18147,\"journal\":{\"name\":\"Lithosphere\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2024-01-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Lithosphere\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://doi.org/10.2113/2024/lithosphere_2023_283\",\"RegionNum\":4,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"GEOCHEMISTRY & GEOPHYSICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Lithosphere","FirstCategoryId":"89","ListUrlMain":"https://doi.org/10.2113/2024/lithosphere_2023_283","RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"GEOCHEMISTRY & GEOPHYSICS","Score":null,"Total":0}
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摘要

在气象组织北区,采集了原地和浮游的辉长岩样品(图 1(b))。在罗丁河,对一块具有亚辉质地的叶状铁-氧化物辉长岩(RR-04;41.37467°S,173.29011°E;图 2(a) 和 (e))进行了原位采样。在 RR-04 地点西南两公里处,从一个约 20 米宽的露头采集到了由细长(小于 10 厘米)辉绿岩长钉侵入的各向同性铁-钛-氧化辉长岩(RR-07;41.36678°S,173.30453°E)(图 2(b))。在同一地点附近(RR-07 西北方 4 公里处),从罗丁河(Roding River)的巨石中采集到辉长岩辉长岩(RR-02B;41.35869°S,173.25853°E)(图 2(d))。鉴于河床中橄榄岩和辉长岩巨石的数量以及上游辉长岩露头的存在,该样本被认为来自于 DMO。另一个各向同性的铁-钛-氧化辉长岩(图 2(f)),位于 DMO 与麦饭石组接触点以西 500 米处,采集自矿工河(HT-04;41.39433°S,173.23656°E)中的巨石。考虑到橄榄岩巨石的出现,以及米纳河上游地区被绘制为蛇绿岩地壳段的组成部分,其成因被认为与 DMO 有关(图 1)[38]。在红山超基性岩块内,从 Lowther 溪的一个露头采集到一个辉长岩堤(样本 LC-03;-41.64775,173.00594)(图 2(c) 和 (g))。该堤坝宽 2 米,浅倾角,侵入上地幔橄榄岩,其正长石和富橄榄石层的成分带陡倾。制备的样品用于岩相学、地球化学和锆石同位素分析。表 1 概述了样品的岩相特征,详细情况见在线补充材料 1。全岩主要元素和痕量元素分析在澳大利亚布里斯班的澳大利亚实验室服务设施进行。样品首先经过一系列步骤进行制备,包括清洗、干燥、破碎、分裂和粉碎。使用 X 射线荧光光谱仪测定主要元素氧化物的浓度,精度为 ±2%-5%。此外,还使用电感耦合等离子体质谱仪(ICP-MS)测量了 30 种微量元素,大多数元素的测量精度优于 ±5%。实施了质量控制措施,发现所有标准都在目标范围内,表明分析非常准确。主要氧化物的检出限为 0.01%,而微量元素的检出限则各不相同(在线补充材料 2)。锆石分离是在中国廊坊的河北地质调查院采用标准方法(重力、磁力和重液分离)进行的。将锆石装入环氧树脂中,然后抛光,露出晶核。使用配备了背散射、二次电子和阴极射线(CL)探测器的日立 SU3500 扫描电子显微镜对其进行成像。这些图像用于识别矿物裂缝、分带、内部结构和 CL 特性(CL 图像见在线补充材料 1)。锆石晶粒的同位素和痕量元素分析(91Zr、45Sc、49Ti、88Sr、89Y、93Nb、139La、140Ce、146Nd、147Sm、153Eu、157Gd、172Yb、175Lu、178Hf、206Pb、207Pb、208Pb、232Tb、232Tb、232Tb、232Tb、232Tb)、208Pb、232Th 和 238U)的研究是在昆士兰大学使用配备了 ASI RESOlution SE 193 nm 激光器的 Thermo Fisher iCAP RQ 四极 ICP-MS 进行的。U-Pb 同位素和痕量元素是在同一分析时段采集的。激光光斑的大小根据晶粒的大小进行调整。对于较大的锆石晶体(样品 RR-04、HT-04),采用 30 µm 的光斑尺寸,以 7 Hz 的重复频率和 3 J/cm3 的通量,在 1 秒钟的 30 个周期内采集数据。样品 RR-2B 采用 24 微米光斑尺寸进行分析,激光和 ICP-MS 设置与 30 微米光斑尺寸分析相同。锆石的 U-Pb 年龄分析以 91,500 颗锆石标准[39]为背景,以仪器偏差[40]和 TEMORA2 晶粒[41]为次要标准,以监测精确度和准确度。获得的数据表明,U-Pb 年龄测量的精确度和准确度优于 0.5%(见在线补充材料 1)。按照 Horstwood 等人[42]建议的程序,与 U-Pb 同位素比和一级与二级锆石标准的标准偏差相关的不确定性被传播到样品的不确定性中。对于锆石痕量元素,采用 NIST612 玻璃标准作为主要参考材料。昆士兰大学地球与环境科学学院地质分析质谱中心使用配备了 ASI RESOlution SE 193 nm 激光器的 Nu Plasma II 多收集器 ICP-MS (MC-ICP-MS) 对锆石中的 Lu-Hf(质量 171-180)进行了同位素分析。 在分析 U-Pb 同位素和痕量元素的同一光斑上,使用 50 µm 的较大光斑尺寸,以 8 Hz 的重复频率和 3 J/cm3 的样品通量,进行了三十五次一秒周期的测量。分析程序遵循 Zhou 等人的方法[44]。主要和次要锆石标准与用于 U-Pb 年龄分析的标准相同。一级标准(91,500)和监测标准(TEMORA2)的准确度和精确度均优于 0.1%。有关分析程序、数据质量、地球化学分析、锆石微量元素和同位素数据的更多信息,见在线补充材料 1 和 2。在判别图中,样品位于辉长岩或辉长闪长岩区域,具有亚碱性倾向(在线补充材料 1)。值得注意的是,地球化学可根据样品的元素丰度将其分为两个不同的类别,与Fe-Ti-Ox各向同性辉长岩(HT-04和RR-07;图3和图4)相比,Fe-Ox辉长岩(RR-04)和辉长岩堤(LC-03)具有更贫化的特征。铁氧化辉长岩(RR-04)的 TiO2 丰度也较低(0.24 重量%),但 SiO2 值(49.59 重量%)和 MgO 值(7.72 重量%)较低。与铁钛氧化物辉长岩相比,这些样品的氧化镁、氧化钙和铬(440、870 ppm)含量较高。相比之下,地球化学含量较高的样品(HT-04、RR-07)的二氧化硅(51.19、54.24 wt.%)和二氧化钛(0.86、0.94 wt.%)含量较高,而氧化镁(6.03、7.26 wt.%)和铬(150、340 ppm)含量较低。值得注意的是,贫化程度较高的样品显示出较低的 Ti/V 比值(1-25)和 Nb/Ta 比值(1-3),而铁钛氧化物辉长岩往往显示出较高的 Ti/V 比值(32-40)和 Nb/Ta 比值(11-13)。在主要氧化物地球化学图(MgO vs. TiO2 和 SiO2 vs. MgO;图 3(a)和(b))中,样品被绘制在与俯冲过程(岛弧和 FAB)相关的区域内。在原始地幔归一化痕量和软玉归一化 REE 图(图 4(a)和(b))中,与铁-钛氧化物辉长岩样品相比,堤(LC-03)和铁-氧化物辉长岩(RR-04)显示出更大的痕量元素损耗。这些样品中一些高场强元素(HFSEs),如 Nb、Zr、Hf 和 Ti 的丰度明显较低,大离子亲岩元素(LILEs,如 Ba、K、Rb、Cs 和 Sr)呈正异常。相比之下,富集程度较高的样品(Fe-Ti-氧化物辉长岩)类似于 N-或 E-MORB,表现出 LILE 的富集,但 HFSE 的损耗极小(图 4(a))。在软玉归一化 REE 图中也观察到类似的模式,其中辉长岩堤和铁氧体辉长岩与铁钛氧化物辉长岩样品相比,显示出更大的 REE 损耗(图 4(b)),后者显示的 REE 含量类似于 E- 或 N-MORB。与 N-MORB 熔岩相比,尽管所有样品都有不同的特征,但总体上都显示出流体流动/LILE(铯、铷、钡、钍、钾和锶)的富集和较不流动/HFSE(铌、钽和钛)的明显贫化(图 4(a)和(b))。对样品 RR-04(铁-氧化辉长岩)、HT-04(铁-钛-氧化辉长岩)和 RR-2B(伟晶岩)的锆石进行了分析,以确定铀-铅年代、lu-hf 同位素和微量元素丰度。RR-07 和 LC-03 样品没有产生足够丰度或尺寸的锆石,无法进行分析。回收的锆石晶粒长宽比一般较低(1:1 至 3:1),长度在 15 至 250 微米之间。大多数晶体在 CL 光下具有微弱的振荡和扇形分带(有关 CL 图像,请参阅补充材料),这通常是在岩浆火成岩中观察到的[45]。分析样品中的铀含量(18,940 ppm)和钍含量(3,706 ppm)各不相同,钍/铀比在 0.17 和 0.86 之间。它们表明,从 RR-04(190 和 88 ppm,0.35)和 HT-04(200 和 90 ppm,0.41)到辉长岩辉长岩(209 和 122 ppm,0.54),铀和钍的平均含量以及 Th/U 比率都在增加。锆石的 U-Pb 康科迪亚年龄(206Pb/238U 与 207Pb/206Pb)为二叠纪中期(Roadian 时代),介于 271.6 ± 0.6 至 267.6 ± 0.9 Ma 之间。在测量的样品中,年龄最大的是铁-氧化物辉长岩(RR-04;271.6 ± 0.6 Ma),而铁-钛-氧化物(HT-04)和伟晶岩辉长岩样品(RR-02B)的年龄稍小,分别为 268.1 ± 0.6 Ma 和 267.6 ± 0.9 Ma (2σ)(图 5)。锆石加权平均图显示了单个晶粒的年龄。锆石 Hf 同位素在不同样品之间存在差异,数值介于 +6.8 和 +15.5 之间(图 6)。与铁-钛氧化物样品(+11.1)和辉长岩辉长岩样品(+11.5)相比,铁-氧化物辉长岩样品的εHf(t)中值最高,为+12.2,εHf(t)值也较为一致(+10.8和+13)。
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Geochronological and Geochemical Constraints on the Magmatic Evolution of the Dun Mountain Ophiolite Belt, New Zealand
New whole-rock major and trace element geochemical, zircon U-Pb geochronological, and Hf isotopic data from gabbroic rocks in New Zealand’s mid-Permian Dun Mountain ophiolite belt (DMO) provide insight into the evolution of subduction systems and early stages of intraoceanic arc development. Fe-oxide-bearing gabbros yielded high εHf(t) values (+10.3 to +13) and zircon U-Pb ages of 271.6 ± 0.6 Ma. In contrast, Fe-Ti-oxide-bearing gabbros of 268.1 ± 0.6 Ma show more enriched geochemical characteristics, including a wide range of εHf(t) values (+15.5 to +6.8). New findings strengthen the evolutionary model for the DMO and place constraints on its youngest known magmatic episode. We infer that late magmatism fingerprinted by these gabbros, including consistent negative Nb-Ta anomalies, reflects early stages of arc development and formation of island arc tholeiites on the DMO. Our model is consistent with other existing regional geochronological and geochemical data, implying that the DMO had an early stage of normal-mid-ocean ridge basalt crustal accretion followed by an influx of slab-derived components and maturity of the subducting system between ca. 271.6 and 268 Ma. These results extend our understanding of the evolution of distinct intraoceanic systems.Ophiolites are fragments of ancient oceanic lithosphere that have been incorporated into continental margins [1, 2]. They can be formed in distinct tectonic settings, including mid-ocean ridge, back-arc, and forearc [3, 4]. However, since the recognition of lava with island arc tholeiites (IAT) and calc-alkaline geochemical signatures in the Troodos ophiolite [5], a growing number of studies have associated these fragments of ancient oceanic lithosphere to intraoceanic convergent plate margins [6]. Such ophiolites, formed during sea-floor spreading above the subducting slab, are referred to as suprasubduction zone (SSZ) ophiolites [7]. They are widely interpreted to form during subduction initiation and early growth of island arcs [2, 7, 8]. As a result, studying their geochemical and geochronological signatures is crucial for understanding plate tectonic processes and intraoceanic systems [3, 9-12].Different geochemical signatures, such as forearc basalt (FAB), boninite, and IAT, can often be found in rocks from the ophiolitic crustal section. These signatures are widely used to identify different stages of the ophiolite and the evolution of the intraoceanic system [13, 14]. However, diverse processes can affect the geochemical characteristics of ophiolitic rocks, for example, the injection of fluids and melts from the slab [15, 16], distinct episodes of melt extraction from the mantle [17], and cumulate processes [18, 19]. Additionally, specific processes, such as colder, denser slabs descending more quickly or a thicker sedimentary cover of the slab, can also contribute to the geochemical heterogeneity of ophiolitic rocks [20-22]. This complexity can make it challenging to determine an ophiolite’s tectonic setting or evolutionary model, which is usually complicated by a limited amount of accurate geochronological data in mafic-ultramafic rocks. As a result, different interpretations of the same ophiolite are often proposed.The middle Permian Dun Mountain ophiolite belt (DMO) [23] in New Zealand’s South Island is a prime example of the difficulties in interpreting ophiolites with diverse geochemical signatures and limited geochronological data. The mantle section from the DMO has a depleted geochemical character and spinel Cr# (0.7, 0.8) and TiO2 (wt.% < 0.2%) values that resemble those of subduction-related ophiolites [24, 25]. The lava section, on the other hand, has geochemical signatures similar to mid-ocean ridge ophiolites, dominated by normal-mid-ocean ridge basalt (N-MORB) geochemical signatures, while dikes and uppermost lavas resemble FABs or IAT [26-28]. As a result of these heterogeneous geochemical signatures, several models have been proposed to explain the tectonic setting in which the DMO formed including: at a mid-ocean ridge [29, 30], back-arc [23], in association with slow-spreading ridges in a forearc [26, 31], or fast-spreading ridges [32]. In part, these differing models reflect the limited geochronological data available to support the interpretation of various magmatic rocks geochemical signatures [32-34]. Further geochemical and geochronological research is needed to better understand the magmatic stages of the DMO, particularly within the lower crustal plutonic rocks it contains.This study presents new petrographic, whole-rock geochemical, zircon U-Pb geochronological, Lu-Hf isotopic, and geochemical characteristics of the intrusive mafic rocks of the DMO. The youngest magmatic products reported here indicate associations with subduction processes and magma extraction during the early stages of arc development. When combined with previous research, these new findings improve our understanding of the magmatic evolution of the DMO and provide insight into various stages of the development of an associated intraoceanic system.The DMO consists of serpentinized peridotites, cumulate sequences, gabbros, volcanic rocks, and dikes (Figure 1(a) and (b)). It is overlain by forearc basin sediments of the Maitai Group and structurally overlies the Patuki and Croisilles mélanges [23, 31, 34, 35]. Outcrops of the ophiolite belt have been offset ~480 km dextrally by the Alpine Fault since the early Miocene Epoch, separating them into northern and southern sectors [35, 36].DMO mantle sections are characterized by harzburgite and dunite, with sparse occurrences of podiform chromitite and pyroxenite [23]. Petrogenetic and geochemical studies of the Red Hills complex (northern sector; Figure 1(b)) indicate at least three igneous events associated with distinct melting episodes and refertilization processes [25, 29, 30]. The first event was related to the production of MORB-like melts through 10%–15% partial melting of mantle sources within the garnet stability field (>55 km depth). A subsequent event is interpreted to have been associated with an additional 10% partial melting of the mantle sources, which produced boninite-like melts in the spinel-stability field (30, 50 km depth) in a forearc setting. This stage was associated with the progression of the subduction system [25]. It is assumed that a final stage of development recorded in the mantle rocks reflects the channeling of slab-enriched melts and fluids. This may be attributed to the formation of plagioclase-bearing ultramafic rocks, at shallow depths inside the plagioclase stability field (about 15 km) [25, 29].The DMO crustal segment comprises a dismembered cumulate sequence, isotropic gabbros, and mafic volcanic rocks, such as sheeted dikes, lava flows, pillow lavas, and dikes [23, 26, 32, 37]. Cumulate sequences include pyroxenite, wehrlite, and dunite, interlayered with gabbros, including isotropic hornblende- and clinopyroxene-gabbros [26, 28, 37]. Volcanic rocks are predominantly basaltic and exhibit an upward transition to basaltic-andesites and, rarely, andesites [26, 32]. Early lavas are characterized by MORB-type signatures, with IAT becoming increasingly common up-section [26, 27, 32]. The DMO also contains a complicated network of dikes with varying lithologies and geochemical signatures [27, 32], with a predominance of FAB affinity.Due to earlier efforts to determine the ages of magmatic zircons using the Thermal ionization mass spectrometry(TIMS) method, the DMO has long been considered to have formed during the late Early Permian Period (ca. 280 ± 5 Ma [34]). In a later study, Jugum et al. [31] reanalyzed the same samples using the LA-ICP-MS method, which is also employed in this work, facilitating age comparisons. To maintain data consistency, this study predominantly utilizes the U-Pb zircon ages reported by Jugum et al. [31] to compare and constrain various stages of magmatic evolution within the DMO.Based on zircon U-Pb ages from both mafic and felsic rocks, the genesis and geochemical evolution of the DMO are considered to have taken place during an interval of 9 ± 3 Ma [28, 32, 33]. Samples from the southern sector (i.e., south of the Alpine Fault) tend to yield older ages than those from the northern sector (Figure 1(c)) with plagiogranite and anorthosite dikes yielding concordant Kungurian Age (middle Permian Period) age determinations (206Pb/238U vs. 207Pb/235U) of 277.6 ± 3.3 (MSWD = 1.4) and 277.4 ± 3.4 Ma (MSWD = 5.5), respectively [32]. When interpreted together with zircon geochemical data, these ages are considered representative of episodes of early N-MORB (plagiogranite) and middle MORB-IAT (anorthosite) crustal formation. In the northern sector, a plagiogranite dike cross-cutting the mantle flow foliation in peridotites of the Red Hills ultramafic complex has yielded a Kungurian Age (middle Permian Period) zircon U-Pb age determination of 274.5 ± 0.4 Ma (MSWD = 0.26) [33]. This is deemed the youngest age prior to cessation of deformation in the peridotite complex of the Red Hills massif [25].DMO formation remains a topic of discussion among researchers. Some suggest that it is a mid-ocean ridge (MOR)-type ophiolite that was subsequently exposed to a subduction system based on analyses of whole-rock and mineral geochemistry from mantle and crustal rocks [27, 29, 30]. However, others argue that it formed in a forearc setting [24, 25, 32], citing typical Penrose “stratigraphy,” the refractory nature of the mantle rocks, characteristics of some crustal rocks, and a conformably overlying succession of forearc sediments (Maitai Group). Among the forearc interpretations, DMO is considered to represent both a slow-spreading ridge [31] and a fast-spreading and short-lived ophiolite, similar to the modern Izu-Bonin-Mariana (IBM) forearc system [32].In the northern sector of the DMO, gabbro samples were collected both in situ and from float (Figure 1(b)). In the Roding River, a foliated Fe-oxide gabbro (RR-04; 41.37467°S, 173.29011°E; Figures 2(a) and (e)) with subophitic texture was sampled in situ. Two km SW of the RR-04 site, an isotropic Fe-Ti-oxide gabbro (RR-07; 41.36678°S, 173.30453°E) intruded by thin (<10 cm) dolerite dikes (Figure 2(b)), was collected from a ~20 m wide outcrop. Near the same locality (4 km to NW of RR-07), a pegmatitic gabbro (RR-02B; 41.35869°S, 173.25853°E) was collected from boulders in the Roding River (Figure 2(d)). Given the quantity of peridotite and gabbro boulders in the riverbed and the presence of gabbroic rock outcrops upstream, the sample is considered to be derived from the DMO. Another isotropic Fe-Ti-oxide gabbro (Figure 2(f)), 500 m W of the contact between the DMO and Maitai Group, was collected from boulders in the Miner River (HT-04; 41.39433°S, 173.23656°E). Considering the occurrence of peridotite boulders and that upstream areas of the Miner River are mapped as a component of the ophiolite crustal segment with their genesis considered to be related to the DMO (Figure 1) [38]. Within the Red Hills ultramafic massif, a gabbroic dike (sample LC-03; -41.64775, 173.00594) was collected from an outcrop in Lowther Creek (Figure 2(c) and (g)). This dike is 2 m wide, shallow-dipping, and intrudes an upper mantle peridotite with steeply dipping compositional banding of orthopyroxene and olivine-rich layers. Samples were prepared for petrography, geochemistry, and zircon isotopic analyses. Table 1 provides an overview of sample petrographic characteristics that are detailed in online Supplementary Material 1.Whole-rock major and trace element analysis was conducted at the Australian Laboratory Services facilities in Brisbane, Australia. The samples were first prepared in a series of steps including washing, drying, crushing, splitting, and pulverizing. The concentration of major element oxides was determined using an X-ray fluorescence spectrometer with a precision of ±2%–5%. Additionally, thirty trace elements were measured using an inductively coupled plasma mass spectrometer (ICP-MS) with a precision of better than ±5% for most elements. Quality control measures were implemented, and all standards were found to be within the target range, indicating highly accurate analyses. The detection limit for major oxides is 0.01%, while it varies for trace elements (online Supplementary Material 2).Zircon separation was performed using standard methods (gravimetric, magnetic, and heavy liquid separation) at the Hebei Geological Survey, Langfang, China. The cores of the grains were exposed by mounting the zircons in epoxy and then polishing them. They were imaged using a Hitachi SU3500 scanning electron microscope that was equipped with backscatter, secondary electron, and cathodoluminescence (CL) detectors. The images were used to identify mineral fractures, zoning, internal structures, and CL characteristics (see online Supplementary Material 1 for CL images).Isotopic and trace element analyses of zircon grains (91Zr, 45Sc, 49Ti, 88Sr, 89Y, 93Nb, 139La, 140Ce, 146Nd, 147Sm, 153Eu, 157Gd, 172Yb, 175Lu, 178Hf, 206Pb, 207Pb, 208Pb, 232Th, and 238U) were conducted using a Thermo Fisher iCAP RQ quadrupole ICP-MS equipped with an ASI RESOlution SE 193 nm laser at The University of Queensland. U-Pb isotopes and trace elements were collected in the same analytical session. The laser spot size was adjusted based on the size of the grains. For larger zircon crystals (samples RR-04, HT-04), data were collected with a 30 µm spot size in thirty cycles of 1 second at a repetition rate of 7 Hz and a fluence of 3 J/cm3. Sample RR-2B was analyzed using a 24 µm spot size, with the same laser and ICP-MS settings as the 30 µm spot size session. U-Pb age analyses on zircons were performed using the 91,500 zircon standard [39] for background, and instrumental bias [40] and TEMORA2 grains [41] were used as secondary standards to monitor precision and accuracy. Data obtained indicate precision and accuracy better than 0.5% for U-Pb age measurements (see online Supplementary Material 1). Uncertainties associated with U-Pb isotope ratios and standard deviation of primary and secondary zircon standards were propagated into sample uncertainties following procedures suggested by Horstwood et al. [42]. For zircon trace elements, a NIST612 glass standard was used as a primary reference material. Data were processed using the Iolite software [43], and Zr was used for internal normalization of the trace elements.Isotopic analysis of Lu-Hf in zircon (masses 171–180) was conducted using a Nu Plasma II multicollector ICP-MS (MC-ICP-MS) equipped with an ASI RESOlution SE 193 nm laser at the Center for Geoanalytical Mass Spectrometry, School of Earth and Environmental Sciences at The University of Queensland. Measurements were carried out using a larger spot size of 50 µm, in thirty-five cycles of 1 second at a repetition rate of 8 Hz and an on-sample fluence of 3 J/cm3 for the same spot where the grains were analyzed for U-Pb isotopes and trace elements. Analytical procedures followed Zhou et al. [44]. Primary and secondary zircon standards were the same as those used for the U-Pb age sessions. Accuracy and precision achieved were better than 0.1% for the primary standard (91,500) and monitoring standard (TEMORA2). Additional information on the analytical procedures, data quality, geochemical analyses, zircon trace elements, and isotopic data are available in online Supplementary Materials 1 and 2.Major and trace element values are presented in Table 2. In discrimination diagrams, samples plot within gabbro or gabbro diorite fields, with a subalkaline tendency (online Supplementary Material 1). Notably, geochemistry allows samples to be separated into two distinct categories according to their elemental abundances, with Fe-oxide gabbro (RR-04) and gabbroic dike (LC-03) having more depleted character than Fe-Ti-oxide isotropic gabbros (HT-04 and RR-07; Figures 3 and 4).Sample LC-03 exhibits high SiO2 (52.6 wt.%) and MgO (10.9 wt.%) and low TiO2 (0.23 wt.%) abundance. Fe-oxide gabbro (RR-04) also has low TiO2 (0.24 wt.%) abundance but lower values of SiO2 (49.59 wt.%) and MgO (7.72 wt.%). These samples exhibit higher MgO, CaO, and Cr (440, 870 ppm) values than the Fe-Ti-oxide gabbros. In contrast, more geochemically enriched samples (HT-04, RR-07) have higher concentrations of SiO2 (51.19, 54.24 wt.%) and TiO2 (0.86, 0.94 wt.%) and lower MgO (6.03, 7.26 wt.%) and Cr (150, 340 ppm). Notably, more depleted samples exhibit lower Ti/V (1–25) and Nb/Ta (1–3) ratios, while Fe-Ti-oxide gabbros tend to exhibit higher values for Ti/V (32–40) and Nb/Ta (11–13) ratios. In major oxide geochemical diagrams (MgO vs. TiO2 and SiO2 vs. MgO; Figures 3(a) and (b)), samples are plotted within fields associated with subduction processes (island arc and FAB).On primitive mantle-normalized trace and chondrite-normalized REE plots (Figures 4(a) and (b)), dike (LC-03) and Fe-oxide gabbro (RR-04) exhibit greater depletion of trace elements compared with Fe-Ti-oxide gabbro samples. These samples have notably lower abundances of some high-field-strength elements (HFSEs), such as Nb, Zr, Hf, and Ti, and positive anomalies among large-ion lithophile elements (LILEs; e.g., Ba, K, Rb, Cs, and Sr). In contrast, more enriched samples (Fe-Ti-oxide gabbros) resemble N- or E-MORBs and exhibit enrichment in LILE but minimal depletion in HFSE (Figure 4(a)). Similar patterns are observed in chondrite-normalized REE plot in which gabbroic dike and Fe-oxide gabbro exhibit greater depletion in REEs (Figure 4(b)) compared with Fe-Ti-oxide gabbro samples, which display REE contents similar to E- or N-MORB. Despite having distinct signatures, all samples show an overall enrichment in fluid-mobile/LILE (Cs, Rb, Ba, Th, K, and Sr) and discernible depletion of more immobile/HFSE (Nb, Ta, and Ti) compared with N-MORB lavas (Figures 4(a) and (b)).Zircons from samples RR-04 (Fe-oxide gabbro), HT-04 (Fe-Ti-oxide gabbro), and RR-2B (pegmatite) were analyzed to determine U-Pb ages, Lu-Hf isotopes, and trace elements abundances. Samples RR-07 and LC-03 did not yield zircons of sufficient abundance or size for analysis. Recovered zircon grains exhibit, generally, low length-to-width ratios (1:1 to 3:1) and are between 15 and 250 µm long. Most crystals have weak oscillatory and sector zoning under CL light (refer to supplementary material for CL images), typically observed in mafic igneous rocks [45]. The analyzed samples contain variable U (18, 940 ppm), Th (3, 706 ppm) contents, and Th/U ratios between 0.17 and 0.86. They show an increase in average U and Th content and Th/U ratios from RR-04 (190 and 88 ppm, 0.35) and HT-04 (200 and 90 ppm, 0.41) to pegmatitic gabbro (209 and 122 ppm, 0.54). These values are consistent with U and Th concentrations and Th/U ratios expected for magmatic zircons from gabbroic rocks [46].Zircon U-Pb Concordia ages (206Pb/238U vs. 207Pb/206Pb) are from the middle Permian Period (Roadian Age), ranging from 271.6 ± 0.6 to 267.6 ± 0.9 Ma. Of the samples measured, the oldest age was found in the Fe-oxide gabbro (RR-04; 271.6 ± 0.6 Ma), while the Fe-Ti-oxide (HT-04) and pegmatitic gabbro samples (RR-02B) are slightly younger at 268.1 ± 0.6 and 267.6 ± 0.9 Ma (2σ), respectively (Figure 5). Zircon-weighted mean plots show individual grains ages. Zircon Hf isotopes exhibit variations between samples, with values ranging between +6.8 and +15.5 (Figure 6). The Fe-oxide gabbro samples have the highest median value of εHf(t) at +12.2, and a more consistent εHf(t) values (+10.8 and +13), compared with the Fe-Ti-oxide samples (+11.1) and pegmatitic gabbro (+11.5). It is worth noting that the Fe-Ti-oxide gabbro samples exhibit a wider range of εHf(t) values, with the most and least juvenile zircon samples analyzed having values of +15.5 and +6.8, respectively.Zircon geochemical characteristics from gabbroic samples exhibit similarities with those observed in SSZ-ophiolite and plot between the continental arc and MOR fields (Figure 7(a); U/Yb vs. Nb/Yb diagram). A contrast between samples is better observed on primitive mantle-normalized trace and REE plots (Figures 7(b) and (c)). Fe-oxide gabbro zircons (RR-04) tend to exhibit lower trace and REE elemental abundances compared with zircons from Fe-Ti-oxide (HT-04) and pegmatitic (RR-2B) gabbros, especially for Y, Ce, Nd, Sm, Eu, Gd, Yb, and Lu concentrations and Th/U ratios.Gabbro compositions together with zircon geochronological and geochemical data constrain the timing and evolution of the youngest magmatic products described from the DMO. Analyzed gabbros exhibit low TiO2 contents and general depletion in HFSEs. Such compositions are usually unexpected in MOR ophiolites [47], which sources commonly exhibit smaller degrees of partial melting [3, 7]. Fe-Ti-oxide samples (RR-07, HT-04), Fe-oxide gabbro (RR-04), and gabbroic dike (LC-03) plot near or within the oceanic/island arc fields (Figure 8a), indicating a potential origin related to subduction processes. Furthermore, the AFM discrimination diagram (Figure 8b) exhibits Fe-Ti-oxide gabbros plotting within the arc-related noncumulate gabbros and diorites fields, while Fe-oxide gabbro falls near the arc-related ultramafic and mafic cumulates field. Thus, geochemically depleted Fe-oxide gabbro (RR-04) is likely to reflect fractional crystallization processes of melts formed in an intraoceanic system, whereas the high-Mg gabbroic dike (LC-03) probably fingerprints melt extraction from depleted mantle sources. Despite variances, the consistently low Ti, Zr, Hf, Nb, Ta, and Ti/V values across all analyzed samples indicate their classification as IAT. Furthermore, zircon U-Pb ages from these samples, ranging between 271.6 and 268 Ma, alongside positive εHf(t) values (+6.8 and +15.5), constrain an important episode of oceanic crust formation in the DMO in an island arc tectonic setting.New findings further elaborate on differences between early and late magmatic episodes in the DMO, as previously observed [32, 48]. Zircon U-Pb ages from crustal rocks indicate magmatic evolution of the DMO occurred over a ca. 10 Myr interval ([31, 32]; this study). The oldest magmatic episode (~ 277.5 Ma) is recorded from the southern sector of the DMO (Figure 1(c)), in which geochemical signatures of zircons recovered from anorthositic and plagiogranitic dikes indicate similarities to those observed in MOR and/or IAT settings [32]. This early magmatism is usually associated with lavas with MOR signatures [31, 32], which are considered to be products of deep fertile melt extraction from mantle sources [25, 30, 32].In contrast, younger crustal rocks are mostly observed in the northern sector and yield zircon U-Pb ages between 274.5 and 267.6 Ma ([31, 32]; this study). This younger magmatism is interpreted as a product of melts associated with an intraoceanic setting and is fingerprinted by studies in the crustal and mantle sections [24, 25, 31, 32]. Gabbros analyzed as part of this study exhibits subduction-related signatures, with ages ranging between 271.6 and 268.1 Ma. These findings contribute to a better understanding of the timing of younger magmatism and indicate the establishment of an intraoceanic system. Additionally, data presented herein contribute to the understanding of the temporal dynamics of fluid and melt circulation in the subduction system associated with the DMO.The combination of new geochemical and geochronological data together with existing data results in a refinement of understanding of the magmatic evolution of the DMO (Figures 9(a)–(e)). Zircon U-Pb ages ranging from approximately 277.5 to 267.6 Ma are reported from a diverse range of lithologies and geochemical compositions, distributed across a wide geographic area ([31, 32]; this study]. This age interval is associated with a complex spatial and temporal magmatic evolution that involves rocks from both the southern and northern sectors.Early magmatic episodes in the DMO have traditionally been associated with a mid-ocean ridge setting and deep-fertile melts [30]. Our research suggests that the early magmatic products in the DMO may have been triggered by the upwelling of fertile asthenospheric melts due to decompression processes in the mantle-wedge (Figure 9(b)). These processes may have occured before revented the influx of slab-derived components into the system. This interpretation is supported by considerations that MOR-like lavas can form approximately 1–10 Myr after subduction initiation [20]. This magmatic episode is likely characterized by plagiogranites and anorthosites containing zircon with geochemical signatures similar to those MORB and/or IAT dated at around 277.5 Ma [32]. In this scenario, a progressive evolution of the DMO in a subduction-related setting is preferred (Figure 9(b)–(c)).Following the evolution of the subduction system, FAB and IAT geochemical signatures appear in gabbros, mafic dikes, and lavas, indicating the establishment of an intraoceanic subduction system (Figure 9(d)). Mafic dikes with depleted geochemical characteristics suggest that melts were extracted from a refractory mantle source (Figure 9(d)). Other studies of petrology and geochemistry in the DMO mantle section have revealed the presence of depleted sources, including harzburgite and chromitite, which exhibit signatures comparable to those found in subduction-related settings [25, 29, 30]. Furthermore, these sources display fO2 (above MORB field) in Cr-spinels [25, 30] typical of oxidizing and fluid-rich environments [49].The presence of IAT signatures in the uppermost lava sequence [26] and gabbroic samples (Figures 3 and 8) indicates a more evolved intraoceanic system. Zircon U-Pb ages ranging from 271.6 to 268.1 Ma, occurring approximately 6–9 Myr years after the oldest recorded zircon U-Pb age from IAT-like gabbros in the DMO, could fingerprint the timing of pervasive formation of melts derived from the slab. These ages could also correlate with mantle refertilization [25, 30], potentially triggered by an influx of slab-derived melts into the mantle wedge, resulting in the combination of new fertile melts with previously depleted melts.The magmatic evolution of the DMO shares similarities with that of the IBM forearc system [8] in terms of the progression of its crust from FAB-boninitic rocks to IAT. However, there are notable differences in the timing and distribution of subduction-related signatures. Unlike the DMO, where subducting-related rocks are mostly confined to intrusive rocks and the uppermost lavas, rocks affected by slab-derived components are widespread and were formed shortly after subduction initiation (around 1–2 Myr) in the IBM system [8, 14]. The DMO exhibits a lava sequence largely unaffected by any significant SSZ influence, and subduction-related rocks are mostly recognizable approximately 6–9 Myr after subduction initiation. This suggests slow and protracted evolution in a forearc setting for the DMO, with significant differences from the fast- and short-lived system observed in the IBM forearc system.Petrographic and geochemical data, as well as zircon U-Pb ages, Hf isotopic, and trace element geochemical signatures from gabbroic rocks of the DMO, provide valuable insights into the evolution of an ancient intraoceanic system. Fe-oxide cumulate gabbro with zircon U-Pb ages of ca. 271.6 Ma and Fe-Ti-oxide gabbros (ca. 268.1 Ma) with IAT-like geochemical characteristics indicates evolution toward embryonic arc stage and constrain the DMO youngest magmatic episode. Our findings, when combined with previous geochronological and geochemical results, suggest that the DMO experienced an early stage of N-MORB crust evolution (ca. 277.5 Ma) before a pervasive influx of slab-derived components and refertilization of the mantle wedge resulted in the formation of arc-like rocks at 271.5–268 Ma. Results presented in this study contribute to a better understanding of the magmatic evolution of the DMO and allow comparison with other intraoceanic systems.We thank Dr. David Kimbrough for his comments on geochronological data at our study site, which enriched our research. We also thank Dr. Gültekin Topuz, two anonymous reviewers, and handling editor Professor Bo Wang for their valuable comments and suggestions, which greatly improved our manuscript. The authors acknowledge funding support from the Australian Research Council discovery project Diamonds in ophiolites: Recycling deep mantle into suprasubduction zones (ARC DP190100814).The authors declare no conflicts of interest.The original contributions and data presented in this study are included in the article and the supplementary materials.
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Lithosphere
Lithosphere GEOCHEMISTRY & GEOPHYSICS-GEOLOGY
CiteScore
3.80
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16.70%
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284
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